A Two‐Stage Annealing Strategy for Crystallization Control of CH3NH3PbI3 Films toward Highly Reproducible Perovskite Solar Cells

The solvent‐engineering method is widely used to fabricate top‐performing perovskite solar cells, which, however, usually exhibit inferior reproducibility. Herein, a two‐stage annealing (TSA) strategy is demonstrated for processing of perovskite films, namely, annealing the intermediate phase at 60 °C for the first stage then at 100 °C for the second stage. Compared to conventional direct annealing temperature (DHA) at 100 °C, using this strategy, MAPbI₃ films become more controllable, leading to superior film uniformity and device reproducibility with the champion device efficiency reaching 19.8%. More specifically, the coefficient of variation of efficiency for 49 cells is reduced to 5.9%, compared to 9.8% for that using DHA. The TSA process is carefully studied using Fourier transform infrared spectroscopy, X‐ray diffraction, and UV–vis absorption spectroscopy. It is found that in comparison with DHA the formation of hydrogen bonding and crystallization of perovskite are much slower and can be better controlled when using TSA. The improvements in film uniformity and device reproducibility are attributed to: 1) controllable MAPbI₃ crystal growth stemming from the progressive formation of hydrogen bonding between methylammonium and halide; 2) suppression of intermediate phase film dewetting, which is believed to be due to its decreased mobility at the initial low‐temperature annealing stage.     

In-situ synthesis of TiO2 nanostructures on Ti foil for enhanced and stable photocatalytic performance

TiO_2 nanostructures with strong interfacial adhesion and diverse morphologies have been in-situ grown on Ti foil substrate through a multiple-step method based on conventional plasma electrolytic oxidation(PEO) technology, hydrothermal reaction and ion exchange process. The PEO process is critical to the formation of TiO_2 seeding layer for the nucleation of Na_2Ti_3O_7 and H_2Ti_3O_7 mediates that are strongly attached to the Ti foil. An ion exchange reaction can finally lead to the formation of H_2Ti_3O_7 nanostructures with diverse morphologies and the calcination process can turn the H_2Ti_3O_7 nanostructures into TiO_2 nanostructures with enhanced crystallinity. The morphology of the TiO_2 nanostructures including nanoparticles(NP), nanowhiskers(NWK), nanowires(NW) and nanosheets(NS) can be easily tailored by controlling the NaOH concentration and reaction time during hydrothermal process. The morphology, composition and optical properties of TiO_2 photocatalysts were analyzed using scanning electron microscope(SEM), X-ray diffraction(XRD), photoluminescence(PL) spectroscopy and UV–vis absorption spectrum. Photocatalytic tests indicate that the TiO_2 nanosheets calcined at 500?C show good crystallization and the best capability of decomposing organic pollutants. The decoration of Ag cocatalyst can further improve the photocatalytic performance of the TiO_2 nanosheets as a result of the enhanced charger separation efficiency. Cyclic photocatalytic test using TiO_2 nanostructures grown on Ti foil substrate demonstrates the superior stability in the photodegradation of organic pollutant, suggesting the promising potential of in-situ growth technology for industrial application.     

从“7.18“网络攻击案分析网络黑客犯罪

近年来,互联网应用飞速发展,国内网民规模日益扩大。与此同时,网络黑客的攻击破坏活动已成为影响互联网安全的主要问题之一。本文结合上海警方侦破“7·18”私车额度拍卖系统网络攻击案的现实案例,分析了当前网络黑客案件平民化、趋利化、组织化的规律特点,以及公安机关在案件侦办过程中常见的一些难点问题,并从加强日常管理和完善刑事立法两个层面提出了针对性的对策和建议。     

取代酚对日本长腿蛙蝌蚪急性毒性的QSAR研究

用Hartree-Fock(HF)和DFT-B3LYP方法,分别在较高基组6-31G**和6.311G**水平下,全优化计算了21种取代酚化合物.从中获得分予最高占用和最低空轨道能(EHOMO和ELUMO)、前线轨道能级差(△E＝EHOMO-ELUMO)、分子总能量(ET)、氧原了所带的最高正电荷(QH+)、最负原子的静电荷(Q-)、分子偶极矩(μ)和分子体积(V)等描述符.结合文献中标题化合物对日本长腿蛙蝌蚪的毒性值(-logLC50)和辛醇/水分配系数(logKow),由线性同归方法成功建立包含10gKow、ELUMO和Q-的三参数QSAR模型.其中,模型(5)的复相关系数R2=0.944 8,交叉验证系数Q2=0.920 5,标准偏差SE=0.187,Fisher检验值F=98.390,故其预测能力较好.由此推断,标题物对日本长腿蛙蝌蚪的毒性作用分为2步,首先穿过细胞壁在细胞内富集,以logKow和Q-描述;其次与亲核试剂发生亲电反应,以风ELUMO表示.     

Real-time foveation filtering using nonlinear Mipmap interpolation

In recent years, several techniques have been proposed to simulate the gaze effect of the Human Visual System (HVS). It is believed that this effect is due to the foveation filtering. Current techniques to simulate the foveation filtering in computer graphics are either slow or suffer from artifacts and limitations. In this paper, we present a new approach of foveation filtering based on the Mipmap Pyramid of the current view by considering the relationship between the Gaussian kernel and Mipmap level. Due to the nonlinear Mipmap interpolation under the Bilateral Filtering scheme, we are able to simulate the foveation filtering more naturally and efficiently than in previous work. Moreover, a detail enhancement method based on the Cornsweet illusion is proposed to augment the gazing effect. We demonstrate our new approach with a variety of examples and provide comparisons with recent approaches.     

Dynamically modulated intensity interrogation scheme using waveguide coupled surface plasmon resonance sensors

An electro-optically modulated intensity interrogation method based on tunable waveguide coupled surface plasmon resonance sensors has been proposed. It has been theoretically and experimentally demonstrated that the proposed scheme can enable sensitive measurement of measurand variations. By modulating the refractive index in the waveguide layer, this interrogation method yields modulated signal whose amplitude is related to measurand's refractive index. This amplitude modulated signal offers a higher signal to noise ratio and eliminates additive noise in the sensor system. A preliminary investigation using saline buffers with different NaCl concentrations shows a resolution of 2.3 × 10^?6 refractive index unit by our approach. Resolution can be controlled by the amplitude of the applied modulation voltage and can be further enhanced by optimizing the device structure or improving the electro-optical (E-O) coefficient of the E-O material. This approach is simple, stable, and promising for low-cost or multi-channel SPR biosensor applications.     

基于网络环境下的WEB开发基础课程的多媒体教学设计

随着Internet技术的高速发展,多媒体技术的应用已成为大部分教师的首选,网络教育、网络学习、基于网络的多媒体教学设计也成为授业者和学习者追求的目标。该文将以WEB开发基础科目为例,具体讲述现代多媒体教学模式的设计和网络资源的整合设计。     

双边开关磁阻直线电动机的设计

介绍了双边开关磁阻直线电动机(LSRM)的组成、工作原理及其尺寸设计方法,给出了LSRM样机的尺寸设计结果,并采用有限元法分析LSRM磁场分布规律,进行磁场分段计算,从而得到了最大电感、最小电感和相绕组匝数。测试结果表明,该LSRM样机启动力较大且出力不受电流方向影响,但也存在出力有脉动和噪声较大等问题,该问题可通过优化结构设计和控制算法解决。     

基于感应无线的高分辨率位置检测系统研究

为了提高移动机车位置检测精度,提出了一种感应无线位置的检测方法.该方法采用一条独特的编码电缆,利用电磁感应原理,建立了发送线圈与编码电缆之间的信息传输系统,并通过检测感应电动势的相位和幅度,得到移动机车的位置.分析了感应无线检测的原理和方法,推导出了位置检测公式,并进行相关试验.试验结果表明,感应无线位置检测分辨率为2mm,检测精度达到了国际先进水平,可广泛应用于移动机车自动定位中.     

Fault containment in weakly stabilizing systems

Research on fine tuning stabilization properties has received attention for more than a decade. This paper presents probabilistic algorithms for fault containment. We demonstrate two exercises in fault containment in a weakly stabilizing system, which expedite recovery from single failures, and confine the effect of any single fault to the constant-distance neighborhood of the faulty process. The most significant aspect of the algorithms is that the fault gap, defined as the smallest interval after which the system is ready to handle the next single fault with the same efficiency, is independent of the network size. We argue that a small fault gap increases the availability of the fault-free system.