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991.
The surface energy and surface stability of Ag nanocrystals (NCs) are under debate because the measurable values of the surface energy are very inconsistent, and the indices of the observed thermally stable surfaces are apparently in conflict. To clarify this issue, a transmission electron microscope is used to investigate these problems in situ with elaborately designed carbon‐shell‐capsulated Ag NCs. It is demonstrated that the {111} surfaces are still thermally stable at elevated temperatures, and the victory of the formation of {110} surfaces over {111} surfaces on the Ag NCs during sublimation is due to the special crystal geometry. It is found that the Ag NCs behave as quasiliquids during sublimation, and the cubic NCs represent a featured shape evolution, which is codetermined by both the wetting equilibrium at the Ag–C interface and the relaxation of the system surface energy. Small Ag NCs (≈10 nm) no longer maintain the wetting equilibrium observed in larger Ag NCs, and the crystal orientations of ultrafine Ag NCs (≈6 nm) can rotate to achieve further shape relaxation. Using sublimation kinetics, the mean surface energy of Ag NCs at 1073 K is calculated to be 1.1–1.3 J m?2.  相似文献   
992.
993.
A cobalt-silica hybrid nanocatalyst bearing small cobalt particles of diameter ~5 nm was prepared through a hydrothermal reaction and hydrogen reduction.The resulting material showed very high CO conversion (>82%) and high hydrocarbon productivity (~1.0 gHc·g-1cat,·h-11) with high activity (~8.5 x 10-5 molco·g-1Co·S-1) in the Fischer-Tropsch synthesis reaction.  相似文献   
994.
Yu  Huijuan  Li  Hanwen  Yuan  Shouyi  Yang  Yuchi  Zheng  Jiahui  Hu  Jianhua  Yang  Dong  Wang  Yonggang  Dong  Angang 《Nano Research》2017,10(7):2495-2507
Mesoporous carbons have been widely utilized as the sulfur host for lithium-sulfur (Li-S) batteries.The ability to engineer the porosity,wall thickness,and graphitization degree of the carbon host is essential for addressing issues that hamper commercialization of Li-S batteries,such as fast capacity decay and poor high-rate performance.In this work,highly ordered,ultrathin mesoporous graphitic-carbon frameworks (MGFs) having unique cage-like mesoporosity,derived from self-assembled Fe3O4 nanoparticle superlattices,are demonstrated to be an excellent host for encapsulating sulfur.The resulting S@MGFs exhibit high specific capacity (1,446 mAh·g-1 at 0.15 C),good rate capability (430 mAh.g-1 at 6 C),and exceptional cycling stability (~0.049% capacity decay per cycle at 1 C) when used as Li-S cathodes.The superior electrochemical performance of the S@MGFs is attributed to the many unique and advantageous structural features of MGFs.In addition to the interconnected,ultrathin graphitic-carbon framework that ensures rapid electron and lithium-ion transport,the microporous openings between adjacent mesopores efficiently suppress the diffusion of polysulfides,leading to improved capacity retention even at high current densities.  相似文献   
995.
Two-dimensional layers of metal dichalcogenides have attracted much attention because of their ultrathin thickness and potential applications in electronics and optoelectronics.Monolayer SnS2,with a band gap of ~2.6 eV,has an octahedral lattice made of two atomic layers of sulfur and one atomic layer of tin.Till date,there have been limited reports on the growth of large-scale and high quality SnS2 atomic layers and the investigation of their properties as a semiconductor.Here,we report the chemical vapor deposition (CVD) growth of atomic-layer SnS2 with a large crystal size and uniformity.In addition,the number of layers can be changed from a monolayer to few layers and to bulk by changing the growth time.Scanning transmission electron microscopy was used to analyze the atomic structure and demonstrate the 2H stacking poly-type of different layers.The resultant SnS2 crystals is used as a photodetector with external quantum efficiency as high as 150%,suggesting promise for optoelectronic applications.  相似文献   
996.
Carbon-coated SiC@C nanocapsules (NCs) with a hexagonal platelet-like morphology were fabricated by a simple direct current (DC) arc-discharge plasma method.The SiC@C NCs were monocrystalline,120-150 nm in size,and approximately 50 nm thick.The formation of the as-prepared SiC@C NCs included nucleation of truncated octahedral SiC seeds and subsequent anisotropic growth of the seeds into hexagonal nanoplatelets in a carbon-rich atmosphere.The disordered carbon layers on the SiC@C NCs were converted into SiO2 shells of SiC@SiO2 NCs by heat treatment at 650 ℃ in air,during which the shape and inherent characteristics of the crystalline SiC core were obtained.The interface evolution from carbon to SiO2 shells endowed the SiC@SiO2 NCs with enhanced photocatalytic activity due to the hydrophilic and transparent nature of the SiO2 shell,as well as to the photosensitive SiC nanocrystals.The band gap of the nanostructured SiC core was determined to be 2.70 eV.The SiC@SiO2 NCs degraded approximately 95% of methylene blue in 160 min under visible light irradiation.  相似文献   
997.
998.
999.
Under abnormal conditions, timely and effective decisions of system recovery and protective measures are of great significance for safety‐critical systems. The knowledge of the roles that network nodes play in the spreading process is crucial for developing efficient maintenance decisions; for singling out and preferential control, the ‘pivotal spreaders’ may be a way to maximize the chances to timely hinder the fault pervasion. Inspired by the inhomogeneous topological nature of a complex fault propagation network, this study is devoted to exploring the spreading capabilities of nodes regarding both structural connectivity and causal influence strength, so as to provide decisions of preferential recovery actions under specific fault scenarios. Specifically, the dynamic betweenness centrality and nonsymmetrical entropy are incorporated to adaptively measure the system‐wide fault diffusion risk of a set of controllable fault events. In order to model the dynamics and uncertainties involved in the complex fault spreading process, we introduce the model of a dynamic uncertain causality graph, based on which solutions of time‐varying structure decomposition and causality reduction are adopted to improve the reasoning efficiency. Verification experiments consisting of simulated calculation cases and generator faults of a nuclear power plant show empirically the effectiveness and applicability of this method in large‐scale engineering practice. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   
1000.
This paper presents a reliability analysis method on repairable system with standby structure based on goal oriented (GO) methodology. Firstly, a new combination of GO operator, which is composed of a new logical GO operator named Type 18A operator and a new auxiliary GO operator named Type 20 operator, is created to represent standby mode. The availability formula of standby equipment with translation exception is deduced based on Markov process theory. Then, the application method of combination of GO operator for standby mode and the analysis process of repairable system with standby structure based on GO method are proposed. Thirdly, this new combination of GO operator is applied in availability analysis of the hydraulic oil supply system of power‐shift steering transmission. Finally, the results obtained by the new GO method are compared with the results of fault tree analysis, Monte Carlo simulation, GO methods using Type 2 operator and Type 18 operator to represent the standby mode, respectively. And the comparison results show that this new GO method is applicable and reasonable for reliability analysis of repairable system with standby structure. All in all, this paper provides guidance for reliability analysis of repairable systems with standby structure. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
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