Analysis of the Mechanical Stability of Boreholes Drilled in Sedimentary Rocks

This article presents the method and results of wellbore stability analysis for three common reservoir lithologies consisting of a consolidated sandstone, a shaly sandstone, and a limestone formation. The effect of stress anisotropy on the mechanical stability of wellbores is evaluated while varying the inclination angle from 0 to 90°, for both the Mohr-Coulomb and the Drucker-Prager failure criteria. The selected failure criterion, and the in-situ rock stress regime are found to have significant effects on the safe drilling fluid density required to maintain wellbore integrity. According to some field examples, the Drucker-Prager failure criterion appears to systematically mimic rock conditions more realistically than the Mohr-Coulomb failure criterion. The simulated consolidated sandstone formation is found more stable with lesser drilling fluid density, at any inclination angle, than the simulated shaly sandstone formation. The simulated limestone formation is even more stable than the consolidated sandstone at all inclination angles since it requires lighter fluid density to prevent wellbore collapse. For all these rock types, the higher the deviation angle (from vertical), the higher the drilling fluid density needed for maintaining wellbore integrity. For the depth and rock conditions simulated, both consolidated and shaly sands are unstable in a strike-slip stress regime, but stable in an extensional stress regime. The simulated limestone formation was found stable in both stress regimes. However, in an extensional stress regime, the limestone formation required lighter fluid density to maintain wellbore integrity than in a strike-slip stress regime. This article introduces the theory of using a practically-oriented model to assess the mechanical stability of a wellbore in a linearly-elastic stress field. The model can be used to determine the range of mechanically stable well inclinations for a given formation, and to suggest drilling-fluid density programs tailored to efficient and safe drilling.     

Anti-GBM glomerulonephritis in mice lacking nitric oxide synthase type 2

To determine the relationship between quantitative Doppler parameters of portal, hepatic, and splanchnic circulation and hepatic venous pressure gradient (HVPG), variceal size, and Child-Pugh class in patients with alcoholic cirrhosis, we studied forty patients with proved alcoholic cirrhosis who underwent Doppler ultrasonography, hepatic vein catheterization, and esophagoscopy. The following Doppler parameters were recorded: time-averaged mean blood velocity, volume flow of the main portal vein flow, and resistance index (RI) of the hepatic and of the superior mesenteric artery. Doppler findings were compared with HVPG, presence and size of esophageal varices, and Child-Pugh class. There was a significant inverse correlation between portal velocity and HVPG (r = -.69), as well as between portal vein flow and HVPG (r = -.58). No correlation was found between RI in the hepatic artery or superior mesenteric artery and HVPG. No correlation was found between portal vein measurements and presence and size of varices. Severe liver failure was associated with lower portal velocity and flow. In patients with alcoholic cirrhosis, only portal vein blood velocity and flow, but neither hepatic nor mesenteric artery RI, are correlated to the severity of portal hypertension and to the severity of liver failure.     

Solving partial differential equations of gas–solid reactions by orthogonal collocation

In this work the solution of the coupled partial differential equations for noncatalytic gas–solid reactions has been considered by orthogonal collocation. First of all, by an integral transformation and then by applying the orthogonal collocation method, these partial differential equations are converted to the ordinary differential equations. Then the equations are solved and the conversion–time profiles are obtained. The solution of the equations for volume reaction model, grain model and grain model with product layer resistance, modified grain model, random pore model, nucleation model and reaction of two gas with one solid has been presented in this work. The orthogonal collocation is a rapid method for solving of these equations and shows a good accuracy with respect to other solution techniques in the literature.     

Kinetic modeling and thermodynamic study to remove Pb(II), Cd(II), Ni(II) and Zn(II) from aqueous solution using dead and living Azolla filiculoides

Dead Azolla filiculoides can remove Pb(2+),Cd(2+), Ni(2+) and Zn(2+) corresponding to second-order kinetic model. The maximum adsorption capacity (Q(max)) to remove these metal ions by the alkali and CaCl(2)/MgCl(2)/NaCl (2:1:1, molar ratio) activated Azolla from 283 to 313K was 1.431-1.272, 1.173-0.990, 1.365-1.198 and 1.291-0.981mmol/g dry biomass, respectively. Q(max) to remove these heavy metals by the non-activated Azolla at the mentioned temperature range was obtained 1.131-0.977, 1.092-0.921, 1.212-0.931 and 1.103-0.923mmol/g dry biomass, respectively. In order to remove these metal ions by the activated Azolla, the enthalpy change (DeltaH) was -4.403, -4.495, -4.557 and -4.365kcal/mol and the entropy change (DeltaS) was 2.290, 1.268, 1.745 and 1.006cal/molK, respectively. While, to remove these metal ions by the non-activated Azolla, DeltaH was -3.685, -3.766, -3.967 and -3.731kcal/mol and DeltaS was 2.440, 1.265, 1.036 and 0.933cal/molK, respectively. On the other hand, the living Azolla removed these heavy metals corresponding to first-order kinetic model. It was also shown that pH, temperature and photoperiod were effective both on the rate of Azolla growth and the rate of heavy metals uptake during 10 days. It was appeared the use of Ca(NO(3))(2) increased both Azolla growth rate and the rate of heavy metals uptake while the using KNO(3) although increased Azolla growth rate but decreased the rate of heavy metals uptake.     

Preformed particle gels of sulfonated polyacrylamide: preparation,characterization, and application as permeability modifier

In this study, a preformed particle gel (PPG) was synthesized from sulfonated polyacrylamide and chromium metal cross-linker with specific concentration. The main characteristics of PPG, such as gelation time, gel fraction, swelling properties and salt sensitivity factor were investigated. The gel fraction of 94.1% practically indicated an appropriate conversion of gelant to the gel. The equilibrium swelling ratios of particle gels in distilled water and formation water at 80 °C were 470.49 and 12.61, respectively. Additionally, the rheological properties of gel were studied by a dynamic rheometer. The ultimate storage modulus of gel was measured 35.4 kPa. The linear viscoelastic behavior was observed at strain between 1 and 82.6% and gel structure was stable up to strain of 1120% with small reduction of storage modulus. The kinetics of gelation were also studied at different temperatures and tested against Avrami equation to determine the kinetic parameters. The Avrami exponents for two kinetic steps were about 2.29 and 0.80, respectively, indicating the rapid formation of the gel network at first step due to nucleation and two-dimensional growths of gel nuclei. Furthermore, a core flooding experiment was conducted to study PPG performance in porous media. The residual resistance factor of water and oil was 41.58 and 12.91, respectively. A value of 3.22 for the ratio of these two factors indicated the ability of the synthesized PPG to decrease water-effective permeability compared to oil-effective permeability in porous media.

     

Novel CPG algorithm for tracking fast sudden changes based on tangent rule

ABSTRACT

This paper proposes a novel tracking method to deal with fast changes of solar irradiation and power limit change in order to increase tracking efficiency. This goal is achieved by estimating (i) next operating mode and (ii) next step point with the use of tangent rule in triangle. After every fast response to sudden changes, accurate response phase starts in order to track desired power in each operating mode by adaptive step size. Drift problem in defining next operating mode is eliminated in proposed method by estimating next operating mode, and settling time is decreased to about 25 percent of settling time of other methods by estimating next step point. Simulation and experimental results show the performance of proposed method.     

Preparation of Electrolytic Quasi-Solid-State Nanofibers for Dye-Sensitized Solar Cells

JOM - Nanofibers were prepared from a poly(acrylonitrile-co-vinyl acetate) [P(AN-co-VAC)]/polyvinylidene fluoride (PVDF) blend and used as a quasi-solid (QS) electrolyte for dye-sensitized solar...     

The impact of alphabet size on pattern complexity of maxmin-$$\omega$$ω cellular automata

Natural Computing - We present an analysis of an additive cellular automaton (CA) under asynchronous dynamics. The asynchronous scheme is maxmin-$$\omega$$, a deterministic system, introduced in...