Ammoniaksynthese als Beispiel einer stofflichen Nutzung von intermittierend erzeugtem Wasserstoff

Producing hydrogen‐rich chemicals, such as methane, ammonia or methanol, from renewable energy may foster the integration of renewables into the current energy system. Here, a flexible ammonia synthesis concept is introduced, which is then compared to the widely discussed power‐to‐gas concepts on a technical and economic level. The current ammonia prices result in comparably high hydrogen‐specific revenues, which imply the ability to operate the system more profitable under fluctuating electricity prices and thereby increase the plant capacity factor.     

Single and Polycrystalline Transparent Ceramic Armor with Different Crystal Structure

Contrary to the moderate ballistic advantage of Al₂O₃ ceramics over MgAl₂O₄ polycrystals, the present study shows a reverse ratio of the ballistic strength of alumina and spinel single crystals: Spinel single crystals outperform sapphire and exhibit a similarly high stability as submicrometer Al₂O₃ ceramics. The results correlate with different cleavage of single crystalline spinel and sapphire, changing the fragmentation on ballistic impact.     

Comparison of 3 Spectrophotometric Methods for Carotenoid Determination in Frequently Consumed Fruits and Vegetables

ABSTRACT: Carotenoids are C-40 tetraterpenoid compounds with potential health beneficial effects. Major dietary sources include a variety of fruits and vegetables. Rapid screening methods are therefore desired, but their accuracy varies depending on the carotenoid profile and the matrix of the plant food. In the present study, 3 different methods were compared, all based on a rapid extraction protocol and spectrophotometric measurements to determine the total amount carotenoids present in fruits and vegetables (n = 28), either with or without chlorophyll. Published methods (a) Lichtenthaler and (b) Hornero-Méndez and Mínguez-Mosquera were compared with a newly developed method (method c) based on the average molar absorption coefficient (135310 Lcm⁻¹mol⁻¹) and wavelength (450 nm in acetone), for the 5 predominant carotenoid species (beta-carotene, zeaxanthin, lycopene, lutein, beta-cryptoxanthin) in the investigated foods. All results were compared to HPLC (method d). To avoid overestimating carotenoid concentrations due to chlorophyll A and B presence, the effect of saponification was studied for all methods. Overall, saponification led to significant carotenoid losses (12.6 ± 0.9%). Methods a, b, c, and d yielded 5.1 ± 0.4 mg/100 g, 4.6 ± 0.5 mg/100 g, 4.3 ± 0.5 mg/100 g, and 4.2 ± 0.5 mg/100 g total carotenoids, respectively, with method a leading to significant higher mean concentrations compared to all other methods (P < 0.001, Bonferroni) with methods b and c being not significantly different and highly correlated compared to HPLC (> r = 0.95). Similar results were found when stratifying for chlorophyll content and fruits compared with vegetables, however, accuracy varied for individual fruits, highlighting the limitation to use the same method for all plant foods. Practical Application: This study presents a comparison of various rapid spectrophotometric measurements to determine total carotenoid content in various fruits and vegetables and could aid in the selection of the appropriate method for individual plant foods with different carotenoid profile and matrices.     

The influence of a corrosive wood-cutting environment on the mechanical properties of hardmetal tools

The influence of a corrosive wood-cutting environment on the strength of hardmetals and on their behaviour under static loading conditions has been investigated. Two commercial hardmetals were tested, which differed in hard phase composition. The results show exposure to this environment to have a highly detrimental influence on the strength of both hardmetals investigated, due to localised corrosive attack which results in the formation of stress raisers. The relative loss in strength as a function of corrosion time is the same for both hardmetals. However, the performance of the two grades differ significantly when a static load is applied in this corrosive environment: the strength of the WC-Co grade remains unaffected by the applied load, while the grade containing a mixed carbide phase exhibits stress corrosion cracking which results in a further reduction in strength.     

A Difference Reference Voltage Buffer for ΔΣ-Converters

An open loop architecture for a reference voltage buffer in -converters is presented to achieve fast-settling, since the settling time of the references plays an important role in the global performance of sampled data converters. This design has been tested on a 2-1 -converter with an on-chip bandgap reference increasing the input related dynamic range up to 93.4 dB for a bandwidth of 99 kHz.     

Cognitive Automation for Tactical Mission Management: Concept and Prototype Evaluation in Flight Simulator Trials

This paper describes an approach to cognitive and cooperative operator assistance in the field of tactical flight mission management. A framework for a generic functional concept is derived from general considerations of human performance and cognitive engineering. A system built according to these human-centred design principles will be able to keep up with the change of situation parameters, in order to provide situational adapted operator assistance. Such a cognitive assistant system represents an approach to ensure the highest degree possible of situation awareness of the flight deck crew as well as a satisfactory workload level. This generic approach to mission management and crew assistance for military aircraft has been realised in different application domains such as military transport and air-to-ground attack. The Crew Assistant Military Aircraft is a functional prototype for the air transport application. Even applications in the domain of uninhabited aerial vehicles (UAV) are in reach. This paper mainly covers one state-of-the-art research and development activity in the domain of combat aircraft: the TMM – Tactical Mission Management System is an experimental solution for the air-to-ground attack role. The TMM has been implemented as a functional prototype in the mission avionics experimental cockpit (MAXC), a development flight simulator at ESG and evaluated with German Air Force pilots as subjects in simulator trials. Therefore, the TMM has been compared with a reference cockpit avionics configuration in terms of task performance, workload, situation awareness and operator acceptance. After giving an overview of the system concepts this paper reports on the experimental design and results of the simulator trial campaign.     

Immunohistochemical video-microdensitometry of myocardial collagen type I and type III

Collagen is an essential part of the cardiac interstitium. Collagen subtypes, their location, total amount and the architecture of the fibrillar network are of functional importance. Architecture in terms of density of the fibrillar network is assumed to be reflected by the intensity of immunohistochemical staining of collagen. The aim of this study was to evaluate a video-based microdensitometric method for quantifying density expressed as absorbance of collagen subtypes I and III stained with an indirect immunoperoxidase method in myectomy specimens of patients with hypertrophic obstructive cardiomyopathy. Various factors influencing the immunohistochemical staining product and the technical properties of the image analysis system were investigated. Linearity between collagen concentration and the absorbance of the immunohistochemical staining product was demonstrated for collagen I using a dot-blot technique. Immunohistochemical collagen staining and density measurement were easily reproducible. The cardiac disability of the patients was assessed according to the New York Heart Association (NYHA) criteria. There was a significant increase in collagen type I density with higher NYHA class, whereas no significant association was found for total collagen area fraction. Thus, video-based microdensitometry gives further insight into the structural remodelling of myocardial collagens and reveals their significance in the process of heart failure in hypertrophic cardiomyopathy.     

Differential effects of prenatal stress in two inbred strains of rats

Glucagon-like peptide-1 (GLP-1) may be one of the enterogastrone hormones of the ileal brake mechanism. We therefore studied its effects on gastric lipase secretion in healthy volunteers and vagotomized patients during infusion of pentagastrin. The intestinal incretin hormone GLP-1 (glucagon-like peptide-1, 7-36 amide) was investigated because of its inhibitory effects on gastric acid secretion and motility. GLP-1 infused intravenously in amounts corresponding to the postprandial release significantly inhibited pentagastrin-stimulated gastric lipase secretion and lipolytic activity. The inhibitory effect of GLP-1 persisted in vagotomized patients, suggesting that fundic chief cells, from which gastric lipase is released, or neighboring inhibitory cells could be equipped with GLP-1 receptors. Vagotomized patients had significantly higher plasma concentrations of gastrin and secretin. No significant changes of gastrin, secretin, and CCK secretion were seen during GLP-1 infusion in the vagotomized patients, whereas secretin decreased significantly in the healthy volunteers. GLP-1 seems to be a naturally occurring inhibitor of gastric lipase secretion acting via a nonvagal mechanism. Our results indicate that gastric lipase secretion is subject to hormonal stimulatory as well as inhibitory mechanisms.     

Total and local heat transfer from a smooth circular cylinder in cross-flow at high reynolds number

The total and local heat transfer from a smooth circular cylinder to the cross flow of air has been measured over the Reynolds number range 3 × 10⁴ < Re < 4 × 10⁶. The interaction between flow and heat transfer is discussed. In particular, the boundary-layer effects on the heat transfer, such as transition from laminar to turbulent flow or boundary-layer separation, are considered in conjunction with the distributions of local static pressure and skin friction.