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1.
Fernando J. Muzzio Marcos Llusa Christopher L. Goodridge Nhat-Hang Duong Elizabeth Shen 《Powder Technology》2008,186(3):247-254
This paper investigates the effects of processing and equipment parameters of a ribbon blender (i.e. loading method of lubricant, fill level, blade speed and blade design) on magnesium stearate homogeneity. A core sampling technique is used to obtain at least one hundred samples per sampling event, which are extracted throughout the blender and yield a thorough characterization of the entire bed. The results presented here can be used as a guideline to develop appropriate blending processes and characterization protocols for ribbon blenders. 相似文献
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Fernando J Beltrn F Javier Rivas Olga Gimeno 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(9):973-984
Photocatalytic ozonation (1O3 + VUV + TiO2), ozonation (O3), catalytic ozonation (O3 + TiO2), ozone photolysis (O3 + VUV), photocatalysis (TiO2 + VUV) and photolysis (VUV) have been compared in terms of formation of intermediates, extent of, mineralization (TOC, COD, chloride, nitrate) and kinetics in the aqueous treatment of three phenols (phenol, p‐chlorophenol and p‐nitrophenol). In all cases, photocatalytic ozonation led to lower degradation times for chemical oxygen demand and total organic carbon removal. Intermediates formed were similar in the different oxidation systems with some exceptions. They can be classified into three different types: polyphenols (resorcinol, catechol, hydroquinone), unsaturated carboxylic acids (maleic and fumaric acids) and saturated carboxylic acids (glyoxylic, formic and oxalic acids). First order kinetic equations have been checked for the oxidation processes studied in the case of the parent compound. Rate constants of these systems have also been calculated. Copyright © 2005 Society of Chemical Industry 相似文献
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Alexander Pavlov Gonzalo D Garcia De Fernando Juan A Ordoez Lorenzo Hoz 《Journal of the science of food and agriculture》1994,64(2):141-143
The β-hydroxyacyl-CoA-dehydrogenase (HADH) activity of unfrozen and thawed frog legs was investigated. The enzyme was extracted by either immersing frog legs in phosphate buffer 0.1 M, pH 6.0 at 25°C for 15 min or pressing them between trichinoscopy glasses. The enzyme activity was assayed using acetoacetyl-CoA as substrate and measured spectrophotometrically at 340 nm. It was possible by both extraction methods to distinguish between thawed and unfrozen samples although when the juice was obtained by pressing the HADH activity of the dilution was ~ 1.5 times higher than that obtained by immersion. The HADH activity was significantly higher (P≤0·001) in frozen-thawed frogs than in unfrozen legs because during freezing there is a release of HADH. No significative differences were found in the HADH activity in samples frozen in the temperature range -10 to -196°C. HADH activity was not affected by the storage time in crushed ice up to 6 days. 相似文献
7.
Krick R.F. Clark L.T. Deleganes D.J. Wong K.L. Fernando R. Debnath G. Banik J. 《Solid-State Circuits, IEEE Journal of》1994,29(12):1455-1463
An implementation of the Pentium microprocessor architecture in 0.6 μm BiCMOS technology is described. Power dissipation is reduced and performance is enhanced over the previous generation. Processor features, implementation technology, and circuit techniques are discussed. An internal clock rate of 150 MHz is achieved at 3.7 V and -55°C 相似文献
8.
Javier Lara-Romero Rafael Maya-Yescas José Luis Rico-Cerda José Luis Rivera-Rojas Fernando Chiñas Castillo Matey Kaltchev 《Thin solid films》2006,496(2):463-468
The thermal decomposition of model extreme-pressure lubricant additives on clean iron was studied in ultrahigh vacuum conditions using molecular beam strategies. Methylene chloride and chloroform react to deposit a solid film consisting of FeCl2 and carbon, and evolve only hydrogen into the gas phase. No gas-phase products and less carbon on the surface are detected in the case of carbon tetrachloride. Dimethyl and diethyl disulfide react on clean iron to deposit a saturated sulfur plus carbon layer at low temperatures (∼600 K) and an iron sulfide film onto a Fe + C underlayer at higher temperatures (∼950 K). Methane is the only gas-phase product when dimethyl disulfide reacts with iron. Ethylene and hydrogen are detected when diethyl disulfide is used. 相似文献
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Reda Karoum Antonio de Lucas-Consuegra Fernando Dorado Jose Luis Valverde Alain Billard Philippe Vernoux 《Journal of Applied Electrochemistry》2008,38(8):1083-1088
The electrochemical promotion of catalysis (EPOC) of propene combustion was investigated using Pt sputtered thin film on an
O2− conductor, 8 mol% Y2O3-stabilized-ZrO2 (YSZ). In order to separate the influence of the thermal migration of the O2− oxide ions from the electrolyte to the catalyst surface and the impact of an electrical polarization on the catalytic activity,
several light-off experiments (cool down and heat up procedures) were successively performed under different polarizations,
i.e. OCV, +2 and −2 V. These experiments have clearly shown that the presence of O2− (thermally or electrochemically induced) inhibits the catalytic activity of the platinum for the propene deep oxidation.
These results demonstrate the importance to define a normalized rate enhancement ratio, ρ
n
, from a reference value of the catalytic rate corresponding to a Pt surface state free of O2− ions. 相似文献