Synthesis and characterization of poly(ester‐ether‐imide)s derived from 5‐(4‐trimellitimidophenoxy)‐1‐trimellitimido naphthalene

A series of novel aromatic poly(ester‐ether‐imide)s with inherent viscosity values of 0.44–0.74 dL g^?1 were prepared by the diphenylchlorophosphate‐activated direct polycondensation of an imide ring‐containing diacid namely 5‐(4‐trimellitimidophenoxy)‐1‐trimellitimido naphthalene ( 1 ) with various aromatic dihydroxy compounds in the presence of pyridine and lithium chloride. Owing to comparison of the characterization data, an ester‐containing model compound ( 2 ) was also synthesized by the reaction of 1 with phenol. The model compound 2 and the resulted polymers were fully characterized by FT‐IR and NMR spectroscopy. The ultraviolet λ_max values of the poly(ester‐ether‐imide)s were also determined. The resulting polymers exhibited an excellent organosolubility in a variety of high polar solvents such as N,N‐dimethylacetamide, N,N‐dimethylformamide, dimethyl sulfoxide, and N‐methyl‐2‐pyrrolidone. They were soluble even in common less polar organic solvents such as pyridine, m‐cresol, and tetrahydrofuran on heating. Crystallinity of the polymers was estimated by means of wide‐angle X‐ray diffraction. The resulted polymers exhibited nearly an amorphous nature. From differential scanning calorimetry thermograms, the polymers showed glass‐transition temperatures between 221 and 245°C. Thermal behaviors of the obtained polymers were characterized by thermogravimetric analysis, and the 10% weight loss temperatures of the poly(ester‐ether‐imide)s were found to be over 410°C in nitrogen. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Effect of specimen orientation and heat treatment on electroless Ni-PTFE-MoS<Subscript>2</Subscript> composite coatings

In this study, the effects of simultaneous co-deposition of polytetrafluoroethylene (PTFE) and MoS₂ particles on tribological properties of electroless nickel (EN) coating were studied. The influences of specimen orientation and heat treatment on EN-PTFE-MoS₂ composite coatings were also investigated. Scanning electron microscopy was used to study the morphology of coatings and the distributions of the lubricant particles in the deposits. Chemical analyses of coatings were done by electron dispersive spectrometry. The phases of the coatings were identified by X-ray diffraction utilizing CuKα radiation. Wear and friction properties of the coatings were also determined by pin-on-disk wear tester. The wear investigations showed that the EN-PTFE-MoS₂ composite coating performs better than EN-PTFE and EN-MoS₂ coatings in terms of friction coefficient and wear resistance. PTFE and MoS₂ contents of the EN-PTFE-MoS₂ coating were increased by changing the specimen orientation from vertical to horizontal configuration, which leads to enhancement in tribological properties of the coating. After heat treatment, the wear rate of EN matrix composite coating decreased with corresponding change in phase structure.     

Influence of fusion zone size and failure mode on mechanical performance of dissimilar resistance spot welds of AISI 1008 low carbon steel and DP600 advanced high strength steel

The work here addresses the investigation of the effect of the welding parameters (welding time, welding current and electrode force) on the overload failure mode and mechanical performance of dissimilar resistance spot welds between drawing quality special killed AISI 1008 low carbon steel and DP600 dual phase steel. Mechanical properties of spot welds are described in terms of failure mode, peak load and energy absorption during the quasi-static tensile-shear test. Three distinct failure modes were observed during the tensile-shear test: interfacial, pullout and partial thickness–partial pullout failure modes. Correlations among failure mode, welding parameters, weld physical attributes and weld mechanical performance are analyzed. Effect of expulsion on mechanical performance of welds is also investigated.     

Effects of protein-surface interactions on protein ion signals in MALDI mass spectrometry

The influence of polymer surface-protein binding affinity on protein ion signals in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry is examined. The surfaces of poly(vinylidene fluoride) and poly(ethylene terephthalate) polymer substrates are modified by pulsed rf plasma deposition of allylamine. By varying the on/off duty cycle of the pulsed rf plasma, the polymer substrate surfaces are coated with thin films having varying densities of surface amine groups. The varying surface amine density is shown to lead to systematic changes in the surface binding affinity for the 125I-radiolabeled peptides angiotensin I and porcine insulin. Unlabeled angiotensin I and porcine insulin are then deposited on the pulsed rf plasma-modified substrates and analyzed by MALDI mass spectrometry. The experimental approach involves applying the peptide to the modified polymer surface in an aqueous phosphate-buffered saline solution and allowing the peptide solution to dry completely under ambient conditions. Subsequently, the MALDI matrix alpha-cyano-4-hydroxycinnamic acid in methanol and 10% trifluoroacetic acid in water are added to the peptide-coated modified polymer surfaces. The results of these studies demonstrate that, for the sample preparation method employed, increases in the surface peptide binding affinity lead to decreases in the peptide MALDI ion signal.     

Fabrication of low friction bronze–graphite nano-composite coatings

This paper addresses the fabrication of bronze–nano-graphite coatings containing 30 nm sized graphite particles. Addition of Poly Vinyl Pyrrolidone (PVP) and dispersing the suspension by ultrasound was utilized to stabilize the electroplating solution. Pulsed current electrodeposition was used and the deposits were characterized in terms of graphite content, particle dispersion in coating and morphology. The wear behavior of the coating was compared to bronze–micro-graphite coatings prepared with the same experimental conditions. The present coating showed improved wear resistance in comparison to bronze–micro-graphite coatings at the same graphite content.     

Long term stability assessment of Siah Bisheh powerhouse cavern based on displacement back analysis method

Siah Bisheh pumped storage powerhouse cavern with complex geometry, changeable geological formations and diverse geotechnical properties of rocks, is under construction on the Chalus River at the north of Iran. Powerhouse cavern is located near the lower dam reservoir and its crown is more than 30 m down the lower dam maximum lake level. After impounding of lower dam, powerhouse region will be located under saturated condition. Therefore long term stability assessment of the powerhouse cavern under saturated condition is unavoidable. In this study, displacement based direct back analysis using univariate optimization algorithm were applied and geomechanical properties of rocks, stress ratio and joints parameters were identified. Numerical modeling results are in good agreement with measured displacements using extensometers which confirm the numerical modeling accuracy and back analysis results. Then ordinary analysis of powerhouse cavern under natural condition using back analysis results were carried out. Results of analysis shows that powerhouse cavern is stable under natural condition and existing support system has suitable efficiency and could effectively control displacements. Finally, powerhouse cavern long term stability under saturated condition was analyzed. Results of analysis shows that after lower dam impounding, pore water pressure and uplift pressure in discontinuities around powerhouse cavern will arose and tend to local failure of powerhouse cavern in region 2nd and 3rd instrumentation arrays. To obtain powerhouse long term stability, it is recommended to construct a cutoff curtain around powerhouse cavern.