高抗冲共聚聚丙烯的结构与性能

采用核磁共振仪、差示扫描量热仪、扫描电子显微镜等表征了两种高抗冲共聚聚丙烯(HIPP)和汽车保险杠专用聚丙烯(PP)树脂SP179,研究了HIPP和SP179的动态流变行为.由于HIPP中橡胶相的含量较高,导致HIPP与SP179相比在低温下具有较高的悬臂梁缺口冲击强度和弹性.在-30℃时,两种HIPP的悬臂梁缺口冲击...     

依托特色实验室建立应用化学专业创新性实践教学模式

创新性实践教学是高校人才培养的重要环节,本学院近几年来在依托特色实验室建立应用化学专业创新性实践教学新模式方面进行了一些有益的改革探索,并取得了良好的效果,文章从教学内容、方式和手段等方面对其进行了介绍。     

常压组合反应器中连续合成巯基乙酸工艺

研究了以氯乙酸和硫氢化钠为原料,在常压串联组合反应器中连续合成巯基乙酸工艺.考察了原料物质的量比、反应物浓度、反应时间及反应温度等因素对巯荃乙酸收率的影响.结果表明,在氯乙酸与硫氢化钠物质的量比为1:2.5,溶液氯乙酸质量分率20%,硫氢化钠质量分率15%的条件下.反应物料先在连续操作搅拌釜式反应器中于10℃反应10 ...     

乳化液废水震动膜法处理及出水的可生化性分析

考察了震动膜处理2种不同乳化液废水的效果和处理过程中膜通量变化,结果表明,2种乳化液废水经震动膜处理后COD和油去除率分别为95.4％、99.0％和93.5％、99.0％,震动膜出水回收率分别为82.0％和84.3％,出水可生化性较好,适合进一步生化处理;在处理过程中,震动膜装置的膜通量在一定时间内不降反升,说明震动膜...     

Influence of 4-N,N-dimethylaminopyridine on the photovoltaic performance of dye-sensitized solar cells with poly(ethyleneoxide)/oligo(ethylene glycol) blend electrolytes

4-N,N-Dimethylaminopyridine (DMAP) was introduced into poly(ethyleneoxide)/oligo(ethylene glycol) (PEO/PEG) electrolytes for dye-sensitized solar cells (DSCs). The improved photovoltaic performance of DMAP-doped DSCs was attributed to the integrated effects of the upward displacement of the TiO₂ band edge and the decrease in the electron recombination rate. Remarkably, the presence of DMAP suppresses electron recombination via two combined pathways involving the dissociation of triiodide to iodide by a complexation reaction and a modification of the surface state distribution in the band gap of TiO₂. With the addition of DMAP, the open-circuit voltage enhances dramatically. The short-circuit photocurrent density has a small increase at low DMAP concentration and drops afterwards. The power conversion efficiency is 4.07%, which corresponds to a 63% increase over that of the DSC without DMAP.     

Synthesis and electrochemiluminescence studies of tricarbonylrhenium(I) complexes with a cationic 2,2′-bipyridyl ligand

Two new rhenium(I) carbonyl complexes with cationic 2,2′-bipyridyl ligands were synthesized and characterized. The electrogenerated chemiluminescence (ECL) of the rhenium(I) carbonyl complexes was first investigated in aqueous solution using the co-reactant tri-n-propylamine (TPrA). The ECL behavior of the complexes was also studied in the presence of several surfactants. The oxidation of both TPrA and the rhenium(I) complexes was facilitated in the presence of Triton X-100, and the ECL intensity was enhanced 300-fold at a Au electrode.     

Pulsed laser assisted reduction of graphene oxide

We report a simple approach to reduce graphene oxide (GO) solution by pulsed laser irradiation. The reduction was rapidly carried out at room temperature in only 5 min. The reduced graphene oxide (r-GO) was characterized with UV–visible spectroscopy, X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, thermo-gravimetric analysis, Fourier transform infrared spectroscopy, scanning electron microscopy and atomic force microscopy. Based on this reducing method, an r-GO conductive film with a sheet resistance of 53.8 kΩ/sq was obtained. The pulsed laser reduction of GO in solution creates a new way to produce graphene composites for a variety of applications.     

皮革中富马酸二甲酯残留量的GC-MS内标法测定

文章采用乙酸乙酯对皮革样品超声萃取,并经固相萃取柱制备试样,选取丙二酸二甲酯为内标物,建立了气相色谱-质谱联用测定皮革中富马酸二甲酯(DMF)残留量的分析方法.该方法检出限为0.02mg/kg,回收率为84.4%～95.4%,相对标准偏差为1.7%～3.9%,线性范围为0.05～50 mg/kg,可用于皮革或类似材料中...     

Microwave catalytic NOx and SO2 removal using FeCu/zeolite as catalyst

Non-thermal plasma technology is a promising process for flue gas treatment. Microwave catalytic NO_x and SO₂ removal simultaneously has been investigated using FeCu/zeolite as catalyst. The experimental results showed that a microwave reactor with FeCu/zeolite only could be used to microwave catalytic oxidative 91.7% NO_x to nitrates and 79.6% SO₂ to sulfate; the reaction efficiencies of microwave catalytic reduction of NO_x and SO₂ in a microwave reactor with FeCu/zeolite and ammonium bicarbonate (NH₄HCO₃) as a reducing agent could be up to 95.8% and 93.4% respectively. Microwave irradiation accentuates catalytic reduction of SO₂ and NO_x treatment, and microwave addition can increases SO₂ removal efficiency from 14.5% to 18.7%, and NO_x removal efficiency from 13.4% to 18.7%, separately. FeCu/zeolite catalyst was characterized by X-ray diffraction (XRD), X-ray photoelectron spectrum analysis (XPS), scanning electron microscopy (SEM) and the Brunauer Emmett Teller (BET) method. Microwave catalytic NO_x and SO₂ removal follows Langmuir-Hinshelwood (L-H) kinetics.     

Experimental study on critical breakage stress of float glass with different thicknesses under conditions with temperatures of 25 and 200°C

The objective of this study is to directly measure the critical breakage stress for glass through mechanical tensile experiments based on MTS 810 apparatus. Two series of experiments were, respectively, conducted under the condition with a room temperature (25°C) and a hot environment (200°C) for float glass. The results show that the critical breakage stresses of 6, 8, 10 and 12 mm float glass are, respectively, 74, 127, 158 and 198% larger than that of 4 mm float glass under the condition with a room temperature (25°C). Similarly, the critical breakage stresses of 6, 10 and 12 mm float glass are, respectively, 29, 72 and 93% larger than 4 mm glass in the hot environment (200°C). In addition, through the comparison between the two series of experiments, it suggests that the critical breakage stresses of 6, 8, 10 and 12 mm thick float glass in a hot environment are, respectively, 7, 48, 16 and 19% smaller than that in a room temperature. It is suggested that the measured critical breakage stress of float glass here is relatively smaller than those in the previous measurements. Copyright © 2010 John Wiley & Sons, Ltd.