HDI trimer based fluorine containing urethane methacrylates for hydrophobic photocured coatings

In this work, hexamethylene diisocyanate (HDI) trimer based two urethane methacrylates were synthesized by reacting 2-hydroxyethyl methacrylate (HEMA) and a fluoroalcohol with HDI trimer. Due to the high viscosity of the fluorinated methacrylates, they were applied onto glass substrates after mixing with tripropylene glycol diacrylate (TPGDA). The performance of the fluorinated resins were compared to a fluorine free HDI trimer based trimethacrylate. The TPGDA diluted formulations were better in terms of surface wettability than the neat resins. TPGDA diluted fluorinated resins exhibited a water contact angle of 109°± 2. All coatings exhibited high surface hardness (4H and 5H) and good adhesion.     

User assisted disparity remapping for stereo images

This study concentrates on user assisted disparity remapping for stereo image footage, i.e. the disparity of an object of interest is altered while leaving the remaining scene unattended. This application is useful in the sense that it provides a method for emphasizing/de-emphasizing an object on the scene by adjusting its depth with respect to the camera. The proposed technique can also be used as a post-processing step for retargeting stereoscopic footage on different display sizes and resolutions. The proposed technique involves an MRF-based energy minimization step for interactive stereo image segmentation, for which user assistance on only one of the stereo pairs is required for determining the location of stereo object pair. A key contribution of the proposed study is elimination of dense disparity estimation step from the pipeline. This step is realized through a sparse feature matching technique between the stereo pairs. Moreover, by the help of the proposed technique, novel disparity adjusted views are synthesized using the produced stereo object segments and background information for the images. Qualitative and quantitative evaluation of the generated segments and the disparity adjusted images prove the functionality and superiority of the proposed technique.     

Balancing of U-type assembly systems using simulated annealing

The paper presents a new simulated annealing (SA)-based algorithm for the assembly line-balancing problem with a U-type configuration. The proposed algorithm employs an intelligent mechanism to search a large solution space. U-type assembly systems are becoming increasingly popular in today's modern production environments since they are more general than the traditional assembly systems. In these systems, tasks are to be allocated into stations by moving forward and backward through the precedence diagram in contrast to a typical forward move in the traditional assembly systems. The performance of the algorithm is measured by solving a large number of benchmark problems available in the literature. The results of the computational experiments indicate that the proposed SA-based algorithm performs quite effectively. It also yields the optimal solution for most problem instances. Future research directions and a comprehensive bibliography are also provided here.     

Use of consistency index, expert prioritization and direct numerical inputs for generic fuzzy-AHP modeling: A process model for shipping asset management

The aim of this paper is to develop a generic version of the conventional fuzzy-analytic hierarchy process (FAHP) method and investigate the shipping asset management (SAM) problem in the dry bulk shipping market. The recent literature has various applications of the FAHP, but these studies lack consistency control, use identical decision support rather than weighted expert choices, and lack measurable criteria. The proposed model, generic fuzzy-AHP (here after GF-AHP), provides a standard control of consistency on the decision matrix for the expert group. GF-AHP also improves the capabilities of the FAHP by executing direct numerical inputs without expert consultation. In practical business, some of the criteria can be easily calculated and expert consultation is a redundant process. Therefore, GF-AHP presents how to transform such numerical inputs to a priority scale. Finally, expertise differences on the decision group are reflected in the GF-AHP process by an expert weighting algorithm.     

The effects of Co/Ce loading ratio and reaction conditions on CDRM performance of CoCe/ZrO2 catalysts

This work mainly aims to establish a link between Co/Ce loading ratio in CoCe/ZrO₂ catalysts and their Carbon Dioxide Reforming of Methane (CDRM) performance. In this context, catalysts with different Co and Ce loadings were prepared and characterized via BET, XRD, HRTEM-EDX, XPS and Raman, and parametrically tested under different CDRM conditions. Dispersion of Co particles was nonhomogeneous on all samples. For the sample with the highest Co/Ce ratio (10%Co2%Ce/ZrO₂), higher amount of lattice oxygen vacancies and lowest degree of ceria reduction were determined. Raman analysis showed that graphitic carbon coexisted with amorphous carbon on the surface of all spent samples. The extent of side reactions prevailed in determining selectivity. It was expressed that both CoCe synergistic interaction and synchronous contribution of Ce and ZrO₂ were enhanced for the samples having lower Co/Ce ratio. It was confirmed that Ce is only responsible for oxygen transfer but not its formation.     

Zinc oxide nanowire enhanced multifunctional coatings for cotton fabrics

Zinc oxide (ZnO) nanowires have been grown on cotton fabric to impart self-cleaning, superhydrophobicity and ultraviolet (UV) blocking properties. ZnO nanowires were grown by the microwave assisted hydrothermal method and subsequently functionalized with steraic acid to obtain a water contact angle of 150°, showing their superhydrophobic nature which is found to be stable up to 4 washings. UV protection of the resulting cotton fabric was also examined and significant decrease in the transmission of UV range was observed. Self-cleaning activity of the ZnO nanowire coated cotton fabric was also studied and it showed considerable degradation of methylene blue under UV light irradiation. These results suggest that ZnO nanowires could form ideal multifunctional coatings for textiles.     

Right intra-atrial catheter placement for hemodialysis in patients with multiple venous failure

The purpose of this study is to evaluate the efficacy and safety of direct right atrial catheter insertion for hemodialysis in patients with multiple venous access failure. We retrospectively evaluated the charts of 27 patients with multiple venous access failure who had intra-atrial dialysis catheter placement between October 2005 and October 2010 in our clinic. Permanent right atrial dialysis catheters were placed through a right anterior mini-thoracotomy under intratracheal general anesthesia in all patients. Demographics of the cases, the patency rates of hemodialysis via atrial catheterization, existence of any catheter thrombosis, and catheter-related infections were documented and used in statistical analysis. Seventeen women (63%) and 10 men (37%) with the mean age of 59.0 ± 7.1 years (47-71) were enrolled in this study. Chronic renal failure was diagnosed for the mean of 78.9 ± 24.3 months (33-130). Five patients (18.5%) died. Ventricular fibrillation and myocardial infarction were the causes of death in the early postoperative period in two patients. Two of the remaining three patients died because of cerebrovascular events, and one patient died because of an unknown cause. Ten patients (37%) had been using anticoagulate agents (warfarin) because of concomitant disorders such as deep vein thrombosis, operated valve disease, and arrhythmias. Catheter thrombosis and malfunction was determined in three cases (11.1%). Intra-atrial hemodialysis catheterization is a safe and effective life-saving measure for the patients with multiple venous failure and without any possibility of peritoneal dialysis or renal transplantation.     

Li-doped MgO From Different Preparative Routes for the Oxidative Coupling of Methane

Li-doped MgO was prepared on different preparative routes and with different loadings. The catalytic activity was found to decay for all catalysts for 40 h time on stream. A detailed structural analysis of 0.5 wt% Li-doped MgO showed heavy losses of Li, reduced surface area and grain growth. A correlation between these factors and the deactivation could not be found. The reaction temperature and the flow rate were found to be the main deactivation parameters.