Drying process in vapor swollen heterogels

Disk-shaped heterogels were prepared by combining methyl methacrylate (MMA) and styrene (S) with ethylene glycol dimethacrylate (EGDM) as a crosslinker agent in the presence of 2,2′-azobisisobutyronitrile (AIBN). Swelling experiments were performed under chloroform vapor and the swollen gels are then allowed to dry under room temperature. Gravimetric technique was used to study drying processes. It is observed that two different regimes are present in the drying processes of these heterogels. Fickian diffusion model was used to determine desorption coefficients for each drying step in both regimes. Desorption coefficients, D _d, of heterogels were found to be strongly correlated with the mixture composition of polymeric materials in the heterogel system for both regimes. Heterogels with high S content dry much slower than the heterogels with low S content.     

μ‐Consortium: Aufbau einer mobilen Anlage für die Aus‐ und Weiterbildung in der Mikroverfahrenstechnik

A mobile plant for practical training was developed as part of the project μ‐Consortium to integrate micro process engineering into teaching. Lab experiments in the fields of mixing and homogenous reactions, heterogeneous reactions, heat transfer and particle synthesis were worked out to impart knowledge of different process‐engineering operations.     

Transferrin-Decorated Niosomes with Integrated InP/ZnS Quantum Dots and Magnetic Iron Oxide Nanoparticles: Dual Targeting and Imaging of Glioma

The development of multifunctional nanoscale systems that can mediate efficient tumor targeting, together with high cellular internalization, is crucial for the diagnosis of glioma. The combination of imaging agents into one platform provides dual imaging and allows further surface modification with targeting ligands for specific glioma detection. Herein, transferrin (Tf)-decorated niosomes with integrated magnetic iron oxide nanoparticles (MIONs) and quantum dots (QDs) were formulated (PEGNIO/QDs/MIONs/Tf) for efficient imaging of glioma, supported by magnetic and active targeting. Transmission electron microscopy confirmed the complete co-encapsulation of MIONs and QDs in the niosomes. Flow cytometry analysis demonstrated enhanced cellular uptake of the niosomal formulation by glioma cells. In vitro imaging studies showed that PEGNIO/QDs/MIONs/Tf produces an obvious negative-contrast enhancement effect on glioma cells by magnetic resonance imaging (MRI) and also improved fluorescence intensity under fluorescence microscopy. This novel platform represents the first niosome-based system which combines magnetic nanoparticles and QDs, and has application potential in dual-targeted imaging of glioma.     

Effects of crushed clay brick aggregate on mortar durability

This paper reports an experimental study that aimed to investigate the effects of recycled clay brick, used as a part of fine aggregate, on mortar durability. The brick, in crushed form, was from a local brick manufacturer that salvages its off-standard products. It was used to replace 10% and 20% (by weight) of the river sand in mortar. Effects of the brick replacement on the mortar flow, compressive strength, shrinkage, freeze–thaw resistance, and alkali–silica reaction potential were investigated. The results showed that as the brick replacement level increased, the mortar flowability reduced. The 10% and 20% brick replacements had no negative effect on the mortar compressive strength and very limited effect on the mortar shrinkage. The freeze–thaw resistance of the mortar was improved by the brick replacement. However, the use of crushed brick as aggregate appeared not to reduce potential alkali–silica reaction. The microscopy study revealed the alkali–silica reaction product and associated cracking in the mortar. Additional study indicated that the brick aggregate used in the study had pessimum proportion, 30%, for the alkali–silica reaction expansion.     

Cylindrical and spherical shells with cracks

The symmetric problem for the cylindrical and spherical shells containing a meridional crack is considered. The problem is solved for a uniform membrane load and a uniform bending moment applied to the surface of the crack. The extensional and bending components of the stress intensity factor ratio are obtained as functions of shell parameter and are tabulated. The results are also plotted in order to compare them with the existing asymptotic solutions.

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Zusammenfassung Das symmetrische Problem für zylindrische and sphärische Schalen, die einen meridionalen Riß haben, wurde behandeft. Das Problem wurde für eine einheitliche Membranlast and ein einheitliches Biegungsmoment auf der Oberfläche des Risses angewandt, gelöst.Die ausdehnenden und biegenden Komponente des Druckstärkefaktorenradius wurden als Funktionen des Schalenparameters erhalten and tabuliert. Die Ergebnisse wurden auch aufgezeichnet, um sie mit den bestehenden asymmetrischen Lösungen zu vergleichen.

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Résumé On considère le problème symétrique d'enveloppes cylindriques et sphériques comportant une fissure qui se développe suivant un méridien. La solution est apportée dans le cas d'une contrainte de membrane uniforme et d'un moment de flexion uniformément appliqué aux lèvres de la fissure.Ces composantes de traction et de flexion qui agissent sur le facteur d'intensité des contraintes sont determinées en fonction des paramètres de l'enveloppe, et présentées sous forme de tableaux. Les résultats ont 6t6 également portés en diagrammes, de manière à les comparer aux solutions asymptotiques existantes.

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This work was supported by the National Aeronautics and Space Administration under the Grant NGR 39-007-011.     

Bifunctional Catalyst Control of Alkene Isomerization

The ability to control the formation and chemistry of alkenes is of central importance to organic synthesis in both industry and academia. Progress in using catalysts with bifunctional (heteroaryl)phosphines to control positional and/or geometric selectivity in alkene isomerization and related chemistry is summarized.

     

Confined batch foaming of semi-crystalline rubbery elastomers with carbon dioxide using a mold

Confined foaming of poly(ethylene-co-vinyl acetate-co-carbon monoxide) using carbon dioxide as a physical blowing agent in a mold with either permeable or impermeable boundaries has been explored as a strategy to control final foam dimensions and morphology. The results are discussed in terms of comparisons to free-foaming experiments conducted at the same pressure and temperature conditions following the same pressurization and depressurization paths. Foaming experiments were carried out at 30 and 40°C and 100, 200, and 300 bar followed by rapid depressurization of the foaming cell. Confined foaming led to smaller pores with more uniform distributions across the polymer cross-section. However, bulk foam densities of the foams generated under confinement were higher than those generated under the free-foaming mode. Surface characteristics and skin layer formation were altered by expansion against both the permeable and impermeable boundaries. Confined foaming promotes uniform pore distribution and overall dimensional uniformity and may impart surface texture but the trade-off is in the degree to which the bulk foam density can be lowered.     

Characterization of polymeric LB thin films for sensor applications

The Quartz Crystal Microbalance (QCM) system is utilized to investigate the relationship between mass uptake and associated swelling for Langmuir‐Blodgett (LB) organic thin films obtained from pyrene end‐capped polystyrene (PS). The study was carried out using three different molecular weights of polymeric chains. The changes in resonance frequency associated with mass changes can be attributed to the swelling behavior of polymeric thin films during vapor absorption. This swelling is due to the capturing of organic vapor molecules in the sensor environment. To quantify real‐time QCM data for swelling, early‐time Fick's law of diffusion was adopted to fit the results, and a good linear relationship was observed between the mass uptake and square root of the swelling time. The diffusion coefficients for swelling were thus obtained from the slopes of the fitting curves and was found to be correlation with the amount of organic vapor content in the cell. It was also observed that diffusion of the organic vapor into higher molecular weight polystyrene thin films are much faster than low molecular weight ones in sensor applications. Diffusion coefficients were found to be 0.2–3.0 × 10^?16, 5.0–13 × 10^?16, and 1.0–1.6 × 10^?15 cm²/s for PS1, PS2, and PS3 LB thin films, respectively. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Modelling the impact of land-cover change on potential soil loss in the Taita Hills,Kenya, between 1987 and 2003 using remote-sensing and geospatial data

In sub-Saharan Africa, natural vegetation is being transformed into agricultural lands at a fast rate, endangering ecosystem services and increasing soil-loss potential, which may trigger land degradation. For the Taita Hills study area in Kenya, multi-temporal land-cover models of 1987, 1999 and 2003, derived from Satellite Pour l'Observation de la Terre (SPOT) imagery using a multi-scale segmentation/object relationship modelling (MSS/ORM) methodology and a rainfall layer, a digital elevation model (DEM) and a digital soil map were applied to model potential soil loss. Population growth in the area has led to a shortage of agricultural land and movement of people to the lowlands, evidenced by a 39% (9.3 km²) increase in croplands from 30% to 41% of the study area during the research time frame. Expansion took place mostly in surrounding foothills and lowlands, at the expense of natural shrubland and grassland, but also occurred in the hills. Universal soil-loss equation (USLE) model results showed a 60% (4 km²) increase in the area of very high potential soil loss, from 7% of the study area in 1987 to 12% in 2003, due mainly to very high soil-loss potential in croplands. Whilst the area of croplands as a whole increased, the relative proportion of very high soil-loss potential in croplands remained 20%, both in 1987 and in 2003, indicating that newly cleared agricultural lands with vulnerable soils are the most at-risk areas.