Surface Morphology of Heat-Treated Ceramic Thin Films

The morphology of surfaces of several ceramic materials has been examined using transmission electron microscopy. The approach used was to prepare a sample for examination in the microscope, carefully clean it, and then heat-treat it. In the case of the oxides studied (alumina and spinel) the samples were heated in air; the non-oxides (α-SiC and β -SiC) were annealed under vacuum. The morphology in all but one case was such that the surface faceted parallel to the nearest low-index plane to give well-defined terraces; these were separated by ledges which also tended to facet parallel to the traces of low-index planes. The exception was the {1100} alumina surface, which appears to be unstable in air at temperatures close to 1400°C. A computer program using a multislice approach was used to estimate the height of the steps on the (0001) surface; the step heights appear to be multiples of the c lattice parameter. A reconstruction of this surface as a result of this heat treatment is also proposed.     

Preparation of V/ZrO2 catalysts by the sol-gel method: Physical and structural characterization

Some zirconia-supported vanadium oxides have been prepared by sol-gel method and characterized by different techniques. The vanadium content exerts an effect on the area and pore-size of precursors and samples calcined. The presence of vanadium also affects the decomposition of precursors into ZrO₂ and to its phase transformation, as well as the formation of fibres, as shown by SEM-EDX. XPS analyses show the presence of two species of vanadium at the surface, V^5– and V⁴⁺, the percentage of each one depending on the load of vanadium in the catalyst.     

Study on phase behavior–impact strength relationship of unsaturated polyester/polyurethane hybrid polymer network

The phase behavior of a hybrid polymer network (HPN) composed of poly[(propylene glycol maleate)-co-(propylene glycol phthalate)] crosslinked with styrene and polyester–urethane crosslinked with methylene-bis-ortho-chloroaniline was examined. The correlation between phase separation and impact strength of the HPNs is discussed. The composition of HPNs has an effect on their properties.     

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