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111.
Ca2Gd8(SiO4)6O2 (CGS) nanophosphors with different concentrations of single-doped Dy3+ ions and co-doped Dy3+/Eu3+ ions were prepared by a solvothermal synthesis. Very fine particles in the nanometer range could be achieved by this method, as evidenced by transmission electron microscope measurements. The hexagonal phase of the oxyapatite structure was confirmed by X-ray diffraction patterns. The energy transfer between Eu3+ and Dy3+ ions was investigated by photoluminescence excitation and emission properties. These phosphors had absorption bands in the UV and NUV region, which are suitable for the emission wavelength of UV or NUV light-emitting diodes (LEDs). With increasing the Eu3+ ion concentration, the emission peak intensity corresponding to the 5D0→7F2 transition increased and the yellow (4F9/2→6H13/2) emission intensity also increased compared to the blue (4F9/2→6H15/2) emission intensity due to the increased energy transfer between Dy3+ to Eu3+ ions. Thus, the Eu3+ ions compensated the red emission component of the Dy3+ doped CGS nanophosphors. Such phosphors are expected to have potential applications for NUV based white LEDs. 相似文献
112.
Gabriela Huminic Alexandru Vrdaru Angel Huminic Claudiu Fleac Florian Dumitrache Ion Morjan 《International journal of molecular sciences》2022,23(6)
In the current paper, a new hybrid nanofluid based on graphene oxide sheets and silicon nanoparticles is proposed for thermal applications. GO sheets and Si nanoparticles with different mixture ratios are dispersed in distilled water. Dynamic viscosity is measured at temperatures within the range 20–50 °C and the values are compared to the results available in the literature. The results indicated that the viscosity increases with increasing the mixture ratio of graphene oxide. A new correlation for the dynamic viscosity based on the experimental findings is proposed. Finally, the criteria for the performance of new hybrid nanofluid for thermal applications are analyzed. 相似文献
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114.
Adrián E. Yuchechen S. Gabriela Lakkis Pablo O. Canziani 《International journal of remote sensing》2017,38(12):3483-3501
Annual anomalies of Lambertian equivalent reflectivity (LER) retrieved from the total ozone mapping spectrometer spanning the period November 1978–November 2005 were studied in the Southern Hemisphere, in a region bounded by 0° S and 60° S, and their trends were estimated. With the exception of few regions where the variable may represent the contribution of both cloudiness and snow, trends in LER anomalies provided an evolution of total cloudiness. On average, the study region experienced a net increase in LER values of 0.78 reflectivity units (RU) decade?1; if only significant trend values are considered this figure increased to 1.18 RU decade?1. The region that showed the largest upward trend, up to 4 RU decade?1, was located over the eastern Pacific, off the coasts of Chile and Peru, where the presence of marine stratocumulus is frequent. Despite the overall positive trend there were regions that yielded a negative one, most notably the tropical latitudes of South America and Africa. The yearly zonal means also showed a positive trend at all latitudes, but significance occurred beyond 20° S only. Correlation maps between LER anomalies and five different circulation indices were also introduced. The indices with the highest and lowest number of significant correlation values were the Madden–Julian oscillation at 70° E and the quasi-biennial Oscillation, respectively. 相似文献
115.
Raj Kumar Singh Sunil Kumar Sinha A. Rama Rao 《Nuclear Engineering and Design》2009,239(10):1760-1767
The primary function of the shut down system in a nuclear reactor is to terminate any reactivity transient occurring in the core during its entire design life. Normally there is more than one system, which are independent and diverse in its mode of operation. They consist of quick acting mechanisms like dropping of safety rods by gravity, poison injection, etc. Typically in liquid poison injection system wherein high flow velocities are involved, there is significant fluid structure interaction associated with cyclic shock transients in the system. One such phenomenon has been captured and analyzed to understand the dynamics involved in the loop. The trends of loop pressure and vibration indicated presence of more than two pressure transients after complete injection of poison. The first transient arrived after 1.44 s and the second after 0.75 s. The reverse pressure pulses that manifested in the loop as a result of fast injection of fluid has been mathematically characterized by solving basic fluid balance equations. Possibility of ball lifting due to momentum pulse is also discussed. 相似文献
116.
Mihaela Turturică Nicoleta Stănciuc Gabriela Bahrim Gabriela Râpeanu 《Food and Bioprocess Technology》2016,9(10):1706-1715
Five anthocyanins were detected in the sweet cherry extract as follows: cyanidin 3-rutinoside, cyanidin 3-glucoside, peonidin 3-rutinoside, peonidin 3-glucoside, and pelargonidin 3-rutinoside, whereas the cyanidin 3-rutinoside was found to be in the highest amount. The effect of thermal treatment on the degradation of the polyphenolic compounds in sweet cherry extract was investigated in the range of 70–120 °C by means of fluorescence spectroscopy and spectrophotometric techniques. The fluorescence spectra were dominated by emission bands with maximum ranging from 356 nm at 25 °C to 350 nm at 110 °C. The heating of sweet cherry extract resulted in structural changes that led to a significant decrease in fluorescence intensity when increasing temperature. Degradation rate constants were estimated using a fractional conversion kinetic model. The activation energy values revealed a higher-temperature dependence of antioxidant activity, followed by anthocyanins, total polyphenols, and total flavonoids. 相似文献
117.
Trauma survivors with posttraumatic stress disorder (PTSD) often experience or report social stigmatization and isolation. Williams (2001) provided an experimental paradigm to assess behavioral effects of social exclusion. This paradigm (face-to-face version) has been applied in a 2 × 2 group × experimental condition design. Participants in the PTSD group (N = 16) and the nontraumatized control group (N = 25) were randomly assigned to an exclusion or inclusion condition. The results showed interaction effects for main psychopathological assessments (depression, anxiety, psychoticism) and expected main effects for the majority of outcome measures (psychopathology, well-being, belonging, and meaningful existence). The research concludes that a general assumption of elevated levels of self-perceived social exclusion in PTSD patients has to be considered in terms of differentiated psychopathological effects of exclusion. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献
118.
119.
Odilia I Bermudez Claire Toher Gabriela Montenegro-Bethancourt Marieke Vossenaar Paul Mathias Colleen Doak Noel W Solomons 《Nutrition journal》2010,9(1):20
Background
Consumption of healthy diets that contribute with adequate amounts of fat and fatty acids is needed for children. Among Guatemalan children, there is little information about fat intakes. Therefore, the present study sought to assess intakes of dietary fats and examine food sources of those fats in Guatemalan children. 相似文献120.
A. Mohan BabuB.C. Jamalaiah J. Suresh KumarT. Sasikala L. Rama Moorthy 《Journal of Alloys and Compounds》2011,509(2):457-462
Lead tungsten tellurite (LTT) glasses doped with different Dy3+ ion concentrations have been prepared and characterized through optical absorption, photoluminescence and decay measurements. The glassy nature of the LTT host has been confirmed through the XRD measurements. The three phenomelogical intensity parameters Ωλ (λ = 2, 4, 6) have been determined from the absorption spectral intensities using the Judd-Ofelt (J-O) theory. The hypersensitivity of 6H15/2 → 6F11/2 transition based on the magnitude of Ω2 parameter has also been discussed. By using the J-O intensity parameters several radiative properties such as spontaneous transition probabilities (AR), fluorescence branching ratios (βR) and radiative lifetimes (τR) have been determined. The effect of Dy3+ ion concentration on the emission intensities of 4F9/2 → 6HJ′ (J′ = 15/2, 13/2, 11/2 and 9/2) transitions has also been reported. 相似文献