Detection of gases by correlation spectroscopy

This paper describes the detection of various common gases by means of correlation spectroscopy, employing a complementary-source-modulation (CoSM) approach based on compact light-emitting diode (LED) sources. Theoretical results for the quantitative detection of O₂, CO, and CO₂ by this CoSM method are presented, using, as their basis, spectral absorption data from the Hitran database. In demonstrating the proposed detection principle, new experimental results for the detection of O₂ in air are presented, with the use of practical low-cost LED sources.     

Comparison of conventional and soft computing-based power control methods in mobile communications systems

 In this paper, we give a comparison between the conventional power control scheme and soft computing-based approaches in a mobile communications application. At the base station, the `bang–bang' control strategy and a neural network-based prediction control method are employed. In addition, full power command transmission mode, single-bit command transmission mode, and fuzzy logic-based power command enhancement unit are considered. Based on simulation experiments, we quantitatively evaluate the performance of various combinations of these control methods and command transmission modes. Conclusions on the optimal configuration are finally drawn.     

串联补偿技术在远距离高电压交流输电系统中的应用

文章针对远距离,重载,跨区间交流输电系统的稳定及传输容量问题,提出了串联补偿方案,并围绕采用串联补偿技术所应考虑的一些主要问题,以远距输电系统为例进行了讨论,文中还从理论的角度阐述了可控串补提高系统稳定性,增加系统功率传输容量的原理,通过仿真对其有效性进行了论证并与固定串补进行了对比。     

Influence of carbonitriding defects on fatigue strength of 25KhGT gear teeth

Metal Science and Heat Treatment -     

Ligand‐Free Synthesis of Aluminum‐Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color‐Tuned Highly Efficient Organic Solar Cells

The color of polymer solar cells using an opaque electrode is given by the reflected light, which depends on the composition and thickness of each layer of the device. Metal‐oxide‐based optical spacers are intensively studied in polymer solar cells aiming to optimize the light absorption. However, the low conductivity of materials such as ZnO and TiO₂ limits the thickness of such optical spacers to tenths of nanometers. A novel synthesis route of cluster‐free Al‐doped ZnO (AZO) nanocrystals (NCs) is presented for solution processing of highly conductive layers without the need of temperature annealing, including thick optical spacers on top of polymer blends. The processing of 80 nm thick optical spacers based on AZO nanocrystal solutions on top of 200 nm thick polymer blend layer is demonstrated leading to improved photocurrent density of 17% compared to solar cells using standard active layers of 90 nm in combination with thin ZnO‐based optical spacers. These AZO NCs also open new opportunities for the processing of high‐efficiency color tuned solar cells. For the first time, it is shown that applying solution‐processed thick optical spacer with polymer blends of different thicknesses can process solar cells of similar efficiency over 7% but of different colors.     

Enhanced photoluminescence from free-standing microstructures fabricated on MBE grown PbSe–PbSrSe MQW structure

Fabrication of microrods from multi-quantum well (MQW) PbSe–PbSrSe structure grown in molecular beam epitaxy (MBE) followed by its morphological as well as optical characterizations are described. Pulsed PL intensity is increased by 64 times per unit surface area from a free-standing MQW microrod mounted on copper heat sink compared with the bulk sample. Enhancement in side emission power due to the higher optical confinement effect during pulsed photoluminescence (PL) from MQW semiconductor microtube inserted in hollow quartz optical fiber signifies that these microstructures are robust in nature and crucial contenders for portable mid-infrared optoelectronic devices to be used in the field of industrial trace-gas sensing.     

Single‐Step Deposition of Au‐ and Pt‐Nanoparticle‐Functionalized Tungsten Oxide Nanoneedles Synthesized Via Aerosol‐Assisted CVD,and Used for Fabrication of Selective Gas Microsensor Arrays

Tungsten oxide nanostructures functionalized with gold or platinum NPs are synthesized and integrated, using a single‐step method via aerosol‐assisted chemical vapour deposition, onto micro‐electromechanical system (MEMS)‐based gas‐sensor platforms. This co‐deposition method is demonstrated to be an effective route to incorporate metal nanoparticles (NP) or combinations of metal NPs into nanostructured materials, resulting in an attractive way of tuning functionality in metal oxides (MOX). The results show variations in electronic and sensing properties of tungsten oxide according to the metal NPs introduced, which are used to discriminate effectively analytes (C₂H₅OH, H₂, and CO) that are present in proton‐exchange fuel cells. Improved sensing characteristics, in particular to H₂, are observed at 250 °C with Pt‐functionalized tungsten oxide films, whereas non‐functionalized tungsten oxide films show responses to low concentrations of CO at low temperatures. Differences in the sensing characteristics of these films are attributed to the different reactivities of metal NPs (Au and Pt), and to the degree of electronic interaction at the MOX/metal NP interface. The method presented in this work has advantages over other methods of integrating nanomaterials and devices, of having fewer processing steps, relatively low processing temperature, and no requirement for substrate pre‐treatment.