A variational treatment for the time dependent boltzmann equation as a basis for numerical solutions conserving neutrons

A maximum principle for the time-dependent first-order Boltzmann equation is established in two independent ways:- by a generalized least squares method and by a method based on the properties of an appropriate bi-linear form. The second derivation suggests a metric for a Hilbert space which provides a geometrical interpretation of the variational principle. This interpretation leads to a Petrov-Galerkin weighted residual method in contrast to the Galerkin method of Martin for time dependent transport.

The maximum principle is used to define a figure of merit for the global error of any numerical solution for time dependent transport. The principle is used also to demonstrate the neutron conservation property of optimized numerical solutions, and the convergence of finite element methods based on the variational principle.

A direct use of the maximum principle give a conservative three level scheme for transients in the angular flux. A less massive calculation for a conservative solution proceeds in two stages. The first stage obtains a preliminary solution based on a sequence of tailored steady state calculations for the even-parity angular flux. The relevant equations are derived by making residual terms vanish in the variational principle. They are equivalent to the finite element - finite difference equations used by de Oliveira and Wood for the analysis of oil-well logging by means of a neutron pulse. For the second stage the preliminary solution is weighted at each time step. The weights are determined by the maximum principle to yield a conservative solution which is continuous in time. The solution can be arranged to have also a continuous time derivative. Thus the maximum principle can be used both as a way of predicting and correcting solutions.     

Chelants to inhibit magnesia (MgO) hydration

Magnesium oxide (MgO) presents excellent refractoriness and high resistance to basic slag. However, in the presence of water, MgO undergoes an expansive hydration reaction generating Mg(OH)₂, which can lead to swelling and cracking. In this work, additives called chelants were added to dead burnt magnesia suspensions in order to check their effectiveness as inhibitors of the magnesium oxide hydration. Zeta potential, ionic conductivity, pH and temperature measurements were used to provide information related to the magnesia surface and the chelant adsorption. Assessment of the hydration degree and volumetric expansion provided indications of the amount of Mg(OH)₂ formed, as well as its likelihood to damage the ceramic bodies. The results showed that citric acid can inhibit hydration to some extent, whereas ethylenediamine tetraacetic acid (EDTA) was more effective in preventing volume expansion. An addition of 0.3 wt% of these chelants was sufficient to prevent hydration and avoid expansion.     

High-Throughput Analysis of Algal Crude Oils Using High Resolution Mass Spectrometry

Lipid analysis often needs to be specifically optimized for each class of compounds due to its wide variety of chemical and physical properties. It becomes a serious bottleneck in the development of algae-based next generation biofuels when high-throughput analysis becomes essential for the optimization of various process conditions. We propose a high-resolution mass spectrometry-based high-throughput assay as a ‘quick-and-dirty’ protocol to monitor various lipid classes in algal crude oils. Atmospheric pressure chemical ionization was determined to be most effective for this purpose to cover a wide range of lipid classes. With an autosampler-LC pump set-up, we could analyze algal crude samples every one and half minutes, monitoring several lipid species such as TAG, DAG, squalene, sterols, and chlorophyll a. High-mass resolution and high-mass accuracy of the orbitrap mass analyzer provides confidence in the identification of these lipid compounds. MS/MS and MS3 analysis could be performed in parallel for further structural information, as demonstrated for TAG and DAG. This high-throughput method was successfully demonstrated for semi-quantitative analysis of algal oils after treatment with various nanoparticles.     

CONJUGATE HEAT AND MASS TRANSFER IN CONVECTIVE DRYING OF MULTIPARTICLE SYSTEMS. PART I: THEORETICAL CONSIDERATIONS

This is the first of two papers concerning conjugate transport in convective drying of multiparticle systems. In this study, a methodology for the solution of conjugate transport problems is proposed. The theoretical aspects and relevant assumptions are briefly discussed and the results for convective heat and mass transfer in assemblages of spheres are presented. It is shown that both heat and mass transfer rates for an assemblage of two spheres in tandem arragement are significantly different from those of a single sphere case, and that care should be taken when modeling multiparticle systems by means of single-particle analysis.     

Effect of chitosan and Dysphania ambrosioides on the bone regeneration process: A randomized controlled trial in an animal model

The focus of this triple‐blind study was on evaluating the effect of chitosan combined with Dysphania ambrosioides (A) extract on the bone repair process in vivo. In total, 60 male Wistar rats (Rattus norvegicus albinus) weighing between 260 and 270 g were randomly selected for this study and distributed into four groups (n = 15). Group C (chitosan), Group CA5 (chitosan + 5% of D. ambrosioides), Group CA20 (chitosan + 20% of D. ambrosioides), and Group CO (Control‐Blood clot). In each animal, bone defects measuring 2 mm in diameter were performed in both tibias for placement of the substances. After 7, 15, and 30 days, the animals were sedated and sacrificed using the cervical dislocation technique and the tissues were analyzed under optical microscope relative to the following events: inflammatory infiltrate, necrosis, osteoclasts, osteoblasts, fibroblasts, periosteal, and endosteal bone formation. The data were evaluated to verify distribution using the Kolmogorov–Smirnov test, and variance, using the Levene test; as distribution was not normal, data were subjected to the Kruskal–Wallis and Dunn nonparametric tests (p < .05). A significant inflammatory infiltrate was observed in Group CA5 (p = .008) in the time interval of 7 days, and in Group C at 15 (p = .009) and 30 (p = .017) days. Osteoblastic activity was more significant in Group CA20 (p = .027) compared with CA5 in the time interval of 7 days. Group CA20 demonstrated a significantly higher endosteal and periosteal bone formation value in the time interval of 7 (p = .013), 15 (p = .004), and 30 days (p = .008) compared with the other groups. The null hypothesis was refuted, bone regeneration was faster in spheres with an association of chitosan and 20% extract, and complete bone repair occurred clinically at 15 days and histologically at 30 days. The spheres proved to be a promising method for the biostimulation of alveolar bone repair and bone fractures.     

The effects of hot isostatic pressing (HIP) and solubilization heat treatment on the density,mechanical properties,and microstructure of austenitic stainless steel parts produced by selective laser melting (SLM)

Despite ongoing optimization, selective laser melting (SLM) technology still cannot guarantee the production of completely defect-free components. This wor     

Immune parameters in female workers exposed to urban pollutants

Urban outside workers, such as traffic police, are daily exposed to air pollutants and psychosocial stressors: for these workers, the working environment corresponds to the living environment of the general population. Studies in the literature have shown that immune parameters could be affected by chronic exposure to various chemical pollutants. The aim of this study is to evaluate whether occupational exposure to urban pollutants can cause alterations in NK, IL-2, IFN-gamma and C3 plasma levels in female traffic police compared to a control group. After excluding subjects with the principal confounding factors, 86 female traffic police and 87 controls were matched by age, years of police work and habitual alcohol consumption. The distribution of NK values in female traffic police and controls was significantly different (p=0.000); NK values above the upper limit of the normal laboratory range were observed in 23 female traffic police and in 2 controls (p=0.000). IL-2 mean levels were higher in traffic police compared to controls, but the difference was not significant. The mean and the distribution of IFN-gamma values in female traffic police and controls were not different. C3 mean levels were higher in female traffic police versus controls, but the difference was not significant. Considering that the subjects with the principal confounding factors were excluded from the study and that female traffic police and controls were matched by the above-mentioned variables, our results suggest that chronic occupational exposure to low doses of chemical stressors, which may interact with and add to psychosocial ones, can affect both innate and adaptative immunity.     

Optimizing the use of dry cutting in rough turning steel operations

The main objective of using cutting fluids in machining operations is the reduction of temperature in the cutting region to increase tool life. However, the advantages offered by cutting fluids have been strongly debated because of their negative effects on the economic aspect, the environment and the health of workers using them. A trend to solve these problems is cutting without fluid, a method named dry cutting, which has been made possible due to technological innovations. This work aims to seek conditions in which dry cutting is satisfactory compared with the flood of fluid (called here wet cutting) usually used. Aiming at this goal, several experiments were carried out varying parameters such as cutting speed, feed, depth of cut and tool material in rough turning of ABNT 1045 steel in dry and wet cutting. The analysis of the results showed that wet turning is, as expected, better for tool life. The second conclusion is that dry cutting cannot be used with large depth of cut. But the main conclusion is that, if the tool material is changed to a more wear resistant one, dry cutting can be used with results very similar to those obtained with a flood of fluid.