State-based predictions with self-correction on Enterprise Desktop Grid environments

The abundant computing resources in current organizations provide new opportunities for executing parallel scientific applications and using resources. The Enterprise Desktop Grid Computing (EDGC) paradigm addresses the potential for harvesting the idle computing resources of an organization’s desktop PCs to support the execution of the company’s large-scale applications. In these environments, the accuracy of response-time predictions is essential for effective metascheduling that maximizes resource usage without harming the performance of the parallel and local applications. However, this accuracy is a major challenge due to the heterogeneity and non-dedicated nature of EDGC resources. In this paper, two new prediction techniques are presented based on the state of resources. A thorough analysis by linear regression demonstrated that the proposed techniques capture the real behavior of the parallel applications better than other common techniques in the literature. Moreover, it is possible to reduce deviations with a proper modeling of prediction errors, and thus, a Self-adjustable Correction method (SAC) for detecting and correcting the prediction deviations was proposed with the ability to adapt to the changes in load conditions. An extensive evaluation in a real environment was conducted to validate the SAC method. The results show that the use of SAC increases the accuracy of response-time predictions by 35%. The cost of predictions with self-correction and its accuracy in a real environment was analyzed using a combination of the proposed techniques. The results demonstrate that the cost of predictions is negligible and the combined use of the prediction techniques is preferable.     

Estimating maize ground cover using spectral data from Aqua-MODIS in Córdoba,Argentina

Ground cover by foliage is a biophysical property of vegetation linked both to the interception of photosynthetically active radiation and to the crop transpiration rate. The spectral information provided by the Moderate Resolution Imaging Spectroradiometer on board the Aqua (Aqua-MODIS) satellite, which has a spatial resolution of 250 m, is an observation and monitoring resource that may be appropriate for estimating the ground cover of maize when plots exceed 40 ha. In this research, 10 maize plots were monitored in the central region of the province of Córdoba, Argentina, during the 2005–2006 growing season, obtaining photographic records of ground cover and soil moisture data. The normalized difference vegetation index (NDVI) of the Aqua-MODIS images showed a significant linear relationship with maize ground cover which, when the complete cycle is taken into account, is sufficient to explain 87% of the variability of ground cover, with an RMSE of 9%, a level of accuracy that increases when the crop is in the vegetative stage and the moisture conditions of the soil are less limiting. Other vegetation indices and linear mixed models were assessed. In addition to using data from the red and near-infrared channels, they incorporate information about soil conditions, but they showed no predictive advantages compared to the NDVI, resulting in simple models that explained between 77% and 87% of the variability of ground cover, with RMSE values of between 9% and 14%.     

Batch treatment of liquid fraction of pig slurry by intermittent aeration: process simulation and microbial community analysis

BACKGROUND: Manure treatment in intensive livestock farming is required to reduce the risk of negative environmental impacts by nitrogen disposal. Biological removal through intermittent aeration in a single bioreactor is a suitable method for this purpose. The characteristic operation based on the alternation of oxic/anoxic phases confers these systems with certain particularities in terms of process modelling and of understanding the microbial interactions. RESULTS: The performance of a sequencing batch reactor (SBR) treating raw liquid fraction of pig slurry (LFPS) under loading rates of 0.13 g N L^?1 d^?1 was studied. Three different aeration strategies were applied: (1) constant airflow; (2) dissolved oxygen (DO) set‐point; and (3) DO‐based real‐time control. The comparatively low aeration intensity applied throughout the third strategy resulted in the process being performed mainly via nitrite, implying a reduction on the requirements of organic carbon and oxygen. However, a decrease in the nitrification rate was observed under those conditions. Experimental results were satisfactorily simulated by a mathematical model focused on organic carbon and nitrogen removal. Microbial community structure analysis through denaturing gradient gel electrophoretic profiling of 16S rDNA genes showed that the aeration exerted a strong influence on the dominant microbial populations. The presence of the ammonia‐oxidizing species Nitrosomonas europaea, and of denitrifying bacteria related to Thauera sp. and Ralstonia sp., was detected in the strategy at low DO. CONCLUSION: Dependence of model statement and parameter values on the bioreactor operational patterns and piggery wastewater composition was evidenced. Oxygen limitation was responsible for a significant microbial shift in SBR treating LFPS. Copyright © 2009 Society of Chemical Industry     

Detecting vegetable oil adulteration in hazelnut paste (Corylus avellana L.)

The possibilities of detecting hazelnut paste adulterated with refined and non-refined vegetable oils have been studied. Research was focussed mainly on peanut, high oleic-acid sunflower, corn and soybean oils which have a similar composition to hazelnut oil. The analytical procedures to detect fatty acid (FA), triacylglycerol (TAG) and tocopherol profiles as indicators of adulteration were determined. The better indicators experimentally determined were seven FA (palmitic, stearic, linoleic, linolenic, arachidonic, behenic and lignoceric acids) and different TAG with three unsaturated FA (the code letters used for FA are: P = C_16:0; S = C_18:0; O = C_18:1; L = C_18:2;; L_n = C_18:3) (LLL_n, LLL and OOO), two unsaturated FA (POL, PLL and SOO), and one unsaturated FA (PPL). As expected, when refined vegetable oils were added to hazelnut paste, the increment of stigmasta-3,5-diene allowed detection at levels of 2% oil added. Limits of detection were measured using standard and adulterated hazelnut with different amounts of non-refined vegetable oils added (5%, 10%, 20% and 30%). The distribution of tocopherols and tocotrienols is highly useful, except in the case of added sunflower oil. The differences between the experimental and theoretical values of the TAG with equivalent carbon number (ΔECN) of 42 does not improve the detection limit of hazelnut paste adulterated with peanut or sunflower oils. Similarly, tocopherols usually added to refined vegetable oils as an antioxidant were also determined.     

The longitudinal electrical conductivity of metal-matrix composites at cryogenic temperature in the presence of a longitudinal magnetic field

We solve the Boltzmann equation in the relaxation time approximation with parallel E and B fields parallel to the continuous fibres reinforcing a metal matrix. It is shown that this solution is identical to that described by us elsewhere, except for the addition of the cyclotron frequency. The addition of the cyclotron frequency term shows that the electrons follow helical paths as they drift down the composite. The boundary considered is either the external or the internal surface of a cylinder representing the fibre. To apply this solution to metal-matrix composite materials we assumed that the cylindrical fibres are non-conducting cylinders in a matrix of pure crystalline metal. The electron mean free path is never greater than half the fibre separation distance. In a companion paper we discuss the application of this solution to metal-matrix composites.     

High temperature lithium cells using conversion oxide electrodes

Oxidized stainless steel electrodes containing chromium oxides without any conducting additives or binder have been successfully cycled at high temperatures (up to 100 °C) in organic solvent-based electrolytes with high reversibility. Cycling at high temperature results in an enhancement of the capacity at lower voltages, which is maintained upon cycling. After studying different electrolyte candidates, the best results were obtained using lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) dissolved in ethylene carbonate.     

Synthesis and characterization of core–shell SiO2@(Er3+,Yb3+):Lu2O3

We synthesized crystalline Erbium Er³⁺ and Ytterbium Yb³⁺ codoped -Lu₂O₃ nanolayers on SiO₂ microspheres using the modified Pechini method. Two different kinds of precursors, nitrates and chlorides, have been used leading to a layer-to-layer morphology and necklaces structures, respectively. In both cases, the size of nanocrystallites constituting the optical active layer is around 5 nm. We performed X-ray powder diffraction to confirm the cubic crystalline structure of the sesquioxides layer. High resolution transmission electron microscopy analyses corroborate the crystalline nature of the layer. The optical emission of Er³⁺ in the visible range has been recorded.     

Effects of natural antioxidants on the lipid profile of electron beam‐irradiated beef burgers

The purpose of this study was to assess the efficacy of rosemary and oregano extracts in avoiding oxidative changes in beef burgers, and to evaluate the fatty acid profile of these products after electron beam exposition. Extracts, individually or in combination, were added to beef burgers and compared to synthetic antioxidants commonly used in food (butylated hydroxytoluene, butylated hydroxyanisole). The ground beef were submitted to electron beam irradiation at doses of 0, 3.5 and 7 kGy, and stored for 90 days. At regular time intervals, lipid oxidation and fatty acid composition were evaluated through measurement of thiobarbituric acid‐reactive substances (TBARS) and gas chromatography, respectively. The results indicate that, although the irradiation process triggers an increase in the lipid oxidation ratio expressed by TBARS values, great changes in the fatty acid profiles were not observed; instead, they continued to present characteristics very similar to that of non‐irradiated beef. Thus, as irradiation doses of up to 7 kGy for frozen meat can make foods safe from foodborne pathogens, natural antioxidants derived from spices are able to reduce and avoid lipid changes that may cause a deterioration of the sensory quality of these foods, and these natural extracts offer a good choice for replacing synthetic additives.     

Life-cycle assessment of electricity from biomass: Case studies of two biocrops in Spain

Through the Renewable Energies Plan 2000–2010, Spain has fixed the objective of covering 12% of the primary energy demand from renewable sources. The achievement of this objective implies an annual increase of 22.4% of the energy produced from renewable sources. In this context, the objective of this study is to determine if the electricity from biomass produced in Spain would be environmentally competitive with electricity from natural gas or from the Spanish electricity mix. For that, the environmental impacts associated to the whole life cycle of two energetic crops in Spain, Poplar and Ethiopian mustard, used for power generation were evaluated. The overall assessment includes the cultivation and collection of biomass, its transport and the processes of its energetic transformation. We calculated different scenarios of electricity production from biomass in different capacity power plants (10, 25 or 50 MW), different transport scenarios and different productivities for biomass production. Our results show that, given the assumptions of this study, Ethiopian mustard is more impacting than Poplar when used for electricity production. Also, the transportation of biomass from the field to the power plant is an important stage that has to be carefully planned in order to get the maximum amount of electricity with a minimum environmental impact. Compared to electricity from natural gas or the Spanish electricity mix, the electricity obtained from biomass is more impacting in three from six impact categories we present here.     

Remarks on the use of Boltzmann's equation for electrical conduction calculations in metal matrix and in situ composites

The Boltzmann equation and its solutions are cental to the development of microscopic models describing the longitudinal and transverse electrical conductivity of metal matrix and in situ composites. Such solutions are needed to describe electron and phonon scattering and transport phenomena in the matrix due to the presence of a second filamentary phase, and to describe electrical conductivity at cryogenic and higher temperatures. In this paper, we derive solutions to the Boltzmann equation in the relaxation time approximation in cylindrical coordinates. It is shown that one solution for the electric field parallel to the fibre direction leads to an expression for composite conductivity at cryogenic and higher temperatures. We also present a solution for the case in which the electric field is normal to the fibre direction.