Thermal stability and high-temperature wear of Ti–TiN and TiN–CrN nanomultilayer coatings under self-mated conditions

Ti–TiN and TiN–CrN nanomultilayers were thermally stable retaining uniform and sharp layer interfaces up to 24 h at 773 K, without any oxidation or phase transformation accompanying each individual layer. Decreasing the multilayer spacing resulted in an increase in the hardness in both cases. The coating hardness was found to be independent of the substrate type, when applied on HS718, Ti64 and HCHCr substrates. In scratch testing, the multilayers displayed a better resistance to the onset of failure, as compared to the monolayer TiN. The substrate plasticity played an important role in determining the coating failure mode. Self-mated wear tests revealed the CrN–TiN system to exhibit the best wear behaviour, both at room temperature and at 773 K. The Ti–TiN coatings are more accommodative with all three substrates, as compared to TiN–CrN and TiN.     

A packet delay analysis for cellular digital packet data

We formulate and analyze a model of voice and data burst traffic for cellular digital packet data (CDPD). To develop a tractible model, we make some reasonable simplifying assumptions to model the voice traffic and one of the logical CDPD channels as an M/M/1 queue in a random environment. Rather than explicitly solve the resulting matrix quadratic equation, we develop an asymptotic analysis that gives us simple approximate formulas (with error bounds) for many performance measures of interest. In particular, one metric that we highlight comes from using our approximate mean data burst delay formula to characterize the performance of a set of interacting logical CDPD channels. We do so by describing it in terms of an equivalent number of independent, dedicated CDPD channels, We can use this metric to suggest what the optimal number of logical CDPD channels for a given system should be     

Are Diamonds a MEMS' Best Friend?

Next-generation military and civilian communication systems will require technologies capable of handling data/ audio, and video simultaneously while supporting multiple RF systems operating in several different frequency bands from the MHz to the GHz range [1]. RF microelectromechani-cal/nanoelectromechanical (MEMS/NEMS) devices, such as resonators and switches, are attractive to industry as they offer a means by which performance can be greatly improved for wireless applications while at the same time potentially reducing overall size and weight as well as manufacturing costs.     

A survey of sensory data boundary estimation,covering and tracking techniques using collaborating sensors

Boundary estimation and tracking have important applications in the areas of environmental monitoring and disaster management. A boundary separates two regions of interest in a phenomenon. It can be visualized as an edge if there is a sharp change in the field value between the two regions or alternatively, as a contour with a field value $f=\tau$ separating two regions with field values $f>\tau$ and $f<\tau$. Examples include contours/boundaries of hazardous concentration in a pollutant spill, frontal boundary of a forest fire, isotherms, isohalines etc. Recent advances in the area of embedded sensor devices and robotics have led to deployments of networks of sensors capable of sensing, computing, communication and mobility. They are used to estimate the boundaries of interest in physical phenomena, monitor or track them over time and also in some cases, mitigate the spatial spread of the phenomena. Since these sensors work autonomously in the environment, minimizing the energy consumed while maximizing the accuracy of estimation or tracking is the main challenge for algorithms for boundary estimation and tracking. Several algorithms with these objectives have been proposed in the literature. In this work, we focus on the algorithms that estimate and cover boundaries found in the sensory data in a field and not the topological boundary of the sensor network per se, which is beyond the scope of this paper.Here, our objective is to provide a comprehensive survey of the algorithms for boundary estimation and tracking by providing a taxonomy based on two broad categories — (i) Boundary estimation and tracking, where the sensors estimate the boundary without physically covering the boundary and (ii) Boundary covering — where the sensors not only predict the location and estimate the entire boundary but also physically cover the boundary by surrounding and bounding it. We further classify the techniques based on (a) sensing capabilities —in situ, range or remote sensing (b) movement capabilities — static or mobile sensors and (c) boundary type — static or dynamic and (d) type of estimation — field estimation where the entire field is sampled to search for contours and localized estimation where sampling is done near the boundary and (e) different types of mobility models in the case of mobile sensors. We believe that such a survey has not been performed before. By capturing and classifying the current state-of-the-art and identifying open research problems, we hope to ignite interest and stimulate efforts towards promising solutions for real-world boundary estimation and tracking problems.     

Effect of interfacial impurities on intermixing of bilayers

Mixing experiments were performed on Ni/Pt and René N4/Pt systems to understand the effect of interfacial impurities on the ion-beam mixing process. A layer of platinum 15 or 50 nm thick was deposited on metallographically polished sputter-cleaned nickel and René N4 substrates as well as on metallographically polished uncleaned René N4 by electron-beam deposition techniques. These targets were exposed to the bombardment of a Pt⁺ 1 MeV beam. A range of fluences, 2×10¹⁵ to 2×10¹⁶ Pt⁺/cm²⁺ was used to cause intermixing. The amount of mixing was evaluated by Rutherford backscattering spectroscopy and Auger sputter depth profiling. The mixing rates were the same for Ni/Pt and René N4/Pt with the clean interface. However, it was significantly less in René N4/Pt with an interfacial native oxide/impurity layer. The initial high volume fraction of precipitates in René N4 along the ion path became disordered under bombardment, and the alloying elements present significantly in the resultant solid solution did not influence the mixing process. Mixing in Ni/Pt and René N4/Pt with the clean interface appears to be dominated by thermochemical influences.     

Ionic transport studies of the glassy silver vanadomolybdate system

Ionic conductivity of the Ag₂O-MoO₃-V₂0₅ system has been studied over a wide range of frequency, temperature and composition. A narrower glass forming region has been found in comparison to the corresponding Ag₂O-MoO₃-P₂O₅ and Ag₂O-B₂O₃-P₂O₅ systems. The highest conductivity at room temperature, _rt, = 3.21 × 10^–6–1 cm^–1 (d.c.) with an activation energy,E _act, of 0.466 eV, was observed for the glass former's ratio of unity. Further, it reached a maximum value of 2.2 × 10^–2¨-1 cm^–1 withE _act = 0.153 eV when the oxide-base glass was dissolved with Agl. D.c. conductivity, hopping rate and relaxation time in the present system have been found to be characterized by the same activation energy.     

An evaluation of the performance of an automated procedure for comparative modelling of protein tertiary structure

A 3-D model of a protein can be constructed from its amino acidsequence and the 3-D structures of one or more homologues byannealing three sets of fragments: the structurally conservedregions, structurally variable regions and the side chains.The method encoded in the computer program COMPOSER was assessedby generating 3-D models of eight proteins whose crystal structuresare already known and for which 3-D structures of homologuesare available. In the structurally conserved regions, differencesbetween modelled and X-ray structures are smaller than the differencesbetween the X-ray structures of the modelled protein and thehomologues used to build the model. When several homologuesare used, the contributions of the known structures are weighted,preferably by the square of sequence similarity; this is especiallyimportant when the similarities of the homologues to the modelledstructure differ greatly. The ‘collar’ extensionapproach, in which a similar region of different length in ahomologue is used to extend the framework, can result in a moreaccurate model. If known homologues comprise more than one relatedgroup of proteins and they are both distantly related to theunknown, then alignment of the sequence to be modelled witheach group of homologues facilitates identification of structurallyconserved regions of the unknown and leads to an improved model.Models have root mean square differences (r.m.s.d.s) with thestructures defined by X-ray analysis of between 0.73 and 1.56Å for all C atoms, for seven of the eight models. Forthe model of mucor pepsin, where the closest homologue has 33%sequence identity and 20% of the residues are in structurallyvariable regions, the r.m.s.d. for the framework region is 1.71Å and the r.m.s.d. for all C atoms is 3.47 Â.     

Melt rheology and morphology of PP/SEBS/PC ternary blend

Melt rheological properties of the ternary blend of isotactic polypropylene (PP), styreneethylene–butylene–styrene terpolymer (SEBS), and polycarbonate (PC), PP/SEBS/PC, are studied in a wide range of composition, such that PP is the matrix and SEBS and PC are the minor components, with the proportion of one varying from 0 to 30% at various fixed compositions of the other. The respective binary blends, PP/SEBS and PP/PC, studied as the reference systems for interpretation of results on the ternary blends yielded interesting new information about the morphology development and its correlation with melt rheological properties of these binary blends. The studies include the measurement of melt rheological properties on a capillary rheometer in the shear rate range 10¹–10⁴ s^?1 at a fixed temperature of 240°C. The data presented as conventional flow curves are analyzed for the effect of blend composition and shear rate on pseudoplasticity, melt viscosity, and melt elasticity, and role of each individual component is identified. Morphology of dispersed phases of these blends is studied through scanning electron microscopy of the cryogenically fractured and suitably etched surfaces. Variations of morphology with blend composition and shear rate showed interesting correlation with melt rheological properties, which are discussed in detail. An important finding of the morphological studies is that in the PP/SEBS/PC ternary blend the SEBS phase forms two types of morphologies depending on the blend composition and shear rate: (i) simple droplets and (ii) boundary layer at the surface of the PC droplets. © 1993 John Wiley & Sons, Inc.     

Explicit finite difference scheme for nonlinear convective problems

An explicit finite difference scheme is proposed for nonlinear convective problems. The procedure is applied to a nonlinear convective diffusion problem with a nonlinear boundary condition. It is shown that the nonlinear boundary condition may be treated directly without linearization which has to be carried out in the implicit method to avoid a nonlinear system of algebraic equations. The explicit procedure is more direct and less cumbersome than the implicit procedure and the answers are in excellent agreement with those of the implicit method.     

An electrochemically regenerative hydrogen-chlorine energy storage system: electrode kinetics and cell performance

The electrochemical oxidation and reduction of hydrogen and chlorine in hydrochloric acid has been investigated on graphite, ruthenized titanium and platinum electrodes. Both steady state and potentiostatic pulse methods were used. Cell studies were also carried out in cells with flow-by and flow-through chlorine electrodes. Results indicate that the electrode kinetics are fast and the electrolysis and fuel cell reactions can be carried out in the same cell with electric-to-electric efficiencies in excess of 75% at current densities of 300 mA cm^–2. Mass transfer limitations at the chlorine electrode during discharge can be eliminated by cell pressurization and the use of flow-through electrodes.This study was carried out under the auspices of the US Department of Energy.in the summers of 1976 and 1977