The effect of reduced tillage agriculture on carbon dynamics in silt loam soils

Reduced tillage (RT) agriculture is an effective measure to reduce soil loss from soils susceptible to erosion in the short-term and is claimed to increase the soil organic carbon (SOC) stock. The change in distribution and total SOC stock in the 0–60 cm layer, the stratification of microbial biomass carbon (MB-C) content in the 0–40 cm layer and the carbon (C) mineralization in the upper 0–5 cm layer in silt loam soils in Western Europe with different periods of RT agriculture were evaluated. Ten fields at seven locations, representing the important RT types and maintained for a different number of years, and eight fields under conventional tillage (CT) agriculture with similar soil type and crop rotation were selected. RT agriculture resulted in a higher stratification of SOC in the soil profile than CT agriculture. However, the total SOC stock in the 0–60 cm layer was not changed, even after 20 of years RT agriculture. The MB-C was significantly higher in the 0–10 cm layer under RT agriculture, even after only 5 years, compared to CT agriculture. The higher SOC and MB-C content in the upper 0–5 cm layer of RT fields resulted in a higher C mineralization rate in undisturbed soil in the laboratory. Simulating ploughing by disturbing the soil resulted in inconsistent changes (both lower and higher) of C mineralization rates. A crop rotation with root crops, with heavy soil disturbance every 2 or 3 years at harvest, possibly limited the anticipated positive effect of RT agriculture in our research.     

Beef sausage structure affected by sodium chloride and potassium lactate

A histological and ultrastructural study was conducted to characterize changes in the muscle fibre structure of three fresh sausage preparations, depending on meat composition, sodium chloride (NaCl) and potassium lactate (K-lactate) contents. After addition of 0.8% and 1.6% NaCl, 65% and 51%, respectively, of the area observed showed well preserved fibres (histological data). The altered regions presented a large disorganization of the myofilaments and a solubilization of the sarcolemma and of the Z lines. K-lactate addition had no marked effects on meat structure. The preparation containing some sheep meat was more sensitive to salt than the others containing only bovine meat. The level of alteration was much lower than those obtained in pork meat in another study. Technological conditions used to modify the internal muscle fibre structure during sausage processing depend on the species used. Therefore, the classification of the sausage preparation to “meat preparation” or “meat product” under the EU regulation (EC) No. 853/2004 (which assign meat preparations to meat if the product has undergone a process insufficient to modify the internal muscle fibre structure of the meat) must be systematically controlled when changing the meat sausage composition.     

Effect of Wood Welding Process on Chemical Constituents of Australian Eucalyptus

Thermochemical changes occurring during wood welding were investigated in Eucalyptus saligna and Eucalyptus pilularis. Unwelded reference wood and material from welded interface were compared via Py-GC/MS, thermogravimetric analyses, X-ray photoelectron spectroscopy, and attenuated total reflection Fourier transform infrared spectroscopy to explain differences in mechanical properties of welded wood between species. It appeared that the species originally containing more condensed substructures also provided stronger joints. The condensation index after welding allowed validating that the adhesive properties of lignin are more accessible in such species. The presence of more carbonyl functions, attributed to carbohydrate solicitation during welding process, potentially made lignin less accessible. Changes following welding were evidenced by the contribution of extractive compounds, fatty acid chains, and terpenoids, possibly reacting with hydroxyl groups and leading to adhesive properties by chemical linkage through new covalent bonds formation. Results corroborate the better mechanical properties of E. saligna, providing stronger joints possibly due to more accessible adhesive properties by esterification between lignin and fatty acid.     

XAS study of arsenic coordination in Euglena gracilis exposed to arsenite

Among the few eukaryotes adapted to the extreme conditions prevailing in acid mine drainage, Euglenae are ubiquitous in these metal(loid)-impacted environments, where they can be exposed to As(III) concentrations up to a few hundreds of mg x L(-1). In order to evaluate their resistance to this toxic metalloid and to identify associated detoxification mechanisms, we investigated arsenic coordination in the model photosynthetic protozoan, Euglena gracilis, cultured at pH 3.2 and exposed to As(III) at concentrations ranging from 10 to 500 mg x L(-1). E. gracilis is shown to tolerate As(III) concentrations up to 200 mg * L(-1), without accumulating this metalloid. X-ray absorption spectroscopy at the As K-edge shows that, in the cells, arsenic mainly binds to sulfur ligands, likely in the form of arsenic-trisglutathione (As-(GS)3) or arsenic-phytochelatin (As-PC) complexes, and to a much lesser extent to carbon ligands, presumably in the form of methylated As(III)-compounds. The key role of the glutathione pathway in As(III) detoxification is confirmed by the lower growth rate of E. gracilis cultures exposed to arsenic, in the presence of buthionine sulfoximine, an inhibitor of glutathione synthesis. This study provides the first investigation at the molecular scale of intracellular arsenic speciation in E. gracilis and thus contributes to the understanding of arsenic detoxification mechanisms in a eukaryotic microorganism under extreme acid mine drainage conditions.     

Thermal properties of new varieties of yam starches

Starches isolated from yam varieties of Dioscorea alata and Dioscorea cayenensis‐rotundata species were prepared at different time–temperature conditions and characterised by DSC, amperometric iodine titration, light microscopy and rheology and compared to native and chemical modified tapioca starches. The observation by light microscopy showed different morphologies of the granules when heated above 100°C and the tendency for disintegration decreased in the order native tapioca starch > yam starch > modified tapioca starch. Differences between yam and tapioca starches were also revealed by DSC. Yam starch enthalpy is higher than tapioca starch, but the peak temperature is low. However, the significant differences between yam and the other tested starches were found in terms of their rheological behaviour. The viscosity of yam starch was very stable at high temperatures on the viscograph. With this property, yam starch can be used as thickening and gelling agent in food.     

Impact of social externalities on the formation of an international environmental agreement: an exploratory analysis

We analyze the impact of social externalities (SEs) on the stability of an international environmental agreement (IEA). We consider a framework in which players are divided into two homogeneous groups, namely, developed and developing countries. We assume that members of an IEA get some additional benefits, to which we refer as SEs. One main result is that any coalition that is internally stable will expand to include all countries, which is related to the minimum participation clause considered in some papers. However, our minimum, which is endogenously defined, is not the largest stable coalition size, but the grand coalition.     

A parametric investigation on seat/occupant contact forces and their relationship with initially perceived discomfort using a configurable seat

The present work investigates the contact forces between sitters and seat as well as their correlations with perceived discomfort. Twelve different economy class aeroplane seat configurations were simulated using a multi-adjustable experimental seat by varying seat pan and backrest angles, as well as seat pan compressed surface. Eighteen males and 18 females, selected by their body mass index and stature, tested these configurations for two sitting postures. Perceived discomfort was significantly affected by seat parameters and posture and correlated both with normal force distribution on the seat-pan surface and with normal forces at the lumbar and head supports. Lower discomfort ratings were obtained for more evenly distributed normal forces on the seat pan. Shear force at the seat pan surface was at its lowest when sitters were allowed to self-select their seat-pan angle, supporting that a shear force should be reduced but not zeroed to improve seating comfort.

Practitioner Summary: The effects of seat-pan and backrest angle, anthropometric dimensions and sitting posture on contact forces and perceived discomfort were investigated using a multi-adjustable experimental seat. In addition to preferred seat profile parameters, the present work provides quantitative guidelines on contact force requirement for improving seating comfort.