OH and COOH functionalized single walled carbon nanotubes-reinforced alumina ceramic nanocomposites

Alumina ceramics reinforced with 1 wt.% single-walled carbon nanotube (SWCNT) were fabricated via spark plasma sintering (SPS) of composite powders containing carboxyl (COOH) or hydroxyl (OH) group functionalized single-walled carbon nanotubes. The samples were SPS’ed at 1600 °C under 50 MPa pressure for holding time of 5 min and at a heating rate of 4 °C/s. The effects of CNT addition having different surface functional groups on microstructure, conductivity, density and hardness were reported. It was shown that nanotube addition decreased the grain sizeof alumina from 3.17 μm to 2.11 μm for COOH-SWCNT reinforcement and to 2.28 μm for COOH-SWCNT reinforcement. The hardness values of the composites are similar for all samples but there is 4.5 and 7.5 times increase in electrical conductivity with respect to monolithic alumina for COOH-SWCNT and OH-SWCNT, respectively. It was also shown by TEM and FEG SEM observations that transgranular fracture behaviour of alumina was changed to mostly intergranular fracture mode by the addition of both types of CNTs which may be due to location of CNTs along the grain boundaries. A significant grain size reduction in alumina is considered toresult fromthe suppressing effect of CNTs during sintering.     

Investigation of wind characteristics and assessment of wind-generation potentiality in Uludağ-Bursa,Turkey

In this study, wind characteristic and wind energy potential of the Uluda? skinning which is located in the south Marmara region of Turkey were analyzed using the wind speed data collected during the period 2000–2006. The wind speed distribution curves of Uluda?-Bursa were obtained by using the Weibull and Rayleigh probability density functions. The average Weibull shape parameter k and scale parameter c were found as 1.78 and 7.97 m/s for the period 2000–2006. The yearly mean wind speed in Uluda?-Bursa was obtained as 7.08 m/s for period of 7 years. A technical and economic assessment has been made of electricity generation from four wind turbines having capacity of (600, 1000, 1500 and 2000 kW). The yearly energy output, capacity factor and the electrical energy cost of kW h produced by the three different turbines were calculated. The cost of each kW h produced using the chosen wind turbines in Uluda?-Bursa were found to between 0.255 and 0.306 $/kW h.     

Evaluation of wind energy potential and electricity generation at six locations in Turkey

In this study, wind characteristics were analyzed using the wind speed data collected of the six meteorological stations in Turkey during the period 2000–2006. The annual mean wind speed of the six stations (Erzurum, Elaz??, Bingöl, Kars, Manisa and Ni?de) is obtained as 8.7, 8.5, 5.9, 6.9, 7.4 and 8.0 m/s at 10 m height, respectively. The mean annual value of Weibull shape parameter k is between 1.71 and 1.96 while the annual value of scale parameter c is between 6.81 and 9.71 m/s. A technical assessment has been made of electricity generation from four wind turbines having capacity of (600 kW, 1000 kW, 1500 kW and 2000 kW). The yearly energy output and capacity factor for the four different turbines were calculated.     

Hydrogen desorption kinetics of MgH2 synthesized from modified waste magnesium

In the present study, hydrogen desorption properties of magnesium hydride (MgH₂) synthesized from modified waste magnesium chips (WMC) were investigated. MgH₂ was synthesized by hydrogenation of modified waste magnesium at 320 °C for 90 min under a pressure of 6 × 10⁶ Pa. The modified waste magnesium was prepared by mixing waste magnesium with tetrahydrofuran (THF) and NaCl additions, applying mechanical milling. Next, it was investigated by X-ray diffraction (XRD), X-ray fluorescence (XRF), scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) techniques in order to characterize its structural properties. Hydrogen desorption properties were determined by differential scanning calorimetry (DSC) under nitrogen atmosphere at different heating rates (5, 10, and 15 °C/min). Doyle and Kissenger non-isothermal kinetic models were applied to calculate energy (E _a ) values, which were found equal to 254.68 kJ/mol and 255.88 kJ/mol, respectively.     

Comparison of the impact of some Minkowski metrics on VQ/GMM based speaker recognition

This paper evaluates the impact of three special forms of the Minkowski metric (Euclidean, City Block, and Chebychev distances) on the performance of the conventional vector quantization (VQ) and Gaussian mixture model (GMM) based closed-set text-independent speaker recognition systems, in terms of recognition rate and confidence on decisions. For the VQ based system, evaluations are carried out using the two most common clustering algorithms, LBG and K-means, and it is revealed which clustering algorithm and distance pair should be used to exploit the best attribute of both to achieve the best recognition rate for a given codebook size. In the case of GMM based system, we introduce the metrics into the GMM using a concatenation of the LBG and K-means algorithms in estimating the initial mean vectors, to which the system performance is sensitive, and explore their impact on system performance. We also make comparison of results obtained from evaluations on clean speech (TIMIT) and telephone speech databases (NTIMIT and NIST2001) with the modern classifiers VQ-UBM and GMM-UBM. It is found that there are cases where conventional VQ based system outperforms the modern systems. Moreover, the impact of distance metrics on the performance of the conventional and modern systems depends on the recognition task imposed (verification/identification).     

Energy inputs and crop yield relationships in greenhouse winter crop tomato production

In this study, energy use patterns and the relationship between energy inputs and yield for single crop (winter) greenhouse tomato production were examined in Antalya province, one of the most important greenhouse centres in Turkey. Data were collected using face-to-face surveys from 85 farms producing winter greenhouse tomatoes. The results indicated that the bulk of energy was consumed in fertilizer (38.22%), electricity (27.09%), manure (17.33%) and diesel-oil (13.65%). Average yield and energy consumption were calculated as 57,905.1 kg/ha and 61,434.5 MJ/ha, respectively. Results also determined an output–input ratio of 0.8 and a respective energy productivity and specific energy of 1.061 MJ/t and 0.94 kg/MJ. In addition, the Cobb Douglas production function was applied to test the relationship among different forms of energy consumption. The findings suggested that single crop tomato producers must optimize their use of indirect energy resources. Single crop producers applied an excess use of chemicals, resulting in an inverse effect on yield as well as imposing risks to natural resources and human health. This research suggested an expansion in energy use training opportunities to greenhouse farmers in the region.     

Active packaging of ground beef patties by edible zein films incorporated with partially purified lysozyme and Na2EDTA

In this study, antimicrobial activity of zein films incorporated with partially purified lysozyme and disodium ethylenediaminetetraacetic acid (Na₂EDTA) has been tested on selected pathogenic bacteria and refrigerated ground beef patties. The developed films containing 700 μg cm^?2 lysozyme and 300 μg cm^?2 Na₂EDTA showed antimicrobial activity on Listeria monocytogenes, Escherichia coli O157:H7, and Salmonella typhimurium. The application of lysozyme and Na₂EDTA incorporated zein films on beef patties significantly decreased total viable counts (TVC) and total coliform counts after 5 days of storage compared to those of control patties (P < 0.05). Zein films incorporated with lysozyme and Na₂EDTA or Na₂EDTA alone significantly slowed down the oxidative changes in patties during storage (P < 0.05). Redness indices of patties coated with zein films were significantly lower than those of uncoated control patties during storage (P < 0.05). This study demonstrated the potential usage of zein films containing lysozyme and Na₂EDTA for active packaging of refrigerated meat products.     

Promising anode candidates for direct ethanol fuel cell: Carbon supported PtSn-based trimetallic catalysts prepared by Bönnemann method

To find an efficient anode catalyst for ethanol electrooxidation, several trimetallic PtSnM/C (M = Ni, Co, Rh, Pd) and their corresponding bimetallic PtX/C (X = Sn, Ni, Co, Rh, Pd) catalysts were synthesized by Bönnemann's colloidal precursor method and evaluated by comparing their electrocatalytic activity using conventional electrochemical techniques. For better understanding of the catalyst deactivation during the ethanol electrooxidation, chronoamperometric test was also combined to X-ray photoelectron spectroscopy (XPS) analysis. A significant finding is that trimetallic compositions PtSnCo/C and PtSnNi/C have enhanced activity compared to that of PtSn/C, with lower onset potential for ethanol electrooxidation and notably improved peak current densities. Thus the presence of Ni and Co heteroatom seems to promote C–C bond cleavage and facilitate the removal from the catalyst surface of adsorbed intermediates. These trends are satisfactorily confirmed by testing in a direct ethanol fuel cell (DEFC), since trimetallic PtSnNi/C and PtSnCo/C anode catalysts have significantly higher overall performance and peak power density than Pt/C, PtSn/C or other trimetallic catalyst compositions PtSnRh/C or PtSnPd/C. Furthermore, the presence of Ni or Co helps to improve the weak stability of PtSn/C by providing a stronger Pt–carbon support interaction. XPS results revealed that the surface Pt/Sn atomic ratio of PtSnNi/C catalyst only slightly decreased even after 12 h at 500 mV. On the other hand, a higher concentration of oxide species appeared on the treated PtSn/C surface as a result of a high degradation of carbon support.