Covalent Adaptable Microstructures via Combining Two-Photon Laser Printing and Alkoxyamine Chemistry: Toward Living 3D Microstructures

Manufacturing programmable materials, whose mechanical properties can be adapted on demand, is highly desired for their application in areas ranging from robotics, to biomedicine, or microfluidics. Herein, the inclusion of dynamic and living bonds, such as alkoxyamines, in a printable formulation suitable for two-photon 3D laser printing is exploited. On one hand, taking advantage of the dynamic covalent character of alkoxyamines, the nitroxide exchange reaction is investigated. As a consequence, a reduction of the Young´s Modulus by 50%, is measured by nanoindentation. On the other hand, due to its “living” characteristic, the chain extension becomes possible via nitroxide mediated polymerization. In particular, living nitroxide mediated polymerization of styrene results not only in a dramatic increase of the volume (≈8 times) of the 3D printed microstructure but also an increase of the Young's Modulus by two orders of magnitude (from 14 MPa to 2.7 GPa), while maintaining the shape including fine structural details. Thus, the approach introduces a new dimension by enabling to create microstructures with dynamically tunable size and mechanical properties.     

256×256 focal plane array midwavelength infrared camera based on InAs/GaSb short-period superlattices

An infrared camera based on a 256×256 focal plane array (FPA) for the second atmospheric window (3–5 μm) has been realized for the first time with InAs/GaSb short period superlattices (SLs). The SL detector structure with a broken gap type-II band alignment was grown by molecular beam epitaxy on GaSb substrates. Effective bandgap and strain in the superlattice were adjusted by varying the thickness of the InAs and GaSb layers and the controlled formation of InSb-like bonds at the interfaces. The FPAs were processed in a full wafer process using optical lithography, chemical-assisted ion beam etching, and conventional metallization technology. The FPAs were flip-chip bonded using indium solder bumps with a read-out integrated circuit and mounted into an integrated detector cooler assembly. The FPAs with a cut-off wavelength of 5.4 μm exhibit quantum efficiencies of 30% and detectivity values exceeding 10¹³ Jones at T=77 K. A noise equivalent temperature difference (NETD) of 11.1 mK was measured for an integration time of 5 ms using f/2 optics. The NETD scales inversely proportional to the square root of the integration time between 5 ms and 1 ms, revealing background limited performance. Excellent thermal images with low NETD values and a very good modulation transfer function demonstrate the high potential of this material system for the fabrication of future thermal imaging systems.     

Messungen von mehreren Flüssigkeitspegeln in Tanks mit Mikrowellen

Übersicht In der Arbeit werden verschiedene Meßverfahren für die Detektion einer Trennschicht vorgestellt und deren Vor- und Nachteile aufgezeigt. Ausgehend von einem FSCW-Radar wird ein neuartiges mehrezielfähiges Auswerteverfahren, das Referenzmodell, vorgestellt. Untersuchungen zeigen, daß eine robuste Entfernungsbestimmung gegenüber Störungen mit sehr hoher Ortsauflösung erfolgen kann.

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Microwave gauging of liquids with the ability of detecting a waterlevel

Contents In this paper different measurement-setups are discussed which are able to detect a second liquid level in a tank. Their advantages and disadvantages are shown. For a FSCW-Radar a novel multitarget evaluating algorithm, the reference-model, is derived. Measurements show that the distance can be determined exactly and that a high resolution can be obtained.

     

Semi‐Markovian modelling and performance analysis of variable rate traffic in ATM networks

Semi‐Markovian processes (SMP) serve as a versatile means to model various traffic types generated by sources or superposed from links in ATM networks. An efficient discrete time analysis method is proposed for SMP/G/1 queueing systems to evaluate ATM switches with non‐renewal input. Some basic results are derived for the autocorrelation function of semi‐Markovian processes and for the effect of state space reduction on autocorrelation, which show how to represent correlated traffic with given characteristic by an adequate SMP model of limited size. This revised version was published online in June 2006 with corrections to the Cover Date.     

Conducting Domain Walls in Lithium Niobate Single Crystals

Ferroic materials play an increasingly important role in novel (nano)electronic devices. Recently, research on domain walls (DWs) receives a big boost by the discovery of DW conductivity (DWC) in BiFeO₃ and Pb(Zr_xTi_1‐x)O₃ ferroic thin films. Here, it is demonstrated that DWC is not restricted to thin films, but equally applies to millimeter‐thick wide‐bandgap, ferroic single crystals, such as LiNbO₃. In this material transport along DWs can be switched by super‐bandgap illumination and tuned by engineering the tilting angle of DWs with respect to the polar axis. The results are consistently obtained using conductive atomic force microscopy to locally map the DWC and macroscopic contacts, thereby in addition investigating the temperature dependence, DW transport activation energies, and relaxation behavior.     

Putting Queens in Carry Chains,N<Superscript><Emphasis Type="Italic">o</Emphasis>̱</Superscript>27

The N-Queens Puzzle is a fascinating combinatorial problem. Up to now, the number of distinct valid placements of N non-attacking queens on a generalized N × N chessboard cannot be computed by a formula. The computation of these numbers is instead based on an exhaustive search whose complexity grows dramatically with the problem size N. Solutions counts are currently known for all N up to 26. The parallelization of the search for solutions is embarrassingly simple. It is achieved by pre-placing the queens within a certain board region. These pre-placements partition the search space. The chosen extent of the pre-placement allows for a wide range of the partitioning granularity. This ease of partitioning makes the N-Queens Puzzle a great show-off case for tremendously parallel computation approaches and a flexible benchmark for parallel compute resources. This article presents the Q27 Project, an open-source effort targeting the computation of the solution count of the 27-Queens Puzzle. It is the first undertaking pushing the frontier of the N-Queens Puzzle that exploits the complete symmetry group D ₄ of the square. This reduces the overall computational complexity already to an eighth in comparison to a naive exploration of the whole search space. This article details the coronal pre-placement that enables the partitioning of the overall search under this approach. With respect to the physical implementation of the computation, it describes the hardware structure that explores the resulting subproblems efficiently by exploiting bit-level operations and their mapping to FPGA devices as well as the infrastructure that organizes the contributing devices in a distributed computation. The performance of several FPGA platforms is evaluated using the Q27 computation as a benchmark, and some intriguing observations obtained from the available partial solutions are presented. Finally, an estimate on the remaining run time and on the expected magnitude of the final result is dared.     

Area, Delay, and Power Characteristics of Standard-Cell Implementations of the AES S-Box

Cryptographic substitution boxes (S-boxes) are an integral part of modern block ciphers like the Advanced Encryption Standard (AES). There exists a rich literature devoted to the efficient implementation of cryptographic S-boxes, wherein hardware designs for FPGAs and standard cells received particular attention. In this paper we present a comprehensive study of different standard-cell implementations of the AES S-box with respect to timing (i.e. critical path), silicon area, power consumption, and combinations of these cost metrics. We examine implementations which exploit the mathematical properties of the AES S-box, constructions based on hardware look-up tables, and dedicated low-power solutions. Our results show that the timing, area, and power properties of the different S-box realizations can vary by up to almost an order of magnitude. In terms of area and area-delay product, the best choice are implementations which calculate the S-box output. On the other hand, the hardware look-up solutions are characterized by the shortest critical path. The dedicated low-power implementations do not only reduce power consumption by a large degree, but they also show good timing properties and offer the best power-delay and power-area product, respectively.     

Untersuchung der Rindenextrakte von Picea abies Karst

Spruce bark contains about 60% of extractable material. For the production of adhesives hot water extracts are suitable which can be produced in nearly 25% yield. The polyphenol content of these extracts is only 50%. Besides this, they contain water soluble hemicelluloses and pectines. Glucosides of hydroxystilbenes also could be identified.