Effect of dopants on alumina grain boundary sliding: implications for creep inhibition

We investigate by means of periodic density functional theory the mechanism of grain boundary sliding along the α-alumina Σ11 tilt grain boundary. We identify minimum and maximum energy structures along a preferential sliding pathway for the pure grain boundary, as well as for grain boundaries doped with a series of early transition metals, as well as barium, gadolinium, and neodymium. We predict that the segregation of those dopants results in a considerable increase in the grain boundary sliding barrier. Grain boundary sliding occurs by a series of bond breaking and forming across the grain boundary. Our results suggest that the presence of large cations inhibits the regeneration of bonds during sliding, which results in a decrease in total number of bonds across the grain boundary interface, thereby raising the barrier to sliding. Trends in predicted grain boundary sliding energies are in good agreement with recently measured creep activation energies in polycrystalline alumina, lending further credence to the notion that grain boundary sliding plays a dominant role in alumina creep.     

Embedded cluster Δ-XANES modeling of adsorption processes on Pt

Full multiple scattering models of X-ray absorption near edge spectra of Pt Janin clusters, with atop and bridge bound oxygen, were systematically improved by increasing the number of cluster atoms contributing X-ray photoelectrons from unity (limited-absorber model), to all six Janin cluster Pt atoms, and finally embedding the Janin cluster into a larger Pt reservoir with photoelectron contributions from all atoms. The simulated XANES of the adsorbate modified clusters were subtractively normalized to their respective clean clusters to yield Δ-XANES signatures. The sequential analysis of previously published limited-absorber model, and the isolated and embedded all atoms models provide insights concerning the relative contribution of surface vs. subsurface atoms to adsorbate induced ligand effects and charge compensation provided by the bulk lattice. Limitations to the application of Δ-XANES signatures to interpretation of Δ-XANES data obtained from an air-breathing fuel cell are discussed.     

A longitudinal study of children's depressive symptoms, self-perceptions, and cognitive distortions about the self.

This longitudinal study examined how depressive symptoms relate to children's self-perceptions and to estimates of children's cognitive distortions about the self in a nonclinical sample of children who were followed from 4th grade (n=248) through 6th grade (n=227). Report card grades measured children's academic competence, and teachers' ratings of children's level of peer acceptance at school indicated social acceptance. Self-reported depressive symptoms predicted a change in children's negative views of the self. Moreover, the self-perceptions of children who exhibited more symptoms of depression appeared to reflect an underestimation of their actual competence. Children's negative self-perceptions and underestimations about the self were not associated with a subsequent change in depressive symptoms. The implications of the findings for cognitive theories of depression and future research with this population are discussed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

‘Baltimore does not condone profiteering in squalor’: the Baltimore Plan and the problem of housing-code enforcement in an American city

In 1941, the Baltimore City Council passed a law, the Ordinance on the Hygiene of Housing, declaring that all property in the city should be ‘maintained in good repair by the owner or agent, and fit for human habitation’. The campaign of housing-code enforcement that followed, known as the Baltimore Plan, made the city famous. When historians write about American housing-reform efforts during the mid-20th century, they tend to focus on big-ticket federal policies; by contrast, the Baltimore Plan seems too small to be significant. But it is more than a curiosity. First in Baltimore and then across the country, the neat cause-and-effect it posited between good stewardship and good housing crowded out more challenging ways of thinking about the problem. Eventually, the Baltimore Plan turned into a policy tool that reinforced the interests of the real estate industry at the expense of poor people. In that regard, the Baltimore Plan laid the foundations for federal disinvestment in the provision of decent housing and the midcentury tragedy of urban renewal.     

Maternal High‐Fat‐Diet Programs Rat Offspring Liver Fatty Acid Metabolism

In offspring exposed in utero to a maternal diet high in fat (HF), we have previously demonstrated that despite similar birth weights, HF adult offspring at 6 months of age had significantly higher body weights, greater adiposity, and increased triacylglycerol (TAG) levels as compared to controls. We hypothesized that a maternal HF diet predisposes to offspring adiposity via a programmed increase in the synthesis of monounsaturated fatty acids in the liver and hence increased substrate availability for liver TAG synthesis. We further hypothesized that programmed changes in offspring liver fatty acid metabolism are associated with increased liver expression of the lipogenic enzyme stearoyl‐CoA desaturase‐1 (SCD‐1). Female rats were maintained on a HF diet rich in monounsaturated fatty acids (MUFA) prior to and throughout pregnancy and lactation. After birth, newborns were nursed by the same dam, and all offspring were weaned to control diet. Plasma and liver fatty acid compositions were determined using gas chromatography/mass spectrometry. Fatty acid C16 desaturation indices of palmitoleic/palmitic and (vaccenic + palmitoleic)/palmitic and the C18 desaturation index of oleic/stearic were calculated. Liver protein abundance of SCD‐1 was analyzed in newborns and adult offspring. Plasma and liver C16 desaturation indices were decreased in HF newborns, but increased in the adult offspring. Liver SCD‐1 expression was increased in the HF adult offspring. These data show that the maternal HF diet during pregnancy and lactation increases offspring liver SCD‐1 protein abundance and alters the liver C16 desaturase pathway.     

Visual Metrics for the Maxton Plains Alvars in Michigan,USA

Planners, designers, environmentalists, concerned citizens, and government officials are interested in the management and preservation of small rare and unique ecological environments. Scholars have discovered that land-use and visual quality metrics often co-vary together and that various land-uses reside on a continuum scale from high respondent preference (biospheric land-uses) to low respondent preference (noospheric land-uses). This study assessed and documented the visual metrics for the Maxton Plains alvar/alvar grassland plant communities found on Drummond Island, Michigan, USA. These unique, small, and rare landscape types are not usually studied by large-scale visual quality mapping efforts which assess urban areas, woodlands, water, farmland, pastureland, and prairies. The visual metrics were assessed using two versions of predictive visual quality assessment models. Results from 60 field photographs reveal that the visual metrics assessment for the Maxton Plains alvars/alvar grasslands have a moderate visual preference, consistent visual quality scores: ranging from the low to middle 50s with the first equation and high 40s to low 50s with the second equation. Compared to many landscape and land-uses, these environments have scores that indicate a moderate visual preference and appreciation. Scores beyond±2.5 of the mean would indicate a significant (p≤0.05) perceivable drift from the existing conditions. The visual metrics provide a numerical framework for managing the spatial contents within and adjacent to the alvars. Landscape features such as buildings, invasive woodlands, agriculture, and pavement would all decrease the visual quality beyond the ± 2.5 score range.