Silicene Nanoribbons on an Insulating Thin Film

Silicene, a new 2D material has attracted intense research because of the ubiquitous use of silicon in modern technology. However, producing free-standing silicene has proved to be a huge challenge. Until now, silicene could be synthesized only on metal surfaces where it naturally forms strong interactions with the metal substrate that modify its electronic properties. Here, the authors report the first experimental evidence of silicene nanoribbons on an insulating NaCl thin film. This work represents a major breakthrough, for the study of the intrinsic properties of silicene, and by extension to other 2D materials that have so far only been grown on metal surfaces.     

On the design of Robust‐WDM local area networks

Robust wavelength division multiplexing (Robust‐WDM) is a proposal to realize cost‐effective WDM local area networks (LANs) which can get around the expensive need for laser wavelength stabilization. The type of these networks that relies on an access protocol with aperiodic reservations and lenient‐token‐passing based control channel (the AR/LTP protocol) is promising. We look at the deployment of the AR/LTP analytical model in designing this type of network. The model is used to predict the effect of component and network parameters on the waiting time characteristics of the network. An increase in node operation times (i.e. receiver response time, transmitter select time and reservation period) would result in increasing the average waiting time of a connection request, but the waiting time is more sensitive to the physical span of the network and its size. It is also observed that increasing the inter‐reservation threshold may result in little increase in waiting time up to some limit beyond which delay increases rapidly. Copyright © 2001 John Wiley & Sons, Ltd.     

Average and randomized communication complexity

The communication complexity of a two-variable function f(x,y) is the number of information bits two communicators need to exchange to compute f when, initially, each knows only one of the variables. There are several communication-complexity measures corresponding to whether (1) the worst case or average number of bits is considered, (2) computation errors are allowed and (3) randomization is allowed. Tight bounds are provided for the typical behavior of all bounded-error communication-complexity measures of Boolean functions. In the present work, the authors formally define the deterministic model. They describe randomized protocols and compare them to deterministic ones. They both survey previous work and describe original results     

Remote‐Controlled Hydrogel Depots for Time‐Scheduled Vaccination

Remote‐controlled drug depots represent a highly valuable tool for the timely controlled administration of pharmaceuticals in a patient compliant manner. Here, the first pharmacologically controlled material that allows for the scheduled induction of a medical response in mice is described. To this aim, a novel, humanized biohybrid material that releases its cargo in response to a small‐molecule stimulus licensed for human use is developed. The functionality of the material in mice is demonstrated by the remote‐controlled delivery of a vaccine against the oncogenic human papillomavirus type 16. It is shown that the biohybrid depot‐mediated immunoprotection is equivalent to the classical multi‐injection‐based vaccination. These results indicate that this material can be used as a universal remote‐controlled vehicle for the patient‐compliant delivery of vaccines and pharmaceuticals.     

Supramolecular Assembly of Aminoethylene‐Lipopeptide PMO Conjugates into RNA Splice‐Switching Nanomicelles

Phosphorodiamidate morpholino oligomers (PMOs) are oligonucleotide analogs that can be used for therapeutic modulation of pre‐mRNA splicing. Similar to other classes of nucleic acid‐based therapeutics, PMOs require delivery systems for efficient transport to the intracellular target sites. Here, artificial peptides based on the oligo(ethylenamino) acid succinyl‐tetraethylenpentamine (Stp), hydrophobic modifications, and an azide group are presented, which are used for strain‐promoted azide‐alkyne cycloaddition conjugation with splice‐switching PMOs. By systematically varying the lead structure and formulation, it is determined that the type of contained fatty acid and supramolecular assembly have a critical impact on the delivery efficacy. A compound containing linolenic acid with three cis double bonds exhibits the highest splice‐switching activity and significantly increases functional protein expression in pLuc/705 reporter cells in vitro and after local administration in vivo. Structural and mechanistic studies reveal that the lipopeptide PMO conjugates form nanoparticles, which accelerate cellular uptake and that the content of unsaturated fatty acids enhances endosomal escape. In an in vitro Duchenne muscular dystrophy exon skipping model using H2K‐mdx52 dystrophic skeletal myotubes, the highly potent PMO conjugates mediate significant splice‐switching at very low nanomolar concentrations. The presented aminoethylene‐lipopeptides are thus a promising platform for the generation of PMO‐therapeutics with a favorable activity/toxicity profile.     

CMOS RF switched capacitor bandpass filter tuned by ring VCO

A new RF switched capacitor bandpass filter and its command circuit made up of a ring voltage controlled oscillator with ‘XOR’ gates are proposed. Implemented in a standard CMOS technology, this circuit is intended to be used in a subset of professional mobile phone applications [380–520 MHz]. Experiments carried out on a prototype show a tunable center frequency range of 260 MHz [240–500 MHz], with a quality factor that can be as high as 300.     

Preliminary assessment of the stability of thin- and polymer thick-film resistors embedded into printed wiring boards

Embedding passive components into multilayer printed wiring boards (PWBs) meet electronic device requirements concerning the necessity of saving the surface board area for active elements, reducing board’s size, improving device functionality and safety as well as overall product cost reduction. Since embedded components cannot be replaced after the board is completed, a long term stability and reliability are the important concerns for manufactures.This paper presents the results of examinations of embedded thin-film NiP resistors and polymer thick-film resistors during their continuous operation and the influence of temperature on the resistance values after the simulation of a lead-free soldering process and after the temperature cycling test (?40 ?C/+85 ?C).     

<Emphasis Type="Italic">In Situ</Emphasis> Spectral Reflectance Investigation of InAs/GaAs Heterostructures Grown by MOVPE

Metalorganic vapor-phase epitaxy of InAs/GaAs heterostructures was monitored in situ by spectral reflectance in the wavelength range from 600 nm to 1000 nm. Three-dimensional (3D) plots of reflectivity as a function of time and wavelength were used to determine the growth rate evolution. Theoretical simulation of reflectivity signals was carried out by combining a transfer matrix method and a multi-sublayer model. In spite of fixed growth parameters, there was temporal variation of the growth rate. By adjusting simulated reflectivity curves, optical constants of the InAs layer at 450°C were determined. The E ₁ critical point energy was also found experimentally at this temperature. Good agreement with calculated values is obtained.     

Direction of Arrival Estimation using EM-ESPRIT with Nonuniform Arrays

This paper deals with the problem of the Direction Of Arrival (DOA) estimation with nonuniform linear arrays. The proposed method is based on the Expectation Maximization method where ESPRIT is used in the maximization step. The key idea is to iteratively interpolate the data to a virtual uniform linear array in order to apply ESPRIT to estimate the DOA. The iterative approach allows one to improve the interpolation using the previously estimated DOA. One of this method’s novelties lies in its capacity of dealing with any nonuniform array geometry. This technique manifests significant performance and computational advantages over previous algorithms such as Spectral MUSIC, EM-IQML and the method based on manifold separation technique. EM-ESPRIT is shown to be more robust to additive noise. Furthermore, EM-ESPRIT fully exploits the advantages of using a nonuniform array over a uniform array: simulations show that for the same aperture and with a smaller number of sensors, the nonuniform array presents almost identical performance as the equivalent uniform array.     

Optimized ITO-free tri-layer electrode for organic solar cells

The optical properties of ZnO/Ag/ZnO (ZAZ) multilayer structures were numerically modeled and calculated by a FDTD method. Such tri-layers were also manufactured using an ion beam sputtering plant. A good agreement is obtained between modelizations and realizations. The impact of the oxide thicknesses on the optical properties of the ZAZ structures were experimentally and numerically investigated, and allow us to adjust the spectral position of the transmission maximum. The transmission of these structures is optimized up to around 74%, on the whole absorption spectral range of the photoactive P3HT:PCBM bulk heterojunction. The best electrode design is glass/ZnO (30 nm)/Ag (14 nm)/ZnO (30 nm), which presents a sheet resistance of 7 Ω/□. The optimized ZAZ structure was successfully integrated in an organic solar cell as anode. A photovoltaic efficiency of 2.58% is obtained and is compared to an organic solar cell integrating a traditional ITO anode with an efficiency of 2.99%. Numerical calculations of the intrinsic absorption inside each layer of the organic solar cells are performed. Alternative ITO-free electrodes for organic solar cells are demonstrated.