一种有实效且易操作的强化辅导教学模式--谈电子设计竞赛的赛前辅导与准备

介绍了电子设计竞赛赛前辅导、训练与准备的主要内容，提出了改革专业技术课教学的3点建议。     

MEASUREMENT OF NEUTRON SPECTRA FROM THICK Be TARGET BOMBARDED WITH DEUTERONS

ＭＥＡＳＵＲＥＭＥＮＴＯＦＮＥＵＴＲＯＮＳＰＥＣＴＲＡＦＲＯＭＴＨＩＣＫＢｅＴＡＲＧＥＴＢＯＭＢＡＲＤＥＤＷＩＴＨＤＥＵＴＥＲＯＮＳＷａｎｇＸｉａｏｚｈｏｎｇ（王效忠）；ＢａｉＸｉｘｉａｎｇ（白希祥）；ＬｉＡｎｌｉ（李安利）；ＬｉｕＷｅｉｐｉｎｇ（柳...     

利用相似理论预测焊接变形的研究

针对薄壁结构,从弹性能的角度出发,利用基于温度场相似的相似准则和数值分析的手段,提出一种研究焊接残余变形的模型方法,并进行了试验验证。     

Na+掺杂对LiNi0.8Co0.1Mn0.1O2正极材料电化学性能的影响

高镍三元正极材料LiNi0.8 Co0.1 Mn0.1 O2(简称NCM811)是非常有前景的动力电池用锂离子电池正极材料.LiNi0.8 Co0.1 M n0.1 O2具有比容量高、成本低、环保等优点,但也存在锂镍混排严重,容量衰减快等缺点.为解决这些问题,促进该材料在动力电池中的应用进程,本研究采用高温固相法合成了NCM811,并通过Na+掺杂对材料进行改性.采用X射线衍射仪(XRD)、扫描电镜(SEM)对材料进行形貌和结构表征.采用循环伏安(CV)、循环、倍率以及电化学阻抗(EIS)等手段研究材料的电化学性能.研究结果表明:在2.7～4.3 V,0.5 C放电条件下,当Na+掺杂量为0.1摩尔分数时,显示了185 m A h/g的初始放电比容量,循环100次后,仍保持151 m A h/g,显示出较好的循环性能.在0.2 C,0.5C,1C,2C,5C和10C下材料的放电比容量分别为195,184,158,137,112和90mAh/g,展现出较好的倍率性能.因此,适量的Na+掺杂能有效提高NCM 811材料的电化学性能.     

QuEChERS-气相色谱-串联质谱法同时测定豇豆中6种菊酯农药残留

建立QuEChERS-气相色谱-串联质谱技术同时测定豇豆中6种菊酯农药(甲氰菊酯、氯氟氰菊酯、氟氯氰菊酯、氯氰菊酯、氟胺氰菊酯、氰戊菊酯)含量的快速检测方法。豇豆样品经乙腈提取,采样QuEChERS法进行净化,目标化合物经TG-5SILMS(30 m×0.25 mm,0.25μm)色谱柱分离,采用三重串联四级杆选择反应监测模式(selected reaction monitoring,SRM)进行定性定量分析,外标法定量。结果表明,6种农药在0.001~0.5 mg/L范围内线性关系良好,相关系数均大于0.99;在3个添加浓度水平(0.01,0.05,0.10 mg/kg)下,平均回收率在89.6%~106.9%之间;5次重复的相对标准偏差在4.0%~11.9%;甲氰菊酯、氟氯氰菊酯和氰戊菊酯的定量限为0.003 mg/kg,氯氟氰菊酯、氯氰菊酯和氟胺氰菊酯的定量限为0.0015 mg/kg。该方法操作简便,结果准确,能满足豇豆中6种菊酯农药残留检测的要求。     

常见块根类蔬菜中钾钠含量的火焰光度法测定

通过硝酸消化法制备了11种常见块根类蔬菜的待测溶液,并用火焰光度法准确测定了其中钾钠的含量。通过对相关资料的查询,了解了正常人体所需的钾钠含量,经过分析以及与参考资料的对比表明,11种常见蔬菜中钾钠含量适中,能够满足人体正常需要,对高血压患者及其想通过改善膳食增进健康的人们具有一定的指导意义和参考价值。     

马氏体/贝氏体异种耐热钢焊接接头的力学性能及界面失效

采用脉冲氩弧焊接工艺、高温加速模拟工况、高温持久、常温力学性能试验研究了不同焊缝强度匹配条件下,马氏体耐热钢9Cr1MoVNbN与贝氏体耐热钢12Cr2MoWVTiB异种钢焊接接头的力学性能、高温强度、蠕变损伤及界面破坏特征。研究结果表明,焊前预热250℃,焊后回火750℃×1 h条件下,加速模拟运行500h、1 000 h、1 500 h后低匹配焊接接头的界面蠕变损伤较严重,力学性能下降明显,失效倾向较大;而中匹配接头的蠕变损伤及失效倾向较小,中匹配与低匹配接头的持久强度比较接近:而高匹配接头的持久强度最低。因此,对于9Cr1MoVNbN/12Cr2MoWVTiB异种钢焊接接头采用中匹配比较合适。     

Effects of aging on latex film formation from polystrene particles: A photon transmission study

Aging due to the storage time on latex film formation was studied using the photon transmission method. The UV visible technique was used to monitor the evolution of transparency during film formation from two different polystyrene (PS) particles produced by using two different steric stabilizers, i.e., polyvinyl alcohol and polyvinyl pyrrolidone. The latex films were prepared from PS particles at room temperature before and after aging and annealed at elevated temperatures in various time intervals above glass transition (T_g). The increase in the transmitted photon intensity I_tr was attributed to the increase in the number of disappeared particle–particle interfaces. Relative decrease in transparency and delay in film formation were observed in the aged latex films compared to the nonaged ones. The Prager–Tirrell model was employed to interpret the increase in crossing density at the junction surface. The back and forth activation energies (ΔE) were measured and found to be dependent on aging for a diffusing polymer chain across the junction surface. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 79: 2014–2021, 2001     

Molecular weight dependent changes with time during latex film formation: a photon transmission study

A photon transmission method was used to probe the change with time of transparency during film formation from latex particles. Two different latex films were prepared from high (HM) and low (LM) molecular weight poly(methyl methacrylate) (PMMA) particles, which were annealed at 10min time intervals at various temperatures above the glass transition T_g. The increase in the transmitted photon intensity I_tr is attributed to the increase in ‘crossing density’ at the junction surface. The back and forth activation energies (ΔE) were measured for HM and LM films and found to be around 29kcalmol^-1 and 53kcalmol^-1, respectively, for a reptating polymer chain across the junction surface. Monte Carlo simulations were performed for photon transmission through a rectangular lattice. The number of transmitted photons N_tr was calculated as a function of the mean free path of the photons. It was observed that N_tr increased similarly to I_tr as the square of the mean free path of the photons increased. © 1998 Society of Chemical Industry