糠醛渣对染料甲基紫的吸附行为

以废弃物糠醛渣为原料制备吸附剂,研究了甲基紫溶液在糠醛渣上的吸附行为,并从热力学和动力学角度探讨了吸附作用机理。吸附平衡模型研究表明,糠醛渣对甲基紫的吸附符合Langmuir与Freundlich型的复合型吸附,即单层吸附和吸附剂表面非均质吸附同时存在;吸附动力学研究表明,糠醛渣对甲基紫的吸附符合准二级吸附动力学方程;热力学参数,ΔG0为-6.667 kJ.mol^-1--8.216kJ.mol^-1、ΔH0为16.866kJ.mol^-1、ΔS0为0.079 kJ.mol^-1.K^-1、为14.753 kJ.mol^-1,说明糠醛渣对甲基紫的吸附是自发进行的、吸热的,且主要为一物理吸附过程。糠醛渣作为吸附剂处理甲基紫废水,是一种有效的方法。该方法实现了以废治废的废物资源化目标,具有良好的社会效益和经济效益.     

基于ARM7的蓄电池组在线监测装置的设计

在研究蓄电池组单体电池电压信号接入A/D转换器需要解决抗高共模电压问题的基础上,提出了一种差分运放与隔离运放相结合的高性能价格比解决方案.基于Philips LPC2138ARM7片上微控制器系统设计了一款蓄电池组在线监测装置,实现了对96只2V/200Ah蓄电池组的在线检测,也可以满足32只12V/300Ah蓄电池组的检测要求.现场运行结果表明,装置抗共模电压能力、采样精度、稳定可靠性符合相关标准的要求.     

基于P-Q分解法的电力系统潮流计算仿真研究

以常规的电力系统为研究对象,建立了潮流计算的基本模型,分析了P-Q分解法潮流计算的基本原理,在此基础上,通过MATALB编程,运行了P-Q分解法的潮流计算过程,仿真结果证明了文本提出的方法的有效性.     

低层建筑抗风设计方法比较与研究

土木工程设计中,最有影响和最易引起工程结构失败甚至破坏的首推风荷载.最近几年风灾严重,尤其是风灾导致的低层建筑损失更是惨重.而国际上发达国家的风荷载规范则在不断变化之中,尤其是对轻型钢结构的抗风设计.因此本文有必要对各国低层轻型钢结构抗风设计方法进行研究.本文分别对中国、日本、美国等国家关于抗风设计方法进行比较,并针对风压系数计算一个实例,最后与风洞试验结果进行对照,对中国抗风设计方法进行研究与探讨.     

尾矿和Na_2O对包钢稀选尾矿微晶玻璃的影响

利用熔融浇注法对包钢稀选尾矿微晶玻璃在生产过程中的流动性进行了研究,利用DSC,XRD,SEM等手段研究了尾矿和Na2O含量对微晶玻璃的析晶特性及其他物理性能的影响.结果表明,当其它成分不变时,随着尾矿含量的增加,流动性增强;当其它成分不变时,随着Na2O含量的增加,流动性增强;在本实验条件下,尾矿加入量较佳范围为40%~50%;Na2O较佳范围为3%~6%.     

介孔TiO2的水热法合成及其光催化性能研究

用阳离子型表面活性剂十六烷基三甲基溴化铵(CRAB)为模板剂,采用水热法制备了介孔TiO2,探究了不同反应条件对样品光催化活性的影响,并对制得的样品进行了XRD,SEM,TEM,N:吸附-解吸及差热-热重等表征.结果表明,所得样品为窄孔道分布,最可几孔径为4.5 nm,其比表面积为134.4 m2/g.当水热温度为110℃,Ti(SO4):与CTAB的摩尔比为12:1,焙烧温度为400℃时,所制得样品的光催化活性最好.     

Surface characteristics and wetting mechanism of respirable coal dust

In this study,FTIR and XPS spectroscopy,specific surface area and pore size analyses,wetting and other experimental means have been applied to investigate respirable coal dust surface properties and wetting mechanism.The research shows that coal dust surface structures,chemical and element compositions are changed in the refining process of coal dust.Compared with large particle coal dust,respirable coal dust is a weak hydrophilic and strong hydrophobic substance.The reason:the smaller the particle size of coal dust,the more unsaturated its surface.The absorption of air is strong and it is easy to form an air film on coal dust surfaces.Coal dust contact with water is actually a compound contact of liquid in contact with a solid and gas in contact with a solid.The smaller the particle size,the larger the pore volume and the higher the degree of surface roughness,the larger the area of gas in contact with a solid and the worse the coal dust wettability.Another reason is that the changes in the composition of atoms on the dust surface and structures affect coal dust wettability.The results of this study establish a theoretical basis for the invention of effective reduced-dust technology.     

Deformation and failure study of surrounding rocks of dynamic pressure roadways in deep mines

In order to understand the change rules of stress-displacement in surrounding rocks of dynamic pressure roadways in deep mines and to obtain a theoretical basis for analyses of roadway stability and designs of support,we established a coupling equation of adjacent rock strength,mining stress and supporting resistance on the basis of an elastic-plastic theory of mechanics.We obtained an analytical solution for stress and displacement distribution of elastic and plastic regions in surrounding rock of dynamic pressure roadway..Based on this theory,we have analyzed the changes in stress-displacement in elastic and plastic regions of surrounding rocks of dynamic pressure roadways in the Haizi Coal Mine.The results show that:1) radial and tangential stress change violently within the first 4 m from the inner surface of a roadway after excavation;radial stress increases while tangential stress decreases within a range of about 6 m from the inner surface of the roadway as a function of q3;2) radial and tangential stress increase with an increase in the mining pressure coefficient k;the increase in the rate of tangential stress is greater than that of radial stress;3) the radial displacement of the inner surface of roadways decreases with an increase in q3,provided that k remains unchanged.     

WFBZ-01型微机发电机变压器组保护装置的运行情况分析

本文根据WFBZ-01型微机发电机变压器组保护装置在河北兴泰发电有限责任公司中的运行情况,对该装置的保护功能、设计原理与传统保护在实际运行中的优点及存在的问题进行对比分析。分析结果表明:其保护配置灵活,设计合理,满足电力系统事故措施要求和保护装置的使用安全性。     

二氨丙基苯固化剂的合成及应用

以无水三氯化铝为催化剂,用苯和1,3-口恶嗪-2-酮进行氨丙基化反应合成了二氨丙基苯。研究了物料物质的量比、反应时间、温度对反应的影响,确定了合成二氨丙基苯的较佳反应条件。通过DSC对环氧树脂中该固化剂的加入量和固化工艺条件进行了研究,对环氧树脂固化物的力学性能等指标进行了考察。