Ferritic stainless steel welding with the A-TIG process

The main advantage of the TIG with flux process (A-TIG welding) is the possibility of obtaining greater penetration of the weld bead while employing the same welding parameters as conventional TIG welding. Various studies have shown the influence of active fluxes on the geometric characteristics of stainless steel austenitic welds. However, little is known about the influence of this process on the geometric and metallurgical characteristics of the weld beads in ferritic stainless steels. In this work, different types of flux are applied when welding ferritic stainless steel with the objective of verifying possible influences on the weld bead's profile, on its visual appearance, on the microstructure, on the hardness of the welded zone and on the impact resistance (Charpy test). The bead-on-plate welds were produced without using any addition metal. Six types of flux were used – one being an oxide produced in a laboratory (TiO₂) and five commercial fluxes. The results showed that use of the flux allows an increase in penetration with significant changes in the appearance of the weld bead. It was also confirmed that the microstructure and the hardness of the weld bead for the steel studied were not affected by the type of flux used, with the microstructure analysed under an optical microscope. The steel in the study showed a high degree of fragility at ambient temperature.     

High accumulation of perfluorooctane sulfonate (PFOS) in marine tucuxi dolphins (Sotalia guianensis) from the Brazilian coast

Perfluorooctane sulfonate (PFOS) and other perfluoroalkyl compounds (PFCs) were measured in liver samples from 29 marine tucuxi dolphins from Rio de Janeiro state (RJ), Brazil. PFC measurement combined liquid chromatography and mass spectrometry, using a CapLC system connected to a Quadrupole-LIT mass spectrometer. PFOS was the only PFC detected and it was so in all samples. PFOS concentrations (ng x g(-1) dw) of dolphins (n=23) from the highly contaminated Guanabara Bay (in RJ) varied between 43 and 2431 as well as between 76 and 427 from areas of RJ other than the quoted bay (n=6). Concentrations of three fetuses and one neonate varied between 664 and 1590. Fetus/mother ratios were calculated in two situations (2.75 and 2.62). It seems that mother-to-calf transference plays important role for relationships between PFOS and age. When a one-year-old male calf presenting 2431 ng x g(-1) dw was excluded from the test, significant correlations were observed between PFOS concentrations and both age and total length. Despite the placental transference, PFOS concentrations were not significantly lower in females than in males. PFOS levels in marine tucuxi dolphins from Guanabara Bay are among the highest detected to date in cetaceans, and this may represent a threat to the small population concerned.     

Warm asphalt mixtures produced with addition of CCBit

There is a growing concern with the environmental damage caused by the various types of industrial activities. Because of that, research in paving has sought alternatives to reduce fuel consumption and emissions of greenhouse gases generated by those. The warm mixtures have received increasing attention because they are capable of decreasing the mixture and compaction temperatures of asphalt mixtures. The objective of this study was to evaluate the effect of the incorporation of CCBit from the mechanical characterization of asphalt mixtures. From the results, it was found that the incorporation of CCBit has the advantage of reducing mixing and compaction temperatures without harming their mechanical behavior.     

Biodiesel Production from Waste Cooking Oil by Enzymatic Catalysis Process

Biodiesel is an excellent option for reducing dependence on fossil fuels with environmental advantages by reducing hazardous emissions. The enzymatic transesterification has attracted the attention of researchers in the last decade and the advantages of enzymatic catalysis show that the production of biodiesel by this route has good potential, mainly because it is friendly environment. For biodiesel, production process by enzyme catalysis is chosen the response surface methodology. It is an experimental strategy to find the best operating conditions oftransesterification reaction to improve the biodiesel quality. The Process has three variables： temperature, molar ratio oil-alcohol and catalyst quantity. The process was monitored by GC-FID （gas chromatography with flame ionization detector）. The yield of the transesterification reaction by enzymatic catalysis decreases with increasing temperature, and may be due to inactivation of the enzyme by denaturation at temperatures above 50 ℃. The second-order design used was the ＂CDC （central design composition）＂ which produced a maximum yield of 95.5% in the transesterification reaction by enzymatic catalysis obtained at a temperature of 45 ℃, molar ratio methanol：oil of 8：1 and a catalyst loading of 8% wt.     

Determination of avermectin and milbemycin residues in bovine muscle by liquid chromatography-tandem mass spectrometry and fluorescence detection using solvent extraction and low temperature cleanup

A simple and inexpensive sample preparation method based on solvent extraction, followed by low temperature cleanup, was demonstrated to be applicable for the determination of avermectin and milbemycin residues in bovine muscle by liquid chromatography-tandem mass spectrometry (LC-MS/MS) and liquid chromatography with fluorescence (LC-FL) detection. The analytical methodology was validated according to the Commission Decision 2002/657/EC, using LC-MS/MS for confirmatory and LC-FL for quantitative purposes. Mean recovery was between 88.9 and 100.7% in three distinct concentrations. The coefficient of variation for repeatability and within-laboratory reproducibility ranged from 0.78 to 5.1% and from 0.28 to 9.0%, respectively. Method precision led to satisfactory values of decision limits (CCα) and detection capabilities (CCβ). The proposed method has been applied in the Brazilian National Residue Control Plan since 2010 for the determination of avermectins and milbemycin residues in bovine muscle samples. A total of 760 samples were analyzed and none of them presented residues at concentrations above the permitted levels established by the more recently applied directives.     

Optimization of single SOFC structural design for maximum power

This paper improves previously published models by the authors for a single solid oxide fuel cell (SOFC), and introduces a procedure to optimize its external configuration and operating conditions, so that the net power is maximized. The previous models are hereby improved to include: i) a constant offset overpotential in total potential drop; ii) heat generation associated with all the potential losses; iii) temperature-dependent thermo-physical properties of fuel and air, and iv) pumping power to maximize fuel cell performance. The thermodynamic model is derived from physical laws (e.g., the first law of thermodynamics, Fick's law, Fourier's law) to obtain the temperature and pressure spatial distribution in the SOFC. The electrochemical model is validated by direct comparison with experimental data from the Pacific Northwest National Laboratory (PNNL), and allows for the computation of the SOFC voltage, current, and power output. Based on the simulation results, the structural design, the active three phase boundaries regions at the electrodes and the fuel utilization factor, and their impact on the SOFC performance are discussed. Subjected to fixed total volume, the optimal geometric and operating parameters are pursued so that the net power of the SOFC is maximized through a 4-way-optimization procedure. The method used is general and the numerically obtained maxima are sharp, taking into account that up to a 631% single SOFC performance variation was observed within the studied parameters' range. The fixed volume constraint was then relaxed, and the effect of total volume variation on performance was investigated, delivering the general optimal parameters for the 4-way maximized SOFC net power output within the studied total dimensionless fuel cell volume range. These findings show the potential to use the model as a tool for future SOFC design, simulation and optimization.     

Modeling extended lactations of dairy cows

Nine mathematical models were compared for their ability to predict daily milk yields (n = 294,986) in standard 305-d and extended lactations of dairy cows of Costa Rica. Lactations were classified by parity (first and later), lactation length (9 to 10, 11 to 12, 13 to 14, 15 to 16, and 16 to 17 mo), and calving to conception interval (1 to 2, 3 to 4, 5 to 6, 7 to 8, and 9 to 10 mo). Of the nine models, the diphasic model and lactation persistency model resulted in the best goodness of fit as measured by adjusted coefficient of determination, residual standard deviation, and Durbin-Watson coefficient. All other models showed less accuracy and positively correlated residuals. In extended lactations, models were also fitted using only test-day records before 305 d, which resulted in a different ranking. The diphasic model showed the best prediction of milk yield in standard and extended lactations. We concluded that the diphasic model provided accurate estimates of milk yield for standard and extended lactations. Interpretation of parameters deserves further attention because of the large variation observed. As expected, the calving to conception interval was found to have a negative effect on milk yield for cows with a standard lactation length. In extended lactations, these negative effects of pregnancy on milk yield were not observed.     

The Transition to Solid-State Lighting

Lighting constitutes more than 20% of total U.S. electricity consumption, a similar fraction in the European Union, and an even higher fraction in many developing countries. Because many current lighting technologies are highly inefficient, improved technologies for lighting hold great potential for energy savings and for reducing associated greenhouse gas emissions. Solid-state lighting shows great promise as a source of efficient, affordable, color-balanced white light. Indeed, assuming market discount rates, engineering-economic analysis demonstrates that white solid-state lighting already has a lower levelized annual cost (LAC) than incandescent bulbs. The LAC for white solid-state lighting will be lower than that of the most efficient fluorescent bulbs by the end of this decade. However, a large literature indicates that households do not make their decisions in terms of simple expected economic value. After a review of the technology, we compare the electricity consumption, carbon emissions, and cost-effectiveness of current lighting technologies, accounting for expected performance evolution through 2015. We then simulate the lighting electricity consumption and implicit greenhouse gases emissions for the U.S. residential and commercial sectors through 2015 under different policy scenarios: voluntary solid-state lighting adoption, implementation of lighting standards in new construction, and rebate programs or equivalent subsidies. Finally, we provide a measure of cost-effectiveness for solid-state lighting in the context of other climate change abatement policies.     

Assessment of personal hygiene and practices of food handlers in municipal public schools of Natal,Brazil

The aim of this study was to assess the hygiene practices of food handlers in municipal schools of Natal, Brazil, where 27 public schools were evaluated, using a checklist and microbiological analysis of hands. It was found that 74.1% of the handlers did not receive periodic training, 51.9% did not undergo annual health examinations and 100% did not practice proper hand hygiene, a situation that reflected significantly (p < 0.05) in hand contamination, in which fecal coliforms were detected on 55.6% of the hands analyzed. It was concluded that the schools studied did not have appropriate hygienic conditions, suggesting the need for interventions that ensure the quality of school food served to the children.     

Adsorption of small molecules on gold single crystal surfaces

Much more work has been carried out on supported gold catalysts (also called “real” catalysts) than on gold single crystal surfaces. However, for fundamental understanding of catalysis by gold, well-defined gold surfaces and controlled conditions using the surface science approach may provide useful information concerning reaction mechanisms and the nature of active centers. This paper presents a brief overview on the work carried out regarding adsorption of several small molecules on gold surfaces from 2004, date of the last review on gold surface science [R. Meyer, C. Lemire, S.K. Shaikhutdinov and H. Freund,Gold Bull., 2004, 37, 72], until recently. Both experimental and theoretical results are discussed. A large difference between the flat Au(111), by far the most studied surface, and stepped/kinked surfaces, is found, demonstrating the importance of low-coordinated Au atoms for high catalytic activity.