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751.
Sebastian Simon Marko Bertmer Gregor J. G. Gluth 《International Journal of Applied Ceramic Technology》2022,19(6):3179-3190
Hydrous lithium aluminosilicate (L–A–S–H) and lithium aluminate (L–A–H) gels are candidate precursors for glass-ceramics and ceramics with potential advantages over conventional processing routes. However, their structure before calcination remained largely unknown, despite the importance of precursor structure on the properties of the resulting materials. In the present study, it is demonstrated that L–A–S–H and L–A–H gels with Li/Al ≤ 1 can be produced via an organic steric entrapment route, while higher Li/Al ratios lead to crystallization of gibbsite or nordstrandite. The composition and the structure of the gels was studied by thermogravimetric analysis, X-ray diffraction, 27Al and 29Si magic-angle spinning nuclear magnetic resonance, and Raman spectroscopy. Aluminium was found to be almost exclusively in six-fold coordination in both the L–A–H and the L–A–S–H gels. Silicon in the L–A–S–H gels was mainly in Q4 sites and to a lesser extent in Q3 sites (four-fold coordination with no Si–O–Al bonds). The results thus indicate that silica-rich and aluminium-rich domains formed in these gels. 相似文献
752.
Herwig Prasch Dr. Andreas Wolfsgruber Dr. Martin Thonhofer André Culum Christoph Mandl Dr. Patrick Weber Melanie Zündel Dr. Seyed A. Nasseri Dr. Andres Gonzalez Santana Dr. Gregor Tegl Prof. Dr. Bernd Nidetzky Prof. Dr. Karl Gruber Prof. Dr. Arnold E. Stütz Prof. Dr. Stephen G. Withers Prof. Dr. Tanja M. Wrodnigg 《Chembiochem : a European journal of chemical biology》2023,24(23):e202300480
Selective covalent labelling of enzymes using small molecule probes has advanced the scopes of protein profiling. The covalent bond formation to a specific target is the key step of activity-based protein profiling (ABPP), a method which has become an indispensable tool for measuring enzyme activity in complex matrices. With respect to carbohydrate processing enzymes, strategies for ABPP so far involve labelling the active site of the enzyme, which results in permanent loss of activity. Here, we report in a proof of concept study the use of ligand-directed chemistry (LDC) for labelling glycoside hydrolases near – but not in – the active site. During the labelling process, the competitive inhibitor is cleaved from the probe, departs the active site and the enzyme maintains its catalytic activity. To this end, we designed a building block synthetic concept for small molecule probes containing iminosugar-based reversible inhibitors for labelling of two model β-glucosidases. The results indicate that the LDC approach can be adaptable for covalent proximity labelling of glycoside hydrolases. 相似文献
753.
Lincoln Sherpa Ralph Müller-Pfefferkorn Udo Enste Gregor Tolksdorf Michael Kawohl Michael Wiedau 《化学,工程师,技术》2023,95(7):1070-1076
Summarizing a key use case of a research workstream of the German publicly funded KEEN project, methods and tool chains are demonstrated to extract and to contextualize process data in an automated way based on engineering information. The contextualized process data serves as a high-quality data source for machine learning methods. The article covers the applied basic methodical approaches, design decisions and the results of a successful pilot installation of the developed tool chain. 相似文献
754.
Darina Makov Ivan Kov
ik Gregor Ondrejovi
《Advanced Synthesis \u0026amp; Catalysis》1991,333(3):389-396
By replacement of methanol in the Cu4OX6(MeOH)4 (X Cl, Br) complexes with thiourea (tu), N,N′-diphenylthiourea (diftu), N,N′-dimethlthiourea (dimtu), tetramethylthiourea (tmtu) and acetylthiourea (actu), the complexes Cu4OCl6L4 where L tu, tu(0.3 Et2O), diftu, dimtu, tmtu, actu (0.5Et2O) and the complexes Cu4OBr6L4, where L tu, diftu, dimtu, tmtu have been prepared. Their infrared and electronic spectra indicate the presence of Cu4O grouping and the trigonal bipyramidal coordination of copper(II). These complexes exhibit e.p.r. signals in the temperature range 100–260 K, in contrast to other known complexes of this structural type, which showed the e.p.r. signals at significantly lower temperatures. Thiourea and its derivatives are not able to reduce copper(II) in reaction with the tetranuclear Cu4OX6(MeOH)4 complexes in methanol-ether solution due to the redox stabilizing effect of the tetranuclear structure. 相似文献