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81.
Mohsen Lashgari 《Electrochimica acta》2011,(9):3322
Using quantum electrochemical/thermodynamical approaches based on coupled cluster/polarized continuum models and density functional theory (CM/PCM–DFT), we investigated the corrosion inhibition mechanism of Al/NaOH system in the presence of some p-phenol derivatives. The influencing parameters on inhibitory action, i.e. charges on oxygen and hydrogen atoms of hydroxyl group, charge transfer, interaction energy, molecular activity and softness, electric dipole moment and de-solvation free energy, were determined for both neutral and deprotonated species at metal|solution interface. A good correlation was observed between these parameters and inhibition efficiency data reported in the literature. By introducing an appropriate thermodynamic procedure, we also determined the proton-loss tendency of the molecules nearby interface. The results were amazing and revealed a complicated protonation/deprotonation cycle for inhibitor species inside electrical double layer; the corrosive agents in the vicinity of metal surface become locally neutralized and pushed away. 相似文献
82.
Mehdi Mohagheghi Karamatollah Rezaei Mohsen Labbafi Seyyed Mohammad Ebrahimzadeh Mousavi 《European Journal of Lipid Science and Technology》2011,113(6):730-736
Pomegranate seeds are by‐products of pomegranate juice industry. Since the seeds contain valuable oil that has nutritional and medicinal properties, they can be useful for food applications (especially in juice and beverage industries) as a functional agent. In this study, the possibility of producing a stable pomegranate‐seed‐oil‐in‐water emulsion to be used as a base formula for a new functional beverage was investigated. The influence of gum Arabic (GA) concentration (10.0, 12.5, and 15.0%, w/w) with a constant oil phase content (6.0% w/w) on the turbidity loss rate, emulsion stability index, and droplet size distribution was investigated. Turbidity loss rate was inversely proportional to the GA concentration for all the formulations studied here. Compared to other emulsions, emulsion with 15.0% w/w GA did not show a discernible cream layer during 42 days of storage. Emulsion with 15.0% w/w GA indicated the smallest polydispersity index during this period. The results of this study showed that it was possible to produce a relatively stable pomegranate‐seed‐oil‐in‐water emulsion for use as a functional agent in beverages. 相似文献
83.
Akbar Zendehnam Mina Arabzadegan Sayed Mohsen Hosseini Nasrin Robatmili Sayed Siavash Madaeni 《Korean Journal of Chemical Engineering》2013,30(6):1265-1271
Polyvinylchloride-blend-styrene butadiene rubber based nanocomposite cation exchange membranes were prepared by solution casting technique. Iron-oxide nanoparticles and Ag-nanolayer were simultaneously utilized as filler and surface modifier in membrane fabrication. The effects of Ag-nanolayer film thickness on membrane physicochemical and antibacterial characteristics of nanocomposite PVC-blend-SBR/Iron-oxide nanoparticles were studied. SEM images showed membrane roughness decreasing by Ag nanolayer thickness increasing. Membrane charge density and selectivity declined by Ag nanolayer coating up to 5 nm in membranes and then showed increasing trend by more nanolayer thickness. Ionic flux also showed increasing trend. Membranes showed good ability in E-Coli removal. 20 nm Ag-nanolayer coated membrane showed better performance compared to others. 相似文献
84.
In situ graft copolymerization of polystyrene (PS) on polybutadiene (PB) during polymerization of PB solution in styrene monomer was investigated to determine the performance of grafting process, chain structure of generated copolymers, and their effectiveness as compatibilizing agents for incompatible PS-rich and PB-rich phases. The amount of copolymers and their chain structures at different stages of polymerization were determined by gel permeation chromatography (GPC) curves of the reactive blends (taken directly from the reaction) and physical blends (physically prepared based on total composition of reactive blends). It was demonstrated that copolymer formation started from the early stage of polymerization and continued up to the phase inversion stage. In addition, PS grafting on PB occurred initially via single-chain attachment and then converted to a double-chain scenario later on. Compatibilizing efficiency of the copolymers was evaluated by Huggins coefficient (k H) obtained by performing dilute solution viscometry (DSV) on samples taken at different stages of conversions. The effect of molecular weight of PB on the grafting process and the effectiveness of copolymers generated were also studied. It was found that while compatibilizing role of the copolymers produced from high molecular weight PB (HPB) increases as conversion goes further, the compatibilizing efficiency of the copolymers produced from low molecular weight PB (LPB) shows a very sharp variation in a small range of conversion. Plotting k H of physical blends against weight fraction of PB molecules in solid content of the solutions (w PB) showed negative deviation from mixture law with a W-like pattern containing two minima with a maximum in between. While a negative deviation was assumed as indication of immiscibility of the components, upward deviation at middle values of w PB was attributed to molecular segregations that reduce the interface between the incompatible PS-rich and PB-rich phases. 相似文献
85.
Mohammad Sabet Masoud Salavati-Niasari Mohsen Ashjari Davood Ghanbari Mahnaz Dadkhah 《Journal of Inorganic and Organometallic Polymers and Materials》2012,22(5):1139-1145
CuInS2/CuS nanocomposite were synthesized by a copper complex, [bis(ethylenediamine)copper(ΙΙ)] sulfate. Eight sulfur sources were used for this experiment. The products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy dispersive X-ray analysis spectroscopy, and room temperature photoluminescence spectroscopy. Thin film of nanocomposite powder was fabricated and its feature (Voc, Jsc and FF) was calculated by current–voltage (I–V) curve. 相似文献
86.
Sarah Pourjafar Ahmad Rahimpour Mohsen Jahanshahi 《Journal of Industrial and Engineering Chemistry》2012,18(4):1398-1405
Novel polyethersulfone (PES)/poly (vinyl alcohol) (PVA)/titanium dioxide (TiO2) composite nanofiltration membranes were prepared by dip-coating of PES membrane in PVA and TiO2 nanoparticles aqueous solution. Glutaraldehyde (GA) was used as a cross-linker for the composite polymer membrane in order to enhance the chemical, thermal as well as mechanical stabilities. TiO2 nanoparticles with different concentrations (0, 0.05, 0.1, 0.5 wt.%) were coated on the surface of PVA/PES composite membrane. The morphological study was investigated by atomic force microscopy (AFM), scanning surface microscopy (SEM) and along with X-ray diffraction (XRD). In addition, the membranes performances, in terms of permeate flux, ion rejection and swelling factor were also investigated. It was found that the increase in TiO2 solution concentration can highly affect the surface morphology and filtration performance of coated membranes. The contact angle measurement and XRD studies indicated that the TiO2 nanoparticles successfully were coated on the surface of PVA/PES composite membranes. However, rougher surface was obtained for membranes by TiO2 coating. The filtration performance data showed that the 0.1 wt.% TiO2-modified membrane presents higher performance in terms of flux and NaCl salt rejection. Finally, TiO2 modified membranes demonstrated the lower degree of swelling. 相似文献
87.
SiO2 nanoparticles of a quantum size (15 nm or less) were prepared via sol–gel method using tetraethylorthosilicate as a precursor. SiO2 nanoparticles were characterized by X‐ray diffraction (XRD) and field‐emission scanning electron microscopy (FESEM) analyses. Polyethersulfone/silica (PES/SiO2) crystal structure nanocomposite was prepared by in situ polymerization using silica nanoparticles as reinforcement filler. The polymerization reaction was done at 160°C in paraffin bath in the presence of diphenolic monomers. XRD and FESEM analyses were used to study the morphology of the synthesized nanocomposite. The purity and thermal property of the PES/SiO2 nanocomposite were studied by energy dispersion of X‐ray analysis and differential scanning calorimetry, respectively. The effect of silica particles on the hydrophilicity of PES/SiO2 nanocomposite was also investigated. It was showed that the PES/SiO2 nanocomposite had a higher swelling degree when compared with the pure PES. The synthesized PES/SiO2 powder was used to remove Cu(II) ions from its aqueous solution. The effect of experimental conditions such as pH, shaking time, and sorbent mass on adsorption capacity of PES/SiO2 nanocomposite were investigated. It was found that incorporation of a low amount of silica (2 wt%) into the polymer matrix caused the increase of the Cu(II) ions adsorption capacity of PES. POLYM. COMPOS., 2012. © 2012 Society of Plastics Engineers 相似文献
88.
The purpose of this paper is to study the characteristics of the combined convection heat transfer and a micropolar nanofluid flow passing through an impermeable stretching sheet in a porous medium. The nanofluid flow field is affected by a magnetic field perpendicular to the sheet. The dynamic viscosity of the micropolar nanofluid changes under the influence of the magnetic field. The continuity, linear momentum, angular momentum, and energy equations are first simplified using the order of magnitude technique that, along with the applied boundary conditions and the definition of the appropriate parameters, are transferred to the similarity space using the similarity analysis. Then the resulting equations are solved using the Runge–Kutta method.The distinction of the macroscale and microscale flow fields and temperature fields resulting from different nanoparticle shapes was clarified. Increasing the Hartmann number, the vortex viscosity parameter, the magnetic parameter, the nanoparticle volume fraction, and the permeability parameter of the porous media increased the surface friction on the sheet. Increasing the vortex viscosity parameter, the magnetic parameter, and the volume fraction of the nanoparticles increases the Nusselt number. 相似文献
89.
Mohsen Izadi 《中国化学工程学报》2020,28(5):1203-1213
This study numerically investigates the impact of porous materials, nano-particle types, and their concentrations on transient natural convection heat transfer of nano-fluid inside a porous chamber with a triangular section. The governing equations of the two-phase mixture model are separated on the computational domain and solved using the Finite Volume Method, taking into account the Darcy–Brinkman model for porous medium. It was observed that convection heat transfer inside the triangular chamber consists of three stages named initial, transient, and semi-steady. The features of each step are provided in detail. The results suggested that the use of a hybrid nano-fluid(water/aluminum oxide-cooper) inside a porous glass material and an increase in volume fraction of nano-particles have adverse effects on heat transfer rate. In contrast, as the nano-particle volume fraction of the single nano-fluid(water/aluminum oxide) inside the chamber increased, convection heat transfer rate improved. At the same time, it was observed that the use of both nano-fluids(single and hybrid) in the porous environment of the aluminum foam could improve convection. 相似文献
90.
Erfan Khodabandeh Hesam Moghadasi Mohsen Saffari Pour Mikael Ersson P r G. J nsson Marc A. Rosen Alireza Rahbari 《中国化学工程学报》2020,28(4):1029-1038
This research investigates a numerical simulation of swirling turbulent non-premixed combustion. The effects on the combustion characteristics are examined with three turbulence models: namely as the Reynolds stress model, spectral turbulence analysis and Re-Normalization Group. In addition, the P-1 and discrete ordinate (DO) models are used to simulate the radiative heat transfer in this model. The governing equations associated with the required boundary conditions are solved using the numerical model. The accuracy of this model is validated with the published experimental data and the comparison elucidates that there is a reasonable agreement between the obtained values from this model and the corresponding experimental quantities. Among different models proposed in this research, the Reynolds stress model with the Probability Density Function (PDF) approach is more accurate (nearly up to 50%) than other turbulent models for a swirling flow field. Regarding the effect of radiative heat transfer model, it is observed that the discrete ordinate model is more precise than the P-1 model in anticipating the experimental behavior. This model is able to simulate the subcritical nature of the isothermal flow as well as the size and shape of the internal recirculation induced by the swirl due to combustion. 相似文献