Engineering Aspects of the Integration of Chemical and Biological Oxidation: Simple Mechanistic Models for the Oxidation Treatment

Oxidation processes can oxidize biorecalcitrant compounds into biodegradable intermediates, which in turn can be treated less expensively by a subsequent biological process. To design such a two-step (chemical+biological) process to treat poorly characterized wastewaters, it is useful to model the time evolution of characteristic global variables, chemical oxygen demand (COD) and biochemical oxygen demand (BOD), in order to develop a useful treatment strategy based upon these classical variables. We consider two simple model reaction networks, requiring three- and five-rate constants, respectively. The first model, proposed recently, involves conversion of a nonbiodegradable species, C, into a single biodegradable intermediate S. Here, biodegradable compounds are immediate kinetic products of oxidation. In general, it is not probable that a single recalcitrant compound undergoes a single-step reaction to CO2. However, when working with complex undefined wastewaters streams, single-step reactions may be used to simplify. The second new model corresponds to a lag time in BOD formation due to the necessity of multiple partial oxidations to reach a first biodegradable intermediate. The second network includes two intermediates, I and S, which are, respectively, nonbiodegradable and biodegradable. We then compare model behavior with an unfortunately sparse literature on BOD and COD values versus time in chemical reactors, and demonstrate the convenience of the first model, and the occasional necessity of the second, which reflects the presence of early intermediates which are nonbiodegradable.     

Trajectories of Alcohol and Drug Use and Dependence From Adolescence to Adulthood: The Effects of Familial Alcoholism and Personality.

This study describes trajectories of substance use and dependence from adolescence to adulthood. Identified consumption groups include heavy drinking/heavy drug use, moderate drinking/experimental drug use, and light drinking/rare drug use. Dependence groups include alcohol only, drug only, and comorbid groups. The heavy drinking/heavy drug use group was at risk for alcohol and drug dependence and persistent dependence and showed more familial alcoholism, negative emotionality, and low constraint. The moderate drinking/experimental drug use group was at risk for alcohol dependence but not comorbid or persistent dependence and showed less negative emotionality and higher constraint. Familial alcoholism raised risk for alcohol and drug use and dependence in part because children from alcoholic families were more impulsive and lower in agreeableness. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Twelve-Week Outcomes From an Investigation of High-Dose Nicotine Patch Therapy for Heavy Smokers With a Past History of Alcohol Dependence.

This study reports findings from an investigation of the efficacy of high-dose nicotine patch (NP) therapy for heavy smokers with a past history of alcohol dependence. One hundred thirty participants were randomly assigned to 42 mg or 21 mg of transdermal nicotine for 4 weeks, followed by an 8-week dose titration. Follow-up assessments were conducted at 4 and 12 weeks. Differences between dose conditions were nonsignificant, although unexpectedly, outcomes favored participants in the 21-mg NP condition. Nicotine abstinence at follow-up was related to longer length of alcohol abstinence at time of enrollment. Future research should investigate ways to improve smoking quit rates in this population, including more frequent counseling sessions and/or other pharmacotherapies. These investigations should focus primarily on smokers in early alcohol recovery. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Physical and Sexual Intimate Partner Violence Among Women in Methadone Maintenance Treatment.

Although several studies have examined the relationship between intimate partner violence (IPV) and drug use among women in drug treatment programs, more information is needed to delineate differences, as a function of the specific drug used. Data from a random sample of 416 women attending methadone programs were analyzed to elucidate the differential associations between IPV and use of the following: marijuana only, cocaine only, heroin only, or cocaine and heroin. Prevalence of IPV among this sample far exceeded estimates from the general population. After adjusting for sociodemographic variables, use of cocaine only was significantly associated with an increased likelihood of experiencing IPV compared with no drug use. Similar results were found for women using both cocaine and heroin. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Theories of Conditional Reasoning: A Developmental Examination of Competing Hypotheses.

Children and adolescents were presented with problems that contained deontic (i.e., if action p is taken, then precondition q must be met) or causal (i.e., if event p occurs, then event q will transpire) conditionals and that varied in the ease with which alternative antecedents could be activated. Results showed that inferences were linked to the availability of alternative antecedents and the generation of "disabling" conditions (claims that the conditionals were false under specific circumstances). Age-related developments were found only on problems involving indeterminate inferences. Correlations among inferences differed for children and adolescents. The findings provide stronger support for domain-general theories than for domain-specific theories of reasoning and suggest, under some conditions, age-related changes in the roles of implicit and explicit processing. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Flux, Pulse, and Spin: Dynamic Additions to the Personality Lexicon.

Personality constructs were proposed to describe intraindividual variability in interpersonal behavior. Flux refers to variability about an individual's mean score on an interpersonal dimension and was examined for the 4 poles of the interpersonal circumplex. Pulse and spin refer to variability about an individual's mean extremity and mean angular coordinate on the interpersonal circumplex. These constructs were measured using event-contingent recording. Latent state-trait analyses indicated high stability of flux in submissive, agreeable, and quarrelsome behaviors and some stability in the flux of dominance. Further analyses indicated moderate to high stability in pulse and spin. Neuroticism predicted greater pulse, spin, and submissive behavior flux. Extraversion predicted greater flux in agreeable behavior. In contrast, Agreeableness predicted reduced spin and quarrelsome behavior flux. Social environmental variables predicted greater flux in dominant behavior. Flux, pulse, and spin provide reliable and distinctive additions to the vocabulary for describing individual differences. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Is the Context Shift Effect a Case of Retrieval Failure? The Effects of Retrieval Enhancing Treatments on Forgetting Under Altered Stimulus Conditions in Rats.

This series of experiments sought to clarify the role of retrieval failure in forgetting that results from a change in context between training and testing (the context shift effect [CSE]). Because spontaneous forgetting (SF) is generally considered to reflect a retrieval failure, the effects of three manipulations known to alleviate SF were examined on forgetting due to an explicit shift in context at a short delay (24 hr). Pretest exposure to a reminder treatment involving the reinforcer from training (Experiment 1), pretest amphetamine administration (Experiment 2), and overtraining (Experiment 3) alleviated both SF and the CSE, supporting the view that the CSE reflects a retrieval deficit. Implications for the context change account of SF are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Category Learning in Rhesus Monkeys: A Study of the Shepard, Hovland, and Jenkins (1961) Tasks.

In influential research, R. N. Shepard, C. I. Hovland, and H. M. Jenkins (1961) surveyed humans' categorization abilities using tasks based in rules, exclusive-or (XOR) relations, and exemplar memorization. Humans' performance was poorly predicted by cue-conditioning or stimulus-generalization theories, causing Shepard et al. to describe it in terms of hypothesis selection and rule application that were possibly supported by verbal mediation. The authors of the current article surveyed monkeys' categorization abilities similarly. Monkeys, like humans, found category tasks with a single relevant dimension the easiest and perceptually chaotic tasks requiring exemplar memorization the most difficult. Monkeys, unlike humans, found tasks based in XOR relations very difficult. The authors discuss the character and basis of the species difference in categorization and consider whether monkeys are the generalization-based cognitive system that humans are not. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Predicting Organizational Success within a Project-Based Joint Venture Alliance

Project-based joint ventures (a special type of alliance) are an often-used method to form competitive organizational structures in the global market; they allow participants to quickly assemble project-needed assets on a short-term basis without substantial investment. However, published discussions of joint ventures describe mixed success and focus on factors that affect the ventures after they are formed. This paper exposes factors, which may be observed at joint venture inception, that are predictive of organizational success within the joint venture. The survey research of U.S. architecture/engineering/construction (A/E/C) firms indicates that smaller partners in a joint venture experience more market growth and are more successful. Also, a firm with strength in legitimacy (client trust) is more likely to gain in short-term income but will likely suffer some long-term market loss in comparison to its less-legitimized partners. It is further concluded that culture match among partners plays a significant role in ensuring profitable joint venture returns.     

Optimal classification methods for mapping agricultural tillage practices

The classification of agricultural tillage systems has proven challenging in the past using traditional classification methods due to the similarity of spectral reflectance signatures of soils and senescent crop residues. In this study, five classification methods were examined to determine the most suitable classification algorithm for the identification of no-till (NT) and traditional tillage (TT) cropping methods: minimum distance (MD), Mahalanobis distance, Maximum Likelihood (ML), spectral angle mapping (SAM), and the cosine of the angle concept (CAC). A Landsat ETM+ image acquired over southern Michigan and northern Indiana was used to test these classification methods. Each classification method was validated with 293 ground truth sampling locations collected commensurate with the satellite overpass. Classification accuracy was then assessed using error matrix analysis, Kappa statistics, and tests for statistical significance. The results indicate that of the classification routines examined, the two spectral angle methods were superior to the others. The cosine of the angle concept algorithm outperformed all the other classification routines for tillage practice identification and mapping, yielding an overall accuracy of 97.2% (Kappa=0.959).