Microwave hybrid fast sintering of red clay ceramics

This work aimed to examine the performance of the hybrid sintering of clay ceramic in a microwave furnace, compared to the sintering process in a conventional furnace. The raw materials were subjected to X-ray fluorescence, loss on ignition (LOI), X-ray diffraction, particle size distribution, real specific mass, and thermogravimetric analyses. The red clay ceramic mass was prepared, extruded, pre-sintered in a conventional furnace at 600°C/60 min, and sintered at temperatures between 700 °C and 1100 °C. The sintering conventional (resistive oven) was carried out for 60 min with a heating rate of 10°C/min. In the microwave furnace, the sintering times were 5, 10, and 15 min, with a heating rate of 50°C/min, with a sintering chamber coated with silicon carbide (susceptor). The sintered specimens were characterized according to linear shrinkage, water absorption, apparent porosity, apparent specific mass, X-ray diffraction, Raman spectroscopy analysis, spectroscopy analysis in the ultraviolet and visible regions, microhardness, and scanning electron microscopy. The results showed that microwave sintering promoted an increase in the microhardness and apparent specific mass, and reduction in water absorption and apparent porosity values, due to greater densification in the microstructure. The best results occurred for specimens sintered at 1100°C.     

The effect of blanching on the quality of dehydrated broccoli florets

Different blanching treatments were applied to broccoli florets prior to dehydration in order to improve product quality. The pretreatments used were a conventional blanching in water at 99ǃ °C, and a stepwise blanching (a blanching at low temperature followed by a short blanching at high temperature after a holding time) using different temperatures for the first step (50, 55, 60, 65 and 70 °C). Five rehydration temperatures were used (25, 40, 55, 65 and 80 °C). Rehydration rate (D_eff and W_e), chlorophyll content and texture of the rehydrated product were evaluated. Rehydration was modelled according to Fick's diffusion equation. A good agreement between the model and the experimental data was obtained when D_eff and W_e values were identified for each temperature (average explained variance 96.9%). Samples stepwise blanched at 60 °C showed, on the average, the lowest W_e values. Stepwise blanching at 60-65 °C and rehydration at 25-55 °C were the combinations that gave the firmest product. Stepwise blanching at 50 °C together with the conventional blanching (99ǃ °C) and rehydration between 25 and 65 °C were the combinations that allowed preservation of the highest chlorophyll content. From these results, it seems difficult to obtain firm samples with a high chlorophyll content without additives.     

Heat transfer characteristics in double tube helical heat exchangers using nanofluids

In the present work a three-dimensional analysis is used to study the heat transfer characteristics of a double-tube helical heat exchangers using nanofluids under laminar flow conditions. CuO and TiO₂ nanoparticles with diameters of 24 nm dispersed in water with volume concentrations of 0.5–3 vol.% are used as the working fluid. The mass flow rate of the nanofluid from the inner tube was kept and the mass flow rate of the water from the annulus was set at either half, full, or double the value. The variations of the nanofluids and water temperatures, heat transfer rates and heat transfer coefficients along inner and outer tubes are shown in the paper. Effects of nanoparticles concentration level and of the Dean number on the heat transfer rates and heat transfer coefficients are presented. The results show that for 2% CuO nanoparticles in water and same mass flow rate in inner tube and annulus, the heat transfer rate of the nanofluid was approximately 14% greater than of pure water and the heat transfer rate of water from annulus than through the inner tube flowing nanofluids was approximately 19% greater than for the case which through the inner and outer tubes flow water. The results also show that the convective heat transfer coefficients of the nanofluids and water increased with increasing of the mass flow rate and with the Dean number. The results have been validated by comparison of simulations with the data computed by empirical equations.     

Variation in fatty acid composition of ewes' colostrum and mature milk fat

Temporal content variations of approximately 70 C4–C24 fatty acids (FA) in colostrum and milk of ewes consuming winter diet were determined by gas chromatography. The content of monounsaturated, polyunsaturated and straight-chain saturated FA 14:0–16:0 in colostrum was higher whereas the content of 4:0–12:0, 18:0 and branched-chain saturated FA 15:0–17:0 was lower than that in mature milk. The effect of ewe breed on the FA profiles was not significant. The composition of FA changed most significantly 1–2 days after lambing in agreement with the time schedule of colostrum formation. Nevertheless, the content of FA further successively changed up to approximately the 6th day of lactation, whereas further changes up to the 60th day of lactation were smaller. This is consistent with the recommendation that ewes' milk is suitable for human consumption after six-to-eight days of lactation. The higher contents of palmitic and myristic acids in colostrum compared with mature milk suggest that FA composition in colostrum matches the changing needs of the growing lambs.     

Cold rolling of MgH2 powders containing different additives

In this study we have used cold rolling (CR) as a successful method to incorporate additives into MgH₂. The mixtures of MgH₂ + 2 Mol% X, with X = Fe, Nb, Fe₂O₃, Nb₂O₅, FeF₃, were processed by CR using a horizontal rolling mill and then followed by a detailed microstructural characterization which includes X-ray diffraction (XRD) with Rietveld refinement, Differential Scanning Calorimetry (DSC) and kinetic measurements. The CR processing resulted in a drastic crystallite size reduction, ∼8–17 nm, strong texture and partial conversion from the β to the γ-MgH₂ phase. The orthorhombic metastable NbH_x phase was detected in the XRD pattern of the mixture MgH₂ + Nb after CR, indicating the high energy involved in the CR processing. The samples containing Fe and FeF₃ as additives presented the lowest desorption temperature ranges. All additives presented beneficial effect on the dehydrogenation kinetic measurements (measured at 623 K and 598 K) compared to pure MgH₂, in especial for the samples containing Nb₂O₅ and FeF₃.     

Probiotics: An alternative strategy for combating salmonellosis: Immune mechanisms involved

Salmonella produces infections of different nature and severity depending of many factors including the Salmonella serovar involved, strain virulence, infective dose, host animal species, age and immune status of the host. The treatments against Salmonella infections rely on supportive and antibiotic therapy to eliminate the pathogen, but the development of resistance by Salmonella to the antimicrobials most commonly used limits its efficacy. Other disadvantages of antibiotic treatments are that they can lead to acute diarrhea (antimicrobials normally induce an imbalance of intestinal bacterial flora) and may produce chronic toxicity. Considering this undesired consequences of antibiotics and because at the present there are no effective oral vaccines which protect against salmonellosis, scientists have been searching for alternative methods to control enteric infections. In the present review, probiotics are proposed as an attractive possibility to attend this concern. Probiotic are live microorganisms, which when administered in adequate amounts confer a health benefit on the host. In vitro and in vivo studies showed the effectiveness of probiotic administration in the prevention or in the treatment against Salmonella infection. There are several mechanisms by which probiotic strains might exert their effects. They include non immune mechanisms (stabilization of the gut mucosal barrier, competition for adhesion, secretion of antimicrobial substances, etc.) and the modulation of the mucosal and systemic immune responses. These mechanisms are species and/or strain specific. There are also evidences that in some cases, a mix of probiotic strains can be more useful than each strain alone against this infection. In addition, the presence of one or more probiotic strains in a fermented product can improve the beneficial properties of the probiotic strains involved. It was also reviewed the security of probiotics administration after Salmonella infection in healthy host and in immunosuppressed or babies hosts. Although, the major part of the researches were performed in animal models through in vivo assays or by in vitro studies using human cell lines, some studies carried out in humans to verify the probiotic effects were also addressed in the present review. Nevertheless, is of critical importance to perform more clinical trials in humans to validate the results obtained with each specific probiotic strain or probiotic product.     

Effect of damaged starch levels on flour-thermal behaviour and bread staling

The effect of the amount of damaged starch in two different flours (wheat and triticale) on the bread quality and its behaviour during storage has been analysed. Two wheat and one triticale flour cultivars were milled in a disc mill to obtain different levels of damaged starch. Differential Scanning Calorimetry (DSC) and Rapid Visco Analyser (RVA) were used to characterize the flour properties and TA-XT2 textural analyses were made on breadcrumb. The effect of the damaged starch content on the bread firming, the amylopectin retrogradation and starch-pasting properties were studied in order to establish any relationship between damaged starch and bread staling. DSC analysis showed that the damaged starch content changed the thermal behaviour of flour–water mixtures: the higher the levels of damaged starch the lower the starch-gelatinization enthalpy and the higher the melting enthalpy of amylose–lipid complexes. The amount of amylopectin retrogradation and breadcrumb firming increased with the damaged starch content at the beginning of storage time; however, differences were decreasing at final storage time. The flour viscosity during pasting decreased as their damaged starch content increased.     

Biochemical characterization and process stability of polyphenoloxidase extracted from Victoria grape (Vitis vinifera ssp. Sativa)

Polyphenol oxidase (PPO) was isolated from Victoria grapes (Vitis vinifera ssp. Sativa) grown in South Africa and its biochemical characteristics were studied. Optimum pH and temperature for grape PPO activity were pH 5.0 and T = 25 °C with 10 mM catechol in McIlvaine buffer as substrate. PPO showed activity using the following substances: catechol, 4 methyl catechol, d, l-DOPA, (+) catechin and chlorogenic acid. K_m and V_max values were 52.6 ± 0.00436 mM and 653 ± 24.0 OD_400 nm/min in the case of 10 mM catechol as a substrate. Eight inhibitors were tested in this study and the most effective inhibitors were found to be ascorbic acid, l-cysteine and sodium metabisulfite. Kinetic studies showed that the thermal inactivation of Victoria grape PPO followed first-order kinetics, with an activation energy, E_a = 225 ± 13.5 of kJ/mol. Both in semipurified extract and in grape juice, PPO showed a pronounced high pressure stability.