Effects of bath temperature on the morphology and performance of EVOH membranes prepared by the cold‐solvent induced phase separation (CIPS) method

The development and characteristics of porous EVOH membranes by cold‐solvent induced phase separation (CIPS) process were investigated. Binary dopes of 1,3‐propandiol/EVOH prepared at 80 °C were immersed in 1,3‐propandiol at a lower temperature to engender polymer precipitation. The quench temperature affects phase separation modes, and hence structure and performance of resulting CIPS membranes. When the bath temperature was set below the crystallization line and above the binodal (e.g. 45 °C), the formed membrane was dominated by a packing of semicrystalline EVOH globules. When the bath was set at a temperature just below the spinodal (e.g. 20 °C), spinodal decomposition (SD) dominated the precipitation process to give a lacy‐like bicontinuous structure; yet there is also a clear imprint from polymer crystallization. When the bath temperature was set deeply within the spinodal dome (e.g. 5 °C), polymer crystallization affected only little the SD‐derived bicontinuous morphology. Water permeation flux, wettability, tensile strength, and ultra‐filtration experiments of the membranes were conducted. The results indicated that those properties were closely correlated with the porosity level, pore size, and membrane morphology. Moreover, X‐ray diffraction and DSC analyses indicated that the formed membranes had a crystallinity of 38 to 42%, consistent with the literature data. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44553.     

Effects of cobalt and cobalt oxide buffer layers on nucleation and growth of hot filament chemical vapor deposition diamond films on silicon (100)

An initial study on the nucleation and growth of diamond, using hot filament chemical vapor deposition (HFCVD) technique, was carried out on Co and CoO thin buffer layers on non-carbon substrates (Si (100)), and the results were compared with conventional scratching method. The substrate temperature during the growth was maintained at 750±50 °C. A mixture of CH₄ and H₂ (1: 100 volume %) was used for deposition. The total pressure during the two hour deposition was 30±2 Torr. X-ray photoelectron spectroscopy (XPS) study showed the diamond nucleation at different time periods on the Co and CoO seed layers. It is observed that Co helps in nucleation of diamond even though it is known to degrade the quality of diamond film on W-C substrate. The reason for improvement in our study is attributed to (i) the low content of Co (~0.01%) compared to W-C substrate (~5–6%), (ii) formation of CoSi₂ phase at elevated temperature, which might work as nucleation sites for diamond. SEM analysis reveals a change in the morphology of diamond film grown on cobalt oxide and a significant reduction in the size of densely packed crystallites. Raman spectroscopic analysis further suggests an improvement in the quality of the film grown on CoO buffer layer.     

Influence of the Polymeric Matrix and Thermal Treatment on the Properties of Polyolefin‐Graphite Nanosheets Nanocomposites

Homo and copolymers of metallocenic poly(propylene) with 1‐hexene and 1‐octadecene are used to prepare nanocomposites via melt mixing by using graphite nanosheets (GNSs) as filler. Different amounts of GNSs are used in order to study the influence of the filler on the thermal, mechanical, and electrical properties of nanocomposites. Significant changes have been observed in the crystallization temperature (T_c) of the nanocomposites. Thermogravimetric analysis shows improvement in thermal stability. Young's modulus and elongation at break of the nanocomposites are depended on the type of the matrix and the amount of GNSs. Materials with high flexibility are obtained in the cases of matrices based on copolymers even at high filler loading. Nanocomposites have become a semiconductor material reaching conductivity of 10^?4 S cm^?1. Two different thermal treatments have been applied in the preparation of the films by compression molding. X‐ray diffraction analysis shows the existence of polymorphism according to the thermal treatment applied.

     

Passive optical remote sensing of river channel morphology and in-stream habitat: Physical basis and feasibility

Successful monitoring of ecologically significant, vulnerable fluvial systems will require improved quantitative techniques for mapping channel morphology and in-stream habitat. In this study, we assess the ability of remote sensing to contribute to these objectives by (1) describing the underlying radiative transfer processes, drawing upon research conducted in shallow marine environments; (2) modeling the effects of water depth, substrate type, suspended sediment concentration, and surface turbulence; (3) quantifying the limitations imposed by finite detector sensitivity and linear quantization; and (4) evaluating two depth retrieval algorithms using simulated and field-measured spectra and archival imagery. The degree to which variations in depth and substrate can be resolved depends on bottom albedo and water column optical properties, and scattering by suspended sediment obscures substrate spectral features and reduces the resolution of depth estimates. Converting continuous radiance signals to discrete digital numbers implies that depth estimates take the form of contour intervals that become wider as depth increases and as bottom albedo and detector sensitivity decrease. Our results indicate that a simple band ratio can provide an image-derived variable that is strongly linearly related to water depth across a broad range of stream conditions. This technique outperformed the linear transform method used in previous stream studies, most notably for upwelling radiance spectra [R²=0.79 for the ln(560 nm/690 nm) ratio]. Applied to uncalibrated multispectral and hyperspectral images of a fourth-order stream in Yellowstone National Park, this flexible technique produced hydraulically reasonable maps of relative depth. Although radiometric precision and spatial resolution will impose fundamental limitations in practice, remote mapping of channel morphology and in-stream habitat is feasible and can become a powerful tool for scientists and managers.     

Induction cisplatin/vinblastine and irradiation vs. irradiation in unresectable squamous cell lung cancer: failure patterns by cell type in RTOG 88-08/ECOG 4588. Radiation Therapy Oncology Group. Eastern Cooperative Oncology Group

PURPOSE: To analyze disease failure patterns by pretreatment characteristics and treatment groups in a prospective randomized trial. METHODS AND MATERIALS: Patients with medically inoperable Stage II, unresectable IIIA and IIIB nonsmall cell lung cancer with KPS > or =70 and weight loss < or =5% were randomized to one of three treatment groups: standard radiation therapy with 60 Gy at 2.0 Gy per day (STD RT), induction chemotherapy with cisplatin 100 mg/m2 days 1 and 29 with vinblastine 5 mg/m2 weekly for 5 weeks followed by 60 Gy at 2.0 Gy per day (CT + RT), or hyperfractionated radiation therapy with 69.6 Gy at 1.2 Gy b.i.d. (HFX RT). Of 490 patients enrolled, 458 were evaluable. Minimum and median periods of observation for this analysis were 4 years and 6 years, respectively. RESULTS: Pretreatment characteristics were equally distributed. Toxicities were previously reported. Median survival rates were 11.4, 13.6, and 12.3 months for STD RT, CT + RT, and HFX RT, respectively (log rank p = 0.05, Wilcoxon p = 0.04). Survivals were 20, 31, and 24% at 2 years, and 4, 11, and 9% at 4 years in the STD RT, CT + RT, and HFX RT groups, respectively. There were no differences in local tumor control rates among the treatments. Patterns of first failure showed less distant metastasis (DM) (other than brain) for CT + RT compared to the RT alone arms (p = 0.04). Within squamous cell carcinoma (SCC), DM (other than brain) rates were 43%, 16%, and 38% in SCC for STD RT, CT + RT, and HFX RT, respectively (p = 0.0015). Patients with peripheral/chest wall lesions were significantly more likely to fail first in the thorax when treated on STD RT compared to CT + RT and HFX RT (p = 0.009). Survival rates were similar among the treatment arms for patients with squamous cell carcinoma. Among patients with nonsquamous cell carcinoma, failure patterns did not differ by treatment group, but survival was significantly better in those who were treated by induction chemotherapy (p = 0.04). CONCLUSION: Patients with squamous cell carcinoma treated on the CT + RT arm had a significant reduction of first DM other than brain, but there was difference in survival. Survival favored CT + RT in nonsquamous carcinoma despite similar failure patterns. Reasons for improved survival with CT + RT in NSCLC are not yet available.     

Modelling with stakeholders to integrate biodiversity into land-use planning – Lessons learned in Réunion Island (Western Indian Ocean)

This paper considers participatory modelling to integrate biodiversity conservation into land use planning and to facilitate the incorporation of ecological knowledge into public decision making for spatial planning. Réunion Island has experienced rapid urban and agricultural expansion, which threaten its unique biodiversity. In this context, we designed three participatory modelling sequences, involving overall 24 multidisciplinary researchers and stakeholders. The sequences aimed: (1) to map land-use and biodiversity, (2) to develop a conservation plan following systematic conservation planning principles using a spatial optimization tool (MARXAN) and (3) to simulate coupled land-use/conservation scenarios using a multi-agent system (MAS). The conservation plan confirms that priority areas for biodiversity protection are located on the coast where rapid land-use changes occur. Nevertheless, stakeholders from the urban and agricultural sector did not participate to this sequence. Indeed, conservation planning tools are useful to locate conservation priorities but they have to be designed with stakeholders to be accepted as negotiation tool. Besides, the researchers engaged in this second sequence were perceived as conservation stakeholders rather than holders of scientific knowledge. In the third sequence, the researchers involved adopted the stance of facilitating the elicitation of each stake and gathered trust from stakeholders. Overall, we conclude that the participatory development of land-use simulation models should be promoted to explore alternative scenarios for biodiversity conservation with stakeholders. In a situation of land-use conflict, a gradual and sequential participatory modelling approach should be implemented to fit into public decision-making processes.     

Geared robot manipulators with a jointed unit: Kinematic analysis and its application

An efficient and systematic methodology for the kinematic analysis of geared robot manipulators (GRMs) with a jointed unit is presented. It is shown that, by decomposing mechanical transmission lines of a GRM into serially connected jointed and disjointed units, kinematic relation between local inputs and local outputs of admissible jointed units can be systematically formulated. Accordingly, angular displacements of input links with respect to their associated primary links can be symbolically expressed in terms of joint angles by a unit‐by‐unit evaluation procedure. This unit‐by‐unit evaluation procedure provides better kinematic insights into how input torques are transmitted to various joints. It is also shown that an actuator in a GRM with a jointed unit can drive nonconsecutive joints by proper design of its gear train. A 3 degrees of freedom GRM with a jointed unit is used as an illustrative example. © 2001 John Wiley & Sons, Inc.     

Millets as potential nutri-cereals: a review of nutrient composition,phytochemical profile and techno-functionality

Millets are sustainable drought-resistant crops capable of surviving a wide range of climatic conditions. They are small-seeded grains rich in proteins, minerals and bioactive compounds inducing several health benefits and provide protection against chronic and degenerative modern lifestyle disorders. Hypoglycaemic profile and bioactive composition are the key elements for the popularity of millets as functional ingredients for the development of novel food products of commercial importance. Despite numerous health benefits and agro-economic potential, millets have lost their popularity due to coarse nature and are underutilised in developed countries. Food scientists and nutritionists are characterising and valorising millets to enhance their use for food applications. The present article reviews research investigations about nutritional composition (macro- and micro-nutrients), biologically active components (phenolic acid, flavonoids, phytosterols and related antioxidant potential) and techno-functionality of millets. Pharmacological impact and their utilisation in value-added products have also been included.     

Electrical conduction in light rare-earth tungstates

This paper reports the results of electrical conductivity (σ) and thermoelectric power (H) of light rare-earth tungstates in the temperature range 600–1200K. Holes are the dominant charge carriers over the whole studied temperature range for Nd, Sm and Gd tungstates. However, in the case of La, Ce and Pr tungstates, the conduction is dominated by electrons at lower temperatures, but above 950K in La, 800K in Ce and 950K in Pr the dominant charge carriers become holes. A sharp break and change in the log σ vs 1/T slope occurs in La, Ce and Pr tungstates around the same temperature at which the dominant charge carrier changes from electrons to holes. In the case of Nd, the conductivity anomaly occurs around 1020K without any change in the nature of the charge carrier. The data have been analysed using band theory.