Antioxidant properties of Prangos ferulacea (L.) Lindl., Chaerophyllum macropodum Boiss. and Heracleum persicum Desf. from Apiaceae family used as food in Eastern Anatolia and their inhibitory effects on glutathione-S-transferase

Therapeutic effects of several medicinal plants and vegetables, which are commonly used as food and in folk medicine against many disease, are well known. Antioxidant capacities of Heracleum persicum Desf., Prangos ferulacea (L.) Lindl., Chaerophyllum macropodum Boiss. species from Apiaceae family were evaluated by determining their effects on DPPH radical scavenging, and lipid peroxidation inhibition, as well as their total phenolic contents. Potential natural glutathione-S-transferase inhibitors have gained great importance in the last decade especially because of the role of glutathione-S-transferases in developing resistance to chemotherapy. Selected plants were therefore further investigated for their influence on the activity of glutathione-S-transferase enzyme.     

A fair comparison of SAC-OCDMA system configurations based on two dimensional cyclic shift code and spectral direct detection

This paper investigates shortcomings that limit the performance of optical code division multiple access (OCDMA) systems including the low cardinality and data rate as well as the high power at reception. The main drawback for such systems known as multiple access interference accompanying by phase induced intensity noise is also investigated to effeciencly propose a novel two dimensional cyclic shift (2D-CS) code to be implemented in non-coherent OCDMA systems. The developed code is based on a one dimensional cyclic shift (1D-CS) code previously provided by research works processing spectral amplitude coding for optical code division multiple access (SAC-OCDMA) systems. Numerical results obtained by this study are therefore compared to previous studies employing different codes like two dimensional extended double weight (2D-EDW), two dimensional flexible cross correlation/modified double weight (2D-FCC/MDW), two dimensional perfect difference (2D-PD), two dimensional diluted perfect difference (2D-DPD), two dimensional multi service (2D-MS) and two dimensional zero cross correlation/multi diagonal (2D-ZCC/MD) codes. Accordingly, it is demonstrated that the proposed 2D-CS code outperforms all codes given previously in terms of system capacity where the small increasing percentage is about 40% compared to 2D-ZCC/MD and 2D-MS. Systems using 2D-CS code can support until 203 simultaneous users with a total code length equal to 171. System performance investigation leads to a BER and Q-Factor closely to1.0E?12 and 1.0E?27, and 6.6 dB and 10.6 dB at 20 km of single mode fiber length using white light source and Laser, respectively. Furthermore, such a code can be easily adopted by OCDMA systems for a long distance up to approximately 55 and 100 km.

     

Microstructural Characterization of Reactively Sintered Mullites

Mullite ceramics have been produced by reaction sintering of powders prepared using pseudoboehmite–colloidal silica and aluminum sulfate–colloidal silica mixtures. The microstructural development of these mullites was studied by a number of transmission electron microscopy based techniques including diffuse dark field, Fresnel fringe defocus imaging, and high-resolution transmission electron microscopy. This characterization procedure showed that mullite ceramics free from glassy phases at triple junctions and grain boundaries could be produced from both mixtures using suitable sintering temperatures and alumina/silica ratios. The wetting of grain boundaries by glass, occurring in the mullite ceramics from either incomplete reaction between alumina and silica components or release of silica from the mullite structure with increasing temperature, was found to depend on the prior thermal history of the ceramics.     

Mechanical characterization of highly porous β-Si3N4 ceramics fabricated via partial sintering & starch addition

In this study, porous β-Si₃N₄ ceramics containing limited amount of Sm₂O₃ and CaO as sintering aids were produced by addition of potato starch (10 and 20 vol.%) and partial sintering. Two different Si₃N₄ powders, α- and β-, were used as starting materials. Scanning electron microscopy investigations revealed that development of elongated β-Si₃N₄ grains were much more pronounced when α-Si₃N₄ starting powder was used. Even though porosity values of the compositions prepared by using α-Si₃N₄ (～57.0–58.4%) is significantly higher than the samples produced by β-Si₃N₄ (42.6%), no significant change was observed for the bending strength, fracture toughness and Weibull modulus. This indicates that microstructural features have a significant contribution to the mechanical properties of the porous materials in terms of bending strength and fracture toughness.     

Real-time monitoring of railroad track tension using a fiber Bragg grating-based strain sensor

Railway and train security are very important in preventing service disruption and ensuring quality and safe journeys. Conventional gauges are used in laboratory environments for the strain measurement of rails used in railways. However, the use of these electrical sensors is not practical in long-distance railways. Instead, access to long distances is possible with fiber optic sensors. In this study, the strain of 49E1 type rail with R260 hardness and quality was calculated theoretically. These results were compared with an experimentally established fiber Bragg grating system. Moreover, a user-friendly interface was prepared for real-time monitoring of the system. Upon examining the results, the maximum deviation at a rate of 2.5% occurred in the strain measurement in the rail in response to force changes between 0 and 200 kN. A value of approximately 1.38?pm/µε was calculated between the wavelength/strain changes.     

Preparation and characterization of membranes obtained from blends of acrylonitrile copolymers with poly(vinyl alcohol)

New microfiltration and ultrafiltration membranes were obtained using acrylonitrile‐vinyl acetate copolymers in mixture with poly(vinyl alcohol) (PVA). Thus, a blend polymer solution was prepared in dimethylsulfoxide (DMSO) and used to obtain bicomponent polymer membranes by phase inversion. The rheological behavior of the DMSO polymer solutions was, mostly, dilatant at low shear gradients and pseudo plastic with quasi Newtonian tendency at higher gradients. Membranes were characterized by Fourier transform infrared spectrometry (FTIR), optical microscopy, atomic force microscopy, thermal gravimetric analysis‐differential thermal gravimetry, and pure water flux (PWF). FTIR spectra displayed the characteristic bands for acrylonitrile, vinyl acetate, and PVA. The morphology and the porosity can be tailored by the preparation conditions. PVA allows controlling the size of the pores and enables, in principle, to use the resulted membranes as supports for enzyme immobilization. PVA content influences the thermal stability. PWF values depend on the copolymer, on the content in PVA, but also on the coagulation bath composition. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 41013.     

An effective synthesis route for improving the catalytic activity of carbon-supported Co–B catalyst for hydrogen generation through hydrolysis of NaBH4

A novel method for synthesis of carbon-supported cobalt boride catalyst was developed for hydrogen generation from catalytic hydrolysis of NaBH₄ solution. The activated carbon and carbon black supported catalysts prepared by “reduction–precipitation” method were found to be much more active than those prepared by conventional “impregnation–reduction” method inspite of the same Co content. A maximum hydrogen generation was achieved using carbon black supported Co–B, which lowers the activation energy to 56.7 kJ mol⁻¹. The effects of NaOH concentration (1–15 wt.%), NaBH₄ concentration (5–20 wt.%) and reaction temperature (25–40 °C) on the performance of the most active catalyst (Co–B/C_B) were investigated in detail. The results indicated that this catalyst can be used in a hydrogen generator for mobile applications such as PEMFC systems due to its high catalytic activity and simple preparation method.     

Gravitational pose estimation

Problem of relative pose estimation between a camera and rigid object, given an object model with feature points and image(s) with respective image points (hence known correspondence) has been extensively studied in the literature. We propose a “correspondenceless” method called gravitational pose estimation (GPE), which is inspired by classical mechanics. GPE can handle occlusion and uses only one image (i.e., perspective projection of the object). GPE creates a simulated gravitational field from the image and lets the object model move and rotate in that force field, starting from an initial pose. Experiments were carried out with both real and synthetic images. Results show that GPE is robust, consistent, and fast (runs in less than a minute). On the average (including up to 30% occlusion cases) it finds the orientation within 6° and the position within 17% of the object’s diameter. SoftPOSIT was so far the best correspondenceless method in the literature that works with a single image and point-based object model like GPE. However, SoftPOSIT’s convergence to a result is sensitive to the choice of initial pose. Even “random start SoftPOSIT,” which performs multiple runs of SoftPOSIT with different initial poses, can often fail. However, SoftPOSIT finds the pose with great precision when it is able to converge. We have also integrated GPE and SoftPOSIT into a single method called GPEsoftPOSIT, which finds the orientation within 3° and the position within 10% of the object’s diameter even under occlusion. In GPEsoftPOSIT, GPE finds a pose that is very close to the true pose, and then SoftPOSIT is used to enhance accuracy of the result. Unlike SoftPOSIT, GPE also has the ability to work with three points as well as planar object models.     

Comparison of SPIN and VIS for protocol verification

In this paper, we compare and contrast SPIN and VIS, two widely used formal verification tools. In particular, we devote special attention to the efficiency of these tools for the verification of communications protocols that can be implemented either in software or hardware. As a basis of our comparison, we formally describe and verify the Asynchronous Transfer Mode Ring (ATMR) medium access protocol using SPIN and its hardware model using VIS. We believe that this study is of particular interest as more and more protocols, like ATM protocols, are implemented in hardware to match high-speed requirements. Published online: 1 March 2002     

Incremental discovery of new defects: application to screwing process monitoring

Defect detection by in-process monitoring plays a key role in the traceability and optimization of production. Many fault detection algorithms are trained on known faults. However, industrial data is generally unlabeled and certain faults are unknown or missing in the training dataset. This paper presents an original approach for the incremental discovery of new manufacturing defects, by Bayes rule and distance rejection. Rejects are analyzed periodically to determine the possible appearance of new defect cluster among them. Visualization then supports the cluster interpretation by a manufacturing expert. The approach was successfully applied to a screwing database from automotive industry.