二甲基硅油 C-Si 伸缩振动模式红外光谱研究

在303~393 K温度范围内,采用变温傅里叶变换衰减全反射红外光谱技术(ATR-FTIR)研究了二甲基硅油的一维红外光谱、二阶导数红外光谱、四阶导数红外光谱和去卷积红外光谱。实验发现,在1800~600 cm~(-1)范围内,二甲基硅油主要存在CH_3伸缩振动模式(νCH_3)、CH_3变形振动模式(δCH_3)、CH_3摇摆振动模式(ρCH_3)、Si-O伸缩振动模式(νSi-O)和Si-C伸缩振动式(νSi-C)等5种红外吸收模式,其中782 cm~(-1)和789 cm~(-1)处的红外吸收峰归属于二甲基硅油νSi-C。以二甲基硅油νSi-C为研究对象,进一步开展相关二维红外光谱的研究。结果发现,随着测定温度的升高,二甲基硅油νSi-C红外吸收强度的变化快慢顺序为:789 cm~(-1)782 cm~(-1)。本项研究拓展了ATR-FTIR技术在二甲基硅油热变性方面的研究范围。     

基于DUBBO+ZOOKEEPER计量服务平台研究

基于DUBBO+ZOOKEEPER的计量服务平台是互联网与传统计量检测服务业相结合的产物,平台系统设计充分考虑了计量行业特点,在此基础上确定系统的建设目标,重点解决分布式系统集群中数据共享、数据一致性与服务水平扩展等问题。系统遵循JF1069-2012、JJF1033-2014、GB/T19022.1、ISO10012-1、ISO9000和ISO/IEC17025等规范,使用JAVA语言和众多开源框架,融入先进的管理理念,对涉及涵盖政府、计量技术机构、企事业单位、高校各个部门计量行业的工作程序进行全面的规范和整合,实现以服务为中心,对计量资源人、才、物(标准、规范、检测业务、器具证书)等方面的科学管理,同时辅以决策支持和实时的智能化预警机制。构建计量管理知识资源化、数字化具有十分重要的现实意义和应用价值。     

Enhanced Thermal Conductivity of 5A Molecular Sieve with BNs Segregated Structures

5A molecular sieves have been widely used as adsorbents in cryogenic distillation for hydrogen isotope separation in fusion reactor engineering, but its low thermal conductivity is detrimental to the process stability. Improving the thermal conductivity of 5A molecular sieves is one of the most important goals for high‐performance devices. Here, firm segregated structures with boron nitride sheets (BNs) are constructed around 5A molecular sieve particles. SEM results show 30 µm BNs tend to form the better networks in comparison with that of 0.12 µm BNs at 40 wt% loadings. It is further verified that BNs with the larger size promote the thermal conductivity. Meanwhile, the thermal conductivity increases with the increasing amounts of BNs. XRD and specific surface area results indicate that the sintering and the addition of BNs exert negligible effects on the structure of 5A molecular sieve. These results indirectly show 5A molecular sieve with BNs segregated structures is very likely to be used for the application of hydrogen isotopic separation. Besides, this work provides new insight into the construction of segregated structure in inorganic porous materials.

     

Nanoconfined Nickel@Carbon Core–Shell Cocatalyst Promoting Highly Efficient Visible‐Light Photocatalytic H2 Production

The realization of large‐scale solar hydrogen (H₂) production relies on the development of high‐performance and low‐cost photocatalysts driven by sunlight. Recently, cocatalysts have demonstrated immense potential in enhancing the activity and stability of photocatalysts. Hence, the rational design of highly active and inexpensive cocatalysts is of great significance. Here, a facile method is reported to synthesize Ni@C core–shell nanoparticles as a highly active cocatalyst. After merging Ni@C cocatalyst with CdS nanorod (NR), a tremendously enhanced visible‐light photocatalytic H₂‐production performance of 76.1 mmol g^?1 h^?1 is achieved, accompanied with an outstanding quantum efficiency of 31.2% at 420 nm. The state‐of‐art characterizations (e.g., synchrotron‐based X‐ray absorption near edge structure) and theoretical calculations strongly support the presence of pronounced nanoconfinement effect in Ni@C core–shell nanoparticles, which leads to controlled Ni core size, intimate interfacial contact and rapid charge transfer, optimized electronic structure, and protection against chemical corrosion. Hence, the combination of nanoconfined Ni@C with CdS nanorod leads to significantly improved photocatalytic activity and stability. This work not only for the first time demonstrates the great potential of using highly active and inexpensive Ni@C core–shell structure to replace expensive Pt in photocatalysis but also opens new avenues for synthesizing cocatalyst/photocatalyst hybridized systems with excellent performance by introducing nanoconfinement effect.     

Influence of Heat Input on Microstructure and Mechanical Properties of Laser Welding GH4169 Bolt Assembly—Numerical and Experimental Analysis

By conducting the numerical and experimental analysis, the influence of heat input on the microstructures and mechanical properties of laser welding GH4169 bolt assembly is systematically investigated. The weld formation, temperature field, and residual stress distribution during laser welding by using the finite element modeling are consistent with experimental results. The numerical simulation results show that the increase of heat input imparts lower residual stresses and higher temperature gradient. During the process of laser welding, the steepest temperature gradient and the peak residual stress arise in the fusion zone (FZ). In addition, the dissolution of γ″ and γ′ toward the fusion line increases in heat affected zone (HAZ), but only Laves phase is observed in FZ. With increasing heat input from 24 to 48 J mm⁻¹, the ultimate tensile strength of welded joints decreases. Both the lowest microhardness values and tensile failure of GH4169 alloy laser welded joint are in FZ. Herein, it is that the relationship among the heat input, microstructures, and mechanical properties of GH4196 bolt assembly in laser welding is systematically established, which will be of guiding significance for the selection of welding parameters in aerospace.     

模拟电路故障诊断的约束聚类集成BP网络算法

针对通用BP网络对于高纬度、大数据量训练收敛困难的问题,在使用动量因子、自适应调整学习速率等方法的基础,引入约束聚类,构造集成神经网络,以提高网络的训练速度及诊断效果;首先,采用约束聚类算法将训练样本集划分为若干个规模相当的子样本集,分别训练生成相应子网络;此外,在诊断过程中除各子网络的输出变量外,还加入了诊断数据相对各子训练样本集的隶属度因子;最后通过一个实际电路板25维采样数据、38类故障的BP网络诊断实例验证了算法的可行性。     

Tissue dynamics spectroscopy for three-dimensional tissue-based drug screening

Tissue dynamics spectroscopy combines dynamic light scattering with short-coherence digital holography to capture intracellular motion inside multicellular tumor spheroid tissue models. The cellular mechanical activity becomes an endogenous imaging contrast agent for motility contrast imaging. Fluctuation spectroscopy is performed on dynamic speckle from the proliferating shell and hypoxic core to generate drug-response spectrograms that are frequency versus time representations of the changes in spectral content induced by an applied compound or an environmental perturbation. A combination of 28 reference compounds and conditions applied to rat osteogenic UMR-106 spheroids generated spectrograms that were crosscorrelated in a similarity matrix used for unsupervised hierarchical clustering of similar compound responses. This work establishes the feasibility of tissue dynamics spectroscopy for three-dimensional tissue-based phenotypic profiling of drug response as a fully endogenous probe of the response of tissue to reference compounds.     

Real-time foveation filtering using nonlinear Mipmap interpolation

In recent years, several techniques have been proposed to simulate the gaze effect of the Human Visual System (HVS). It is believed that this effect is due to the foveation filtering. Current techniques to simulate the foveation filtering in computer graphics are either slow or suffer from artifacts and limitations. In this paper, we present a new approach of foveation filtering based on the Mipmap Pyramid of the current view by considering the relationship between the Gaussian kernel and Mipmap level. Due to the nonlinear Mipmap interpolation under the Bilateral Filtering scheme, we are able to simulate the foveation filtering more naturally and efficiently than in previous work. Moreover, a detail enhancement method based on the Cornsweet illusion is proposed to augment the gazing effect. We demonstrate our new approach with a variety of examples and provide comparisons with recent approaches.     

Tracking in a Dense Crowd Using Multiple Cameras

Tracking people in a dense crowd is a challenging problem for a single camera tracker due to occlusions and extensive motion that make human segmentation difficult. In this paper we suggest a method for simultaneously tracking all the people in a densely crowded scene using a set of cameras with overlapping fields of view. To overcome occlusions, the cameras are placed at a high elevation and only people’s heads are tracked. Head detection is still difficult since each foreground region may consist of multiple subjects. By combining data from several views, height information is extracted and used for head segmentation. The head tops, which are regarded as 2D patches at various heights, are detected by applying intensity correlation to aligned frames from the different cameras. The detected head tops are then tracked using common assumptions on motion direction and velocity. The method was tested on sequences in indoor and outdoor environments under challenging illumination conditions. It was successful in tracking up to 21 people walking in a small area (2.5 people per m²), in spite of severe and persistent occlusions.