全文获取类型
收费全文 | 849篇 |
免费 | 94篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 4篇 |
综合类 | 2篇 |
化学工业 | 359篇 |
金属工艺 | 19篇 |
机械仪表 | 14篇 |
建筑科学 | 18篇 |
矿业工程 | 1篇 |
能源动力 | 39篇 |
轻工业 | 106篇 |
水利工程 | 14篇 |
石油天然气 | 6篇 |
无线电 | 65篇 |
一般工业技术 | 162篇 |
冶金工业 | 13篇 |
原子能技术 | 13篇 |
自动化技术 | 110篇 |
出版年
2024年 | 4篇 |
2023年 | 25篇 |
2022年 | 59篇 |
2021年 | 77篇 |
2020年 | 66篇 |
2019年 | 72篇 |
2018年 | 96篇 |
2017年 | 76篇 |
2016年 | 76篇 |
2015年 | 39篇 |
2014年 | 59篇 |
2013年 | 83篇 |
2012年 | 54篇 |
2011年 | 54篇 |
2010年 | 41篇 |
2009年 | 17篇 |
2008年 | 15篇 |
2007年 | 10篇 |
2006年 | 7篇 |
2005年 | 4篇 |
2004年 | 1篇 |
2001年 | 2篇 |
2000年 | 1篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1992年 | 1篇 |
1989年 | 1篇 |
排序方式: 共有945条查询结果,搜索用时 15 毫秒
101.
Dipyridamole recognition and controlled release by uniformly sized molecularly imprinted nanospheres
Mehdi Esfandyari-Manesh Mehran Javanbakht Fatemeh Atyabi Ali Mohammadi Somayeh Mohammadi Behrouz Akbari-Adergani Rassoul Dinarvand 《Materials science & engineering. C, Materials for biological applications》2011,31(8):1692-1699
We used novel synthetic conditions of precipitation polymerization to obtain uniformly sized molecularly imprinted nanospheres of dipyridamole for application in the design of new drug delivery systems. In addition, the morphology, drug release, and binding properties of molecularly imprinted polymers (MIPs) were studied, and the effects of morphology on other properties were investigated. The MIPs prepared by acetonitrile/chloroform (19:1, v/v) were uniformly sized nanospheres with an average mean diameter of approximately 88 nm at a wetted state, 50 nm at a dry state, and a polydispersity index of 0.062. The imprinted nanospheres showed excellent binding properties and had 62.7% of template binding compared with 17.1% of its blank polymer. The imprinted nanospheres with 67.5 (mg template/of polymer) of binding capacity had better imprinting efficiency than the 50.5% of binding capacity shown by irregularly shaped MIP particles that were prepared by chloroform. The molecular binding abilities of imprinted nanospheres in human serum were evaluated by HPLC analysis (binding about 77% of dipyridamole). Results from release experiments of MIPs showed a very slow, controlled, and satisfactory release of dipyridamole. The loaded drug was released up to 99% in 17 days for nanospheres and 22 days for irregularly shaped particles. 相似文献
102.
Gorji Marzban Anita Herndl Sara Pietrozotto Srijib Banerjee Christian Obinger Fatemeh Maghuly Rainer Hahn Donato Boscia Hermann Katinger Margit Laimer 《Food chemistry》2009
Mal d 2, a thaumatin-like protein from apple was previously described to react to almost 75% of the apple allergic patient sera. Based on the molecular structure of this protein, the present study focused on the conformational stability of Mal d 2 in relation to in vitro IgE-binding under different physico-chemical conditions and proteolysis. The structural integrity of Mal d 2 was monitored using SDS–PAGE, Western blotting using polyclonal antibodies and human sera, fluorescence spectrometry and circular dichroism. Results confirmed the stability of Mal d 2. However, Mal d 2 was reactive to human serum IgEs mainly after reduction of disulphide bridges fixing the α-helical domain II. Contrary to previous assumptions, the current findings suggest that the allergenic epitopes of Mal d 2 are hidden inside the protein structure and none of the rigorous conditions applied in industrial juice processing or digestive proteolysis enhance or reduce the binding to IgE molecules. 相似文献
103.
This paper describes a simple method based on three-phase hollow-fibre liquid-phase microextraction (HF-LPME) for the determination of phenolic acids in fruit juices. Analytes including gallic acid, p-hydroxy benzoic acid, caffeic acid, syringic acid, p-coumaric acid, ferulic acid, and cinnamic acid were separated and determined using high-performance liquid chromatography–photodiode array detection (HPLC–DAD). Parameters affecting the enrichment factors (EFs) were investigated. These compounds were extracted from 5 mL aqueous samples (pH 2) to a thin layer of organic solvent (hexyl acetate) phase impregnated into the pores of the polypropylene hollow fibre wall, and then back extracted to a basic acceptor solution (0.02 M NaOH). EFs ranged from 15 (gallic acid) to 408 (cinnamic acid). The RSD of the method for the analysis of spiked water and fruit juice samples varied from 3.1% to 11.3%. The LODs ranged from 0.01 (cinnamic acid) to 2.0 (caffeic acid) μg/L. 相似文献
104.
A series of biopolymer‐based superabsorbent hydrogels based on carboxymethyl cellulose has been prepared by free‐radical graft copolymerization of acrylamide and 2‐acrylamido‐2‐methylpropan sulfonic acid (AMPS) in aqueous solution using methylenebisacrylamide as a crosslinking agent and ammonium persulfate as an initiator. The effect of variables on the swelling capacity such as: acrylamide/AMPS weight ratio, reaction temperature, and concentration of the initiator and crosslinker were systematically optimized. The results indicated that with increasing the amount of AMPS, the swelling capacity is increased. FT‐IR spectroscopy and scanning electron microscope analysis were used to confirm the hydrogel structure. Swelling measurements of the synthesized hydrogels in different salt solutions indicated considerable swelling capacity. The absorbency under load of the superabsorbent hydrogels was determined by using an absorbency under load tester at various applied pressures. A preliminary swelling and deswelling behaviors of the hydrogels were also studied. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
105.
Mehran Javanbakht Faten Divsar Fatemeh Fatollahi Mohammad Reza Ganjali Marzieh Chaloosi 《Electrochimica acta》2009,54(23):5381-5386
This study introduces the design of an anodic stripping voltammetric (ASV) method for the silver ion determination at a carbon paste electrode (CPE), chemically modified with phenylthiourea-nanoporous silica gel (Tu-SBA-15-CPE). The electroanalytical pro includes two steps: preconcentration of metal ions at an electrode surface, followed by quantification of the accumulated species by differential pulse anodic stripping voltammetric methods. Factors affecting the performance of the anodic stripping were investigated, including the modifier quantity in the paste, the electrolyte concentrations, the solution pH and the accumulation potential or time. The most sensitive and reliable electrode contained 10% Tu-SBA-15 and 90% carbon paste. The accumulation potential and time were set at, −200 mV and 300 s, respectively, and the scan rate at 50 mV s−1 in the scan range of −200 to 700 mV. The resulting electrode demonstrated a linear response over range of silver ion concentration of 8.0-80 pmol/L with detection limit (S/N = 3) of 5 pmol/L. The prepared electrodes were used for the silver determination in sea and tap water samples and very good recovery results were obtained. The accuracy was assessed through recovery experiments and independent analysis by graphite furnace atomic absorption spectrometry. 相似文献
106.
Behrooz Maleki Fatemeh Barakchi Tabrizy Reza Tayebee Mehdi Baghayeri 《Polycyclic Aromatic Compounds》2019,39(2):93-98
Oxidative aromatization of 1,3,5-trisubstituted 2-pyrazolines by in-situ generation of NO+ from oxalic acid/sodium nitrite system has been described. The main advantages of this procedure are the use of an inexpensive and readily available catalyst, facile work-up, and improved yields in aqueous ethanol. 相似文献
107.
Fatemeh Hosseinzadeh Hossein Sarpoolaky 《International Journal of Applied Ceramic Technology》2019,16(4):1544-1556
Taguchi method (TM) and response surface methodology (RSM) have been employed to optimize three parameters, including the amounts of P123, the amounts of nitric acid and calcination temperature, in order to define an optimal setting for sol-gel synthesis of high surface area mesoporous alumina powder (MA). Herein, the comparison of the both statistical approaches has been examined and discussed considering the nitrogen adsorption as the response variable because this important character for mesoporous materials is exceedingly sensitive to the synthesis parameters. The BET surface area (SBET) and pore volume of MA under Taguchi optimal condition were 323.5 m2 g−1 and 0.551 cm3 g−1, respectively, by conducting confirmation test. Furthermore, the confirmation test showed high SBET of MA (363.4 m2 g−1), which was in a good agreement with calculated SBET result (431.25 m2 g−1) by a quadratic model under RSM optimal condition. Moreover, 3D response surface plots and 2D contour plots of desirability have been discussed to visualize the influence of input factors on response variable. It is also concluded that RSM shows more appropriate (12.33% higher SBET than TM) and efficient optimal condition with determining a quadratic function as the relationship between SBET and synthesis parameters. 相似文献
108.
Controlled Preparation and Characterization of Nigella Sativa Electrospun Pad for Controlled Release
Kalhori Fatemeh Arkan Elham Dabirian Farzad Abdi Gisya Moradipour Pouran 《SILICON》2019,11(2):593-601
Silicon - Nigella sativa (NS) oil is an anti-inflammatory agent in the traditional medicine. In the present study, novel electrospun mats contained NS oil/polyacrylonitrile as a sustained release... 相似文献
109.
Shima Ghaffari Maryam Yousefzadeh Fatemeh Mousazadegan 《Polymer Engineering and Science》2019,59(10):2032-2040
The development of functional nanofiber materials with high specific surface area and porosity has been a highly interesting field of research in recent years due to its versatile properties for diverse applications. The combination of nanofibers into material clothes can open up new opportunities to improve comfort performance and thermal management properties. In this work, we demonstrated that the porous lightweight nanofibrous membrane could be coated on the fabric and laminated to improve its thermal comfort. The polyacrylonitrile was electrospun onto the surface of the polyester fabric with three different fineness and laminated with a warp knitted interlining in a controlled condition by sewing/fusing. The effect of the nanofibers diameter, sewing and fusing process on thermal insulation, air permeability, breathability, and water resistance of the obtained three‐layer samples were studied. The results showed that the presence of the nanofibers thin layer could improve the thermal comfort by controlling the studied parameters compared to the external face fabric as control. It was obtained that the fusing technique is more efficient than sewing for this purpose. The fused samples are waterproof and windproof, while instantly venting moisture and had good thermal insulation to protect the body from cold. POLYM. ENG. SCI., 59:2032–2040, 2019. © 2019 Society of Plastics Engineers 相似文献
110.
This paper describes the microwave characterization and wettability of a uniform and light magnetic nanofibers web. Iron oxide nanoparticles/recycled poly (ethylene terephthalate) nanofibers web (Fe3O4 NPs/RPET NFs web) were fabricated from bath-sonication solution via electrospinning method. For environmental conservation and economic reasons, RPET instead of virgin material was used. After synthesizing magnetic Fe3O4 NPs with an average diameter of 35?nm by precipitation method using iron sulfate and sodium hydroxide, Fe3O4 NPs/RPET NFs web was made. The main objective of this work is to show how Fe3O4 NPs are able to significantly modify electromagnetic properties at X-band frequencies. Microwave characterization is based on the microwave scattering parameters measured in the X-band (8–12?GHz). Various characterization methods, including field emission-scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) and vibrating sample magnetometer (VSM), have been used to study morphologies, crystalline structure, magnetic, and wettability properties of NFs web. The saturation magnetization of the Fe3O4 NPs/RPET NFs web at a concentration of 5% was 2.79?emu/g. The mathematical model was estimated for magnetization, diameter and concentration by MathWorks Model Predictive Control Toolbax Software. The wettability, reflection coefficient, absorption coefficient, and EMI shielding of Fe3O4 NPs/RPET NFs web have been improved compared to RPET NFs web. 相似文献