全文获取类型
收费全文 | 848篇 |
免费 | 46篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 2篇 |
综合类 | 2篇 |
化学工业 | 183篇 |
金属工艺 | 7篇 |
机械仪表 | 12篇 |
建筑科学 | 34篇 |
矿业工程 | 8篇 |
能源动力 | 14篇 |
轻工业 | 87篇 |
水利工程 | 6篇 |
石油天然气 | 4篇 |
无线电 | 54篇 |
一般工业技术 | 119篇 |
冶金工业 | 186篇 |
原子能技术 | 4篇 |
自动化技术 | 174篇 |
出版年
2024年 | 2篇 |
2023年 | 7篇 |
2022年 | 18篇 |
2021年 | 34篇 |
2020年 | 21篇 |
2019年 | 13篇 |
2018年 | 23篇 |
2017年 | 22篇 |
2016年 | 21篇 |
2015年 | 24篇 |
2014年 | 26篇 |
2013年 | 57篇 |
2012年 | 41篇 |
2011年 | 59篇 |
2010年 | 39篇 |
2009年 | 43篇 |
2008年 | 44篇 |
2007年 | 44篇 |
2006年 | 35篇 |
2005年 | 42篇 |
2004年 | 31篇 |
2003年 | 29篇 |
2002年 | 20篇 |
2001年 | 11篇 |
2000年 | 12篇 |
1999年 | 18篇 |
1998年 | 12篇 |
1997年 | 19篇 |
1996年 | 10篇 |
1995年 | 12篇 |
1994年 | 10篇 |
1993年 | 8篇 |
1992年 | 6篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 11篇 |
1985年 | 5篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 10篇 |
1981年 | 4篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1976年 | 4篇 |
1972年 | 4篇 |
1963年 | 1篇 |
1955年 | 1篇 |
排序方式: 共有896条查询结果,搜索用时 15 毫秒
41.
Labuda R Parich A Berthiller F Tancinová D 《International journal of food microbiology》2005,105(1):19-25
A total of 50 samples of poultry feed mixtures of Slovakian origin were analyzed for eight toxicologically significant Fusarium mycotoxins, namely zearalenone (ZON), A-trichothecenes: diacetoxyscirpenol (DAS), T-2 toxin (T-2) and HT-2 toxin (HT-2) and B-trichothecenes: deoxynivalenol (DON), 3-acetyl-deoxynivalenol (3-ADON), 15-acetyl-deoxynivalenol (15-ADON) and nivalenol (NIV). The A-trichothecenes and the B-trichothecenes were detected by means of high pressure liquid chromatography with tandem mass spectrometry detection (HPLC-MS/MS) and gas chromatography electron capture detection (GC-ECD), respectively. Reversed phase-high performance liquid chromatography with a fluorescence detector (RP-HPLC-FLD) was used for ZON detection. The most frequent mycotoxin detected was T-2, which was found in 45 samples (90%) in relatively low concentrations ranging from 1 to 130 microg kg(-1) (average 13 microg kg(-1)), followed by ZON that was found in 44 samples (88%) in concentrations ranging from 3 to 86 microg kg(-1) (average 21 microg kg(-1)). HT-2 and DON were detected in 38 (76%) and 28 (56%) samples, respectively, in concentrations of 2 to 173 (average 18 microg kg(-1)) for HT-2 and 64 to 1230 microg kg(-1) sample (average 303 microg kg(-1)) for DON. The acetyl-derivatives of DON were in just four samples, while NIV was not detected in any of the samples investigated. In as many as 22 samples (44%), a combination of four simultaneously co-occurring mycotoxins, i.e. T-2, HT-2, ZON and DON, was revealed. Despite the limited number of samples investigated during this study poultry feed mixtures may represent a risk from a toxicological point of view and should be regarded as a potential source of the Fusarium mycotoxins in Central Europe. This is the first reported study dealing with zearalenone and trichothecene contamination of poultry mixed feeds from Slovakia. 相似文献
42.
N‐Arylsulfonyl Indolines as Retinoic Acid Receptor‐Related Orphan Receptor γ (RORγ) Agonists
下载免费PDF全文
![点击此处可从《ChemMedChem》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dr. Christelle Doebelin Rémi Patouret Ruben D. Garcia‐Ordonez Dr. Mi Ra Chang Dr. Venkatasubramanian Dharmarajan Dana S. Kuruvilla Scott J. Novick Li Lin Dr. Michael D. Cameron Dr. Patrick R. Griffin Dr. Theodore M. Kamenecka 《ChemMedChem》2016,11(23):2607-2620
The nuclear retinoic acid receptor‐related orphan receptor γ (RORγ; NR1F3) is a key regulator of inflammatory gene programs involved in T helper 17 (TH17) cell proliferation. As such, synthetic small‐molecule repressors (inverse agonists) targeting RORγ have been extensively studied for their potential as therapeutic agents for various autoimmune diseases. Alternatively, enhancing TH17 cell proliferation through activation (agonism) of RORγ may boost an immune response, thereby offering a potentially new approach in cancer immunotherapy. Herein we describe the development of N‐arylsulfonyl indolines as RORγ agonists. Structure–activity studies reveal a critical linker region in these molecules as the major determinant for agonism. Hydrogen/deuterium exchange coupled to mass spectrometry (HDX‐MS) analysis of RORγ–ligand complexes help rationalize the observed results. 相似文献
43.
44.
The reliability of solar concentrator is investigated using finite element (FE) modelling. An FE model of the receiver absorber is built and simulated using latin hypercube sampling. A transient thermal structural simulation is conducted, and the maximum thermal stress affecting the absorber is determined. Based on the failure criterion, the most effective parameters are determined and assigned as random variables. A stochastic simulation is performed resulting in a probability density function (PDF) of the thermal stress-life. The PDF is used to estimate the reliability of the absorber. Different designs and materials of the absorber tubes are investigated. Consequently, methods to improve the reliability of the absorber are identified. 相似文献
45.
Zero-valent iron nanoparticles rapidly aggregate. One of the reasons is magnetic forces among the nanoparticles. Magnetic field around particles is caused by composition of the particles. Their core is formed from zero-valent iron, and shell is a layer of magnetite. The magnetic forces contribute to attractive forces among the nanoparticles and that leads to increasing of aggregation of the nanoparticles. This effect is undesirable for decreasing of remediation properties of iron particles and limited transport possibilities. The aggregation of iron nanoparticles was established for consequent processes: Brownian motion, sedimentation, velocity gradient of fluid around particles and electrostatic forces. In our previous work, an introduction of influence of magnetic forces among particles on the aggregation was presented. These forces have significant impact on the rate of aggregation. In this article, a numerical computation of magnetic forces between an aggregate and a nanoparticle and between two aggregates is shown. It is done for random position of nanoparticles in an aggregate and random or arranged directions of magnetic polarizations and for structured aggregates with arranged vectors of polarizations. Statistical computation by Monte Carlo is done, and range of dominant area of magnetic forces around particles is assessed. 相似文献
46.
This study examined the individual and combined effects of exposure to positive Latino exemplars and prototypes in the media on White audience members' attitudes about and judgments regarding Latinos in society. Although it was expected that exposure to these favorable models would promote positive evaluations of Latinos among White consumers, the extent to which one mode of presentation could be privileged in the production of more beneficial outcomes was uncertain based on existing research. These results cautiously indicate that while prototypes may offer some advantages in terms of reducing stereotyping, both exemplar‐ and prototype‐based characterizations of positive race‐related media content (alone and in combination) can positively influence consumers' perceptions of target racial/ethnic groups. 相似文献
47.
Richard W. Johnson Paul R. McHugh Dana A. Knoll 《Numerical Heat Transfer, Part B: Fundamentals》2013,63(2):173-188
Abstract We examine the characteristics of a fully coupled inexact Newton method using defect correction to obtain high-order solutions for two problems: natural convection in a square cavity and mixed-convection flow over a backward step. Newton's method produces a linearized system with a Jacobian matrix and a residual vector, each of which can be formed using different discrete operators. Solution accuracy depends on the discretization used for the residuals. Defect correction employs low-order operators for the Jacobian but high-order operators for the residuals. We employ an O(h3) convection operator in the residual vector and upwinding in the Jacobian. We find that defect correction is an efficient and effective way to achieve high-order solutions. 相似文献
48.
Mariana‐Dana Damaceanu Radu‐Dan Rusu Alina Nicolescu Maria Bruma Alexander L Rusanov 《Polymer International》2011,60(8):1248-1258
This study focuses on the synthesis and characterization of new polyamides based on an aromatic asymmetric diamine‐containing phenoxy‐substituted benzophenone segment. Low‐temperature solution polycondensation reactions of this diamine with various aromatic diacid chlorides containing ether, hexafluoroisopropylidene or diphenylsilane groups resulted in polyamides with molecular weights in the range 102 900–113 200 g mol?1. The structures of these monomers and the corresponding polymers were fully confirmed using elemental analysis and infrared and NMR spectroscopy. All polyamides were easily soluble at room temperature in polar aprotic solvents and even in less polar solvents such as tetrahydrofuran. The polymers showed excellent thermal stability, up to 385 °C, and displayed glass transition temperatures in the range 225–256 °C. All the polymers presented blue florescence upon irradiation with UV light and thus show promise for applications in electroluminescent devices. Copyright © 2011 Society of Chemical Industry 相似文献
49.
Triphenylamine‐based oligomers and polymers with linear, hyperbranched, star‐shaped or dendrimer architectures have been synthesized and studied due to their interesting electro‐optical properties. In many cases insoluble materials are obtained. In this study, we report the synthesis of grafted polytriphenylamine by chemical and electrochemical polymerization of triphenylamine‐end‐functionalized poly(ε‐caprolactone). Functionalized ε‐caprolactone oligomers were obtained by ring‐opening polymerization of ε‐caprolactone initiated by 4‐hydroxymethyltriphenylamine/stannous octanoate (tin 2‐ethylhexanoate). The ring‐opening polymerization of ε‐caprolactone using 4‐hydroxymethyltriphenylamine/stannous octanoate as initiating system provided ε‐caprolactone oligomers, with well‐defined molecular weights, containing a triphenylamine terminal group. Chemical and electrochemical coupling oxidation of the triphenylamine ends allowed the formulation of polyarylamines with ε‐caprolactone oligomers as grafts. Graft copolymers with an aryleneamine backbone and short poly(ε‐caprolactone) grafts were obtained by (electro)chemical oxidation of oligomers containing triphenylamine terminal groups. Copyright © 2009 Society of Chemical Industry 相似文献
50.