Mechanical properties of nano SiO2 filled gypsum particleboard

Nano SiO2 was filled into gypsum particleboard. Effect of the amount of nano SiO2 particles filled, ultrasonic dissipating duration and treating the nano particles with different coupling agents on the mechanical properties of the board were studied respectively. The results show that nano SiO2 is helpful for the improvement of the properties. Adding 3%（mass fraction） nano SiO2 is the best for the improvement of both modulus of rupture（MOR） and modulus of elasticity（MOE） of the boards formed at 30 ℃ or 40 ℃. For the boards formed at 30 ℃, their MOR and MOE can be improved by 8.77% and 12.24%, and MOR and MOE of the boards formed at 40 ℃ can be improved by 44.44% and 108.38%.3% is also the best addition proportion to improve internal bond（IB） of the boards formed at 30 ℃, while 5% is the best for that of the boards formed at 40 ℃. At room temperature, dissipating nano Si02 into flake by ultrasonic has better effect on the properties of the final products. Through ultrasonic treating for 1 h and the best treating duration, the MOR and MOE can be increased by 41.99% and 47.80%. In addition, different coupling agents have different effects on the final properties too, and silane coupling agent KH570 is better for the improvement of properties of the boards formed at room temperature.     

磷酸铁锂粒度测试条件研究

采用激光粒度法测试磷酸铁锂的粒度,研究超声波时间、遮光率、循环速度、分散剂用量对测试结果的影响.结果表明,在超声时间3 min,遮光率5～10,循环速度500 r/min,加入1 mL焦磷酸钠分散剂时,样品分散效果较好.     

概念图在高中化学复习课中的应用研究

化学概念图是一种使用起来非常有效的高中化学教学辅助工具,能够在很大程度上促进师生的共同进步.特别是在复习课中运用概念图,更能够帮助学生自主构建合理的化学知识网络,完善化学知识体系;同时,在复习课中运用概念图,也能够让学生更好地融入课堂并加强学生的合作力,帮助学生更好地理解相应的知识点.一方面它能对化学概念知识进行深层次的梳理贯通,另一方面也可以促使学生整合新旧知识,从整体上掌握知识,提高思维能力,最终使学生学会学习.因此,笔者对概念图在高中化学复习课中的作用进行了分析,探究了几种行之有效的绘制概念图的方法,并列举了实例进行详细分析,希望对一线化学老师的教学有启示作用.     

饮用水中天然有机物的分析与表征方法

天然有机物(NOM)是一类分布广泛、成分复杂的有机混合物,可严重影响饮用水的处理效率,并可能对出水水质产生严重的不利影响。因此,为了改进和优化饮用水的处理过程,在研究和实际应用阶段对NOM进行表征和定量以了解其结构特性和反应性具有重要意义。文中先对NOM的富集方法进行了介绍,接着梳理了不同分离方法的依据及作用,最后总结了各类表征方法的原理及应用,以期有助于对NOM和饮用水处理的深入研究。     

双酰胺类杀虫剂及其作用机制、抗性机理与环境风险

双酰胺类杀虫剂结构新颖多样,作用机制新颖独特,防虫效果卓越广谱.介绍了双酰胺类杀虫剂的结构类型,总结了具有应用价值进入研发程序的双酰胺类杀虫剂,并就其作用机制和抗性机理进行了分析探讨,就其环境风险进行了浅析评价,旨在为双酰胺类杀虫剂的研究、开发与应用提供支持与指导.     

大段长高压电缆护层保护器暂态特性分析与参数优化设计

大段长高压电缆在运行时会产生过高的护层感应电压,这对电缆护层保护器的过电压防护特性提出了更高要求,因此需要针对大段长电缆护层保护器暂态特性进行分析研究。基于PSCAD仿真软件,建立了典型220 kV高压电缆线路仿真模型,得出了在短路过电压和雷击过电压情况下,高压电缆长度对护层感应电压暂态特性的影响。通过绝缘配合与能量保护相结合的方式,得到了保护器参数取值范围及电缆线路短路电流与长度的适配曲线,提出了护层保护器参数优化设计的具体方法,并进行了试验测试。测试结果表明:当电缆线路出现短路故障时,随着电缆长度的增加,护层感应电压先线性增长,随后在保护器残压阈值的限制作用下逐渐趋于"饱和"状态,现有保护器能量吸收能力难以满足大段长电缆需求;改进后的护层保护器能量吸收能力显著提升,20 k A短路电流时允许的电缆长度大幅提高,满足大段长高压电缆线路安全运行的要求。     

The Role of Rigid Residues in Modulating TEM-1 β-Lactamase Function and Thermostability

The relationship between protein motions (i.e., dynamics) and enzymatic function has begun to be explored in β-lactamases as a way to advance our understanding of these proteins. In a recent study, we analyzed the dynamic profiles of TEM-1 (a ubiquitous class A β-lactamase) and several ancestrally reconstructed homologues. A chief finding of this work was that rigid residues that were allosterically coupled to the active site appeared to have profound effects on enzyme function, even when separated from the active site by many angstroms. In the present work, our aim was to further explore the implications of protein dynamics on β-lactamase function by altering the dynamic profile of TEM-1 using computational protein design methods. The Rosetta software suite was used to mutate amino acids surrounding either rigid residues that are highly coupled to the active site or to flexible residues with no apparent communication with the active site. Experimental characterization of ten designed proteins indicated that alteration of residues surrounding rigid, highly coupled residues, substantially affected both enzymatic activity and stability; in contrast, native-like activities and stabilities were maintained when flexible, uncoupled residues, were targeted. Our results provide additional insight into the structure-function relationship present in the TEM family of β-lactamases. Furthermore, the integration of computational protein design methods with analyses of protein dynamics represents a general approach that could be used to extend our understanding of the relationship between dynamics and function in other enzyme classes.     

基于负荷综合权值的配电网孤岛划分策略

提出一种基于负荷综合权值的孤岛划分策略。采用熵值法和最优-最劣法（best-worst method,BWM）对负荷进行评价以得到负荷的客、主观权值,并通过相对熵耦合负荷客、主观权值以进一步求出负荷综合权值;对各负荷相对于不同DG的重要程度进行排序,并依据此排序将负荷纳入DG形成的孤岛中。通过IEEE-69节点配电网系统进行验证,结果表明：所提孤岛划分策略能够有效地保证配电网中重要负荷的供电可靠性并减少了线路损耗。     

深度空气分级条件下配风方式对炉内燃烧特性影响的数值模拟研究

借助数值模拟方法对四角切圆煤粉锅炉进行三维稳态数值模拟,观察其炉内燃烧过程,重点对比了在空气分级下不同配风方式对炉内空气流动和燃烧特性的影响。结果表明:底部配风量较多的正宝塔型、均等、缩腰型配风在炉膛底部形成较高切圆且温度较高,主燃区上部风量较小的正宝塔型和鼓腰型配风速度分布均匀,温度偏差较小,倒宝塔型和鼓腰型配风时出口NOx较其他3种配风方式要小。     

液力忆惯容器装置建模与特性试验

针对液力忆惯容器装置已有数学模型忽略因素过多的问题,考虑油液的惯性、动力学黏度以及装置内部的干摩擦,建立符合工程实际的非线性数学模型. 试制液力忆惯容器装置样机,并进行台架试验. 结果表明,当位移激励的频率较低时,液力忆惯容器装置提供的惯性力、黏滞阻尼力较小,可以近似等效为干摩擦阻尼器;当激励的频率较高时,装置等效为理想忆惯容器、非线性黏滞阻尼器、干摩擦阻尼器三元件并联. 装置的输出合力、惯性力、阻尼力试验值与仿真值最大偏差分别为5.70%、9.15%、5.47%,惯质特性曲线和寄生阻尼特性曲线的试验值与仿真值最大偏差分别为4.23%和8.50%,表明数学模型准确可靠,能够满足工程需要,为液力忆惯容器装置在减振系统中的应用奠定了基础.