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A comparative study of high-temperature oxidation of Ni containing 1 at.% Cr and pure Ni was carried out. Instead of the conventional kinetics study using thermogravimetry, a microlithographic marker experiment was designed. Observation of the markers using cross-sectional TEM and SEM has revealed striking differences in the scale morphology, microstructures, and oxidation mechanisms between pure Ni and the Cr-doped Ni substrates. In particular, the results suggest that a small addition of Cr promotes significant inward transport of oxygen. Marker experiments revealed that NiO grown on pure Ni is wholly attributable to outward-cation diffusion. In contrast, NiO grown on Ni–1 at.% Cr exhibited formation of a substantial inner layer having a submicron grain size, established by the markers to have formed from oxygen ingress. For pure Ni, voids were observed to be distributed only within oxide grains. In contrast, for Ni containing 1 at.% Cr, elongated pores formed extensively along oxide-grain boundaries. Formation of new fine-grain oxide in these pores was observed to have sometimes completely resealed the void. It is, therefore, proposed that the transport of oxygen in the case of oxide scale grown on Ni–1 at.% Cr occurs via voids (pores) formed by vacancy coalescence at the grain boundaries.  相似文献   
24.
Pint  B. A.  Hobbs  L. W. 《Oxidation of Metals》2004,61(3-4):273-292
Y2O3-dispersed NiAl was produced by a powder-metallurgy process. By adding Y as an oxide dispersion (OD), problems with NiYx formation and internal oxidation were avoided. Short-term isothermal and cyclic-oxidation performance at 1200°–1500° C was compared to cast NiAl alloys with and without Zr. Results indicate that the Y2O3 addition was beneficial to scale adhesion and significantly modified the α-Al2O3 scale microstructure, similar to a Zr alloy addition. However, at 1400 and 1500° C, neither the Y2O3 or Zr additions changed the scale-growth rate, eliminated the formation of voids at the metal-scale interface or prevented scale spallation. These similarities in performance suggest that similar mechanisms occur when the reactive element is added as either an OD or an alloy addition.  相似文献   
25.
Abstract. A generalized autoregressive (GAR) process {Z ( t ) ; t = 0 , ±1, …} is defined to satisfy the recurrence relation Z(t) = Aθ (t)Z (t -l)+ u( t ), where {Aθ(t); t = 0,±1, …} is itself a stochastic process depending on a vector parameter θ and where {u( t ); t = 0, ±1, …} is white noise with Eu 2 ( t ) = a 2. This paper develops theory and methodology and implementing the class of GAR processes for time series modeling and forecasting. Conditions on the 'parameter process' { A θ ( t ); t = 0, ±1, …} are obtained for the existence of a GAR process; necessary and sufficient conditions on { Aθ ( t ) ; t = 0, ±1, …} for existence of a stationary GAR process are also obtained. Procedures are developed for computing maximum likelihood estimates of the parameters 0 and u2 and for computing the minimum mean squared error forecasts for GAR processes.  相似文献   
26.
Novel morphologies of activated carbons such as monolith, beads and fiber cloth can effectively capture organic vapors from industrial sources. These adsorbent materials are also unique because they can undergo direct electrothermal regeneration to recover the adsorbed organic vapors for potential re-use. This investigation compares and contrasts the properties of these adsorbents when using electrothermal-swing adsorption. The adsorption systems consisted of an organic vapor generation system, an electrothermal-swing adsorption vessel, a gas detection unit, and a data acquisition and control system. The activated carbon monolith (ACM) had the lowest pressure drop, highest permeability, highest electrical resistivity and lowest cost as compared to the activated carbon beads (ACB) and the activated carbon fiber cloth (ACFC). ACB had the largest throughput ratio and lowest length of unused bed as compared to the other adsorbents. However, ACFC had the largest adsorption capacity for toluene when compared to ACM and ACB. ACFC was also faster to regenerate and had a larger concentration factor than ACM and ACB. These results describe relevant physical, electrical, adsorption and cost properties for specific morphologies of the adsorbents to more effectively capture and recover organic vapors from gas streams.  相似文献   
27.
ABSTRACT

Because there are fewer tools available to probe the interactions therein, the effect of the fundamental chemistry of the organic diluent on solvent extraction equilibria has been under-characterized relative to the aqueous. As a result, diluents for solvent extraction are often selected for an application not for their utility as a medium for reaction, but for other (often equally) important reasons (like low flammability). To begin to improve this imbalance in the science, twenty different diluents have been used in a study of the extraction of radiotracer 152/154Eu3+ from dilute nitric acid solutions using the extractant 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (HEH[EHP]). To increase the utility of the study and to honor the memory of Professor Jan Rydberg, this investigation was conducted by a cadre of comparatively inexperienced separation scientists (who are as a result no longer inexperienced separation scientists) as a radioanalytical chemistry and solvent extraction educational exercise. Slope analysis was used to determine the apparent stoichiometry of the extracted metal complex. The results discussed in the following indicate that, while the pH dependence exhibits the expected three H+ exchanged per metal ion extracted, the extractant dependence suggests that the number of protonated extractant molecules in the extracted complex changes with the organic diluent. The experimentally observed “extractant dependency” ranges from 2.5 to 3.0 dimer equivalent molecules per extracted metal ion. Ironically, in the diluents exhibiting the highest apparent M:(HA)3 stoichiometry, HEH[EHP] extracts Eu3+ less efficiently. Europium luminescence spectroscopy was used to probe for changes in the first coordination sphere of the complex in different diluents. A model and conceptual framework for understanding these observations is described.  相似文献   
28.
In this study, biobased polyester-ether polyols derived from meso-lactide and dimer acids were evaluated for flexible polyurethane foams (PUF) applications. Initially, the catalyst concentration was optimized for the biobased PUF containing 30% of biobased polyol (70% petroleum-based polyol). Then, the same formulation was used for biobased PUF synthesis containing 10%–40% of biobased polyols. The performance of biobased PUF was compared with the performance of the control foam made with 100% petroleum-based polyol. The characteristic times (cream, top of the cup, string gel, rise, tack-free) of biobased PUF were determined. The biobased PUF were evaluated for the mechanical (tensile and compressive) and morphological properties. As the wet compression set is important for automotive applications, it was measured for all biobased PUF. The thermal degradation behavior of biobased PUF was also evaluated and compared with the control foam. The effect of different hydroxyl and acid values of polyols on the mechanical properties of biobased PUF is also discussed. The miscibility of all components of PUF formulations is crucial in order to produce a foam with uniform properties. Thus, the miscibility of biobased polyols with commercial petroleum-based polyol was studied.  相似文献   
29.
Hypermedia technologies have been available for about a decade. Beginning with Douglas Engelbart, researchers have become interested in applying hypermedia concepts and technologies to software development. This paper assesses this symbiosis between hypermedia and software development as described by research contributions; by our count, more than one hundred articles. To date, no collection of, or guide to, this literature has been published. A number of significant contributions are classified, described, and appraised — providing a guide into what has been a rich but perhaps under-reported research area. Hypermedia has made significant contributions to software development in three primary areas: coping with massive amounts of information associated with software development projects; establishing and maintaining linkages between various types of software engineering documents; and enabling development engineers to record, document, and preserve knowledge about development thoughts, processes and rationale. These contributions may help direct the focus of future research towards building on, combining and assessing the resulting contributions. A research agenda is proposed along these lines.  相似文献   
30.
Organizations today face shortages of IT personnel. We investigated workplace factors in one state government in hope of identifying factors that influence perceived organizational support (POS) within an IT work environment. A combination of job characteristics (challenging job and perceived workload), job stressors (work exhaustion, role conflict, and role ambiguity), and the organization’s discretionary actions (pay-for-performance and mentoring opportunities) were measured and hierarchical regression was used to determine the relationships. Four control variables were also included (age, gender, organizational tenure, and professional versus administrator status). Role ambiguity, role conflict, work exhaustion, career mentoring, and pay-for-performance together explained 62% of the variance in the IT employees’ POS. Career mentoring and role ambiguity explained most of the variance.  相似文献   
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