PdO/Pd system equilibrium phase diagram under a gas mixture of oxygen and nitrogen

The thermal equilibrium decomposition properties of the PdO-Pd system under oxygen partial pressures ranging from 0.1 to 1.0 atm in a total combined pressure of oxygen and nitrogen of 1.0 atm were investigated by means of thermal-gravimetric analyses. The phase diagram of Pd-PdO over the range of oxygen/nitrogen gas concentration was established. The decomposition temperature of PdO to Pd was found to increase with the partial pressure of oxygen.     

Evaluating the mixing performance of a ribbon blender

This paper investigates the effects of processing and equipment parameters of a ribbon blender (i.e. loading method of lubricant, fill level, blade speed and blade design) on magnesium stearate homogeneity. A core sampling technique is used to obtain at least one hundred samples per sampling event, which are extracted throughout the blender and yield a thorough characterization of the entire bed. The results presented here can be used as a guideline to develop appropriate blending processes and characterization protocols for ribbon blenders.     

Comparison between photocatalytic ozonation and other oxidation processes for the removal of phenols from water

Photocatalytic ozonation (1O₃ + VUV + TiO₂), ozonation (O₃), catalytic ozonation (O₃ + TiO₂), ozone photolysis (O₃ + VUV), photocatalysis (TiO₂ + VUV) and photolysis (VUV) have been compared in terms of formation of intermediates, extent of, mineralization (TOC, COD, chloride, nitrate) and kinetics in the aqueous treatment of three phenols (phenol, p‐chlorophenol and p‐nitrophenol). In all cases, photocatalytic ozonation led to lower degradation times for chemical oxygen demand and total organic carbon removal. Intermediates formed were similar in the different oxidation systems with some exceptions. They can be classified into three different types: polyphenols (resorcinol, catechol, hydroquinone), unsaturated carboxylic acids (maleic and fumaric acids) and saturated carboxylic acids (glyoxylic, formic and oxalic acids). First order kinetic equations have been checked for the oxidation processes studied in the case of the parent compound. Rate constants of these systems have also been calculated. Copyright © 2005 Society of Chemical Industry     

Data collection: evaluation of a pilot model

The overall purpose of this study was to explore nurses' feelings about the applicability and adequacy of a pilot model of nursing assessment (PMNA) developed for coronary care units (CCU) in order to obtain data that could help in establishing a definitive model. The evaluation, performed by 11 CCU nurses, showed that they considered the development and implementation of PMNA as valuable, and that its design was adequate for interviewing cardiac patients. These results will be employed in the elaboration of a definitive model of nursing assessment.     

Concatenated fibre-wireless channel identification in a multiuser CDMA environment

Radio-over-fibre (ROF) has received increasing attention for its ability to enable broadband wireless access. This fibre-based wireless access scheme meets the demand for broadband service by integrating the high capacity of optical networks with the flexibility of radio networks (the optical and wireless channels are concatenated with one another). There are, however, impairments that come with this appealing technology. The nonlinear distortion of the optical link and the multipath dispersion of the wireless channel are two of the major factors. In order to limit the effects of these distortions, estimation, and subsequently equalisation, of the concatenated fibre- wireless channel needs to be done. An estimation algorithm for the fibre-wireless uplink in a multiuser code division multiple access (CDMA) environment is presented using pseudonoise training sequences. It has already been shown by Fernando et al. (2001) that identification of the fibre- wireless uplink is possible in a single user CDMA environment. However, the more difficult task of identification in a multiuser spread spectrum environment, which is more realistic, is shown. In the multiuser case, the cumulative effect of multiuser interference, multipath dispersion, nonlinear distortion and noise should all be handled together which makes it more challenging. Numerical evaluations of the developed algorithm show that a good estimation of both the linear and nonlinear systems is possible in the presence of 16 independent users and an signal- to-noise ratio (SNR) of 22 dB. The estimation accuracy increases with the length of the PN sequence.