Biological Removal of High Loads of Thiosulfate Using a Trickling Filter Under Alkaline Conditions

Uncontrolled release of thiosulfate can cause high oxygen demand, or generate toxic compounds under anaerobic scenarios. Biooxidation of thiosulfate in a biotrickling filter (BTF) colonized by an alkaliphilic sulfide-oxidizing bacterial consortium was studied at pH ≈10. Inlet thiosulfate concentrations were varied from 3.5 to 21.3 g L^?1, with a residence time of 216 s, emulating conditions encountered in wastewater from mining processes. Sulfate production, oxygen concentration, and biomass in both packing and effluent were periodically analyzed to characterize bioreactor performance. Removal efficiencies near 100 % were obtained during the entire experimental period, with a maximum elimination capacity of 242 g thiosulfate m^?3 h^?1. Although the BTF was able to transfer large amounts of oxygen to biooxidize thiosulfate to sulfate, under high initial thiosulfate loads, thiosulfate was not completely oxidized to sulfate, since biooxidation was conditioned to oxygen supply. Respirometric tests performed to investigate biomass adaptation and activity revealed oxygen consumption values of 0.5 mmol O₂ (g protein)^?1 min^?1 for the period with the highest thiosulfate inlet load.     

“Chipiplexing”只用微控制器少量端口驱动多只LED

实际的微控制器都有强大的双向I/O端口,可以用不同的技术来充分利用这些功能。最近有个设计实例描述了一种"Charlieplexing"方法,它是只用N个双向I/O端口和N个电阻,驱动     

Lipase-catalyzed acidolysis of sunflower oil: Kinetic behavior

In the present study, sunflower oil was modified with a palmitic–stearic acids blend by means of an immobilized sn-1,3 specific lipase (Lipozyme RM IM) to produce structured lipids. Products were analyzed to determine fatty acid incorporation (F_M) into triacylglycerol structure and to quantify by-products as monoglycerides (MG) and diglycerides (DG). The effects of the reaction conditions (temperature, time, incorporated water) on enzymatic acidolysis were studied. Nonlinear regression methods were employed to fit experimental data with kinetic models proposed in the literature. The disappearance of reactant fatty acids (RF) over time was successfully modeled by a Ping-Pong Bi-Bi mechanism. F_M was also represented with a lumped parameter model of the enzymatic mechanism. Maximum RF disappearance and F_M onto sunflower oil glycerides increased with increasing reaction temperature. MG and DG concentrations in water-free systems were stabilized in low levels, while the incorporation of water to the reaction mixture produced a considerable increase in DG formation principally. Kinetic and equilibrium parameters showed temperature dependencies.     

A sonar approach to obstacle detection for a vision-based autonomous wheelchair

An advanced prototype Computer Controlled Power Wheelchair Navigation System or CCPWNS has been developed to provide autonomy for highly disabled users, whose mix of disabilities makes it difficult or impossible to control their own power chairs in their homes. The working paradigm is “teach and repeat” a mode of control for typical industrial holonomic robots. Ultrasound sensors, which during subsequent autonomous tracking will be used to detect obstacles, also are active during teaching. Based upon post-processed data collected during this teaching event, elaborate trajectories–which may involve multiple direction changes, pivoting and so on, depending upon the requirements of the typically restricted spaces within which the chair must operate–will later be called upon by the disabled rider. An off-line postprocessor assigns an ultrasound profile to the sequence of poses of any taught trajectory. Use of this profile during tracking obviates most of the inherent problems of using ultrasound to avoid obstacles while retaining the ability to near solid objects, such as when passing through a narrow doorway, where required by the environment and trajectory objectives. The work in this article describes a procedure to obtain consistent maps of sonar boundaries during the teaching process, and a preliminary approach to use this information during the tracking phase. The approach is illustrated by results obtained by using the CCPWNS prototype.     

A BER-Based Partitioned Model for a 2.4GHz Vehicle-to-Vehicle Expressway Channel

Statistical channel models based on BER performance are presented for a frequency- and time-selective vehicle-to-vehicle wireless communications link in an expressway environment in Atlanta, Georgia, where both vehicles traveled in the same direction. The models are developed from measurements taken using the direct sequence spread spectrum (DSSS) technique at 2.45GHz. A collection of tapped delay line models, referred to as a “partitioned” model in the paper, is developed to attempt to capture the extremes of BER performance of the recorded channel. Overall and partition models are compared to the recorded channel in terms of the BER statistics obtained when the channels are inserted in a dedicated short range radio (DSRC) standard simulation system. The quality of the match between synthesized and recorded channel BER statistics is analyzed with respect to type of modulation (fixed or adaptive), the frame length, and the length of the interval over which the BER was calculated. Guillermo Acosta was born in Mexico City, Mexico, in 1962. He is a Ph.D. Candidate and a graduate research assistant in the School of Electrical and Computer Engineering at the Georgia Institute of Technology, in Atlanta, Georgia. He obtained his Bachelor of Engineering with Honors and Master of Engineering, both in Electrical Engineering, from Stevens Institute of Technology, Hoboken, New Jersey, in 1985 and 1987, respectively. He also obtained a Master of Business Administration with Honors from the Instituto Tecnologico Autonomo de Mexico (ITAM), Mexico City, Mexico, in 1996. Mr. Acosta has held technical and managerial positions in the recording, radio, and TV industries and in the Communications Ministry of Mexico. He has been an adjunct instructor in Electrical Engineering in the Instituto Tecnologico y Estudios Superiores de Monterrey Campus Estado de Mexico (ITESM-CEM) and the Universidad Iberoamericana. He is member of the IEEE, INCE, Tau Beta Pi, and Eta Kappa Nu. Mary Ann Ingram received the B.E.E. and Ph.D. degrees from the Georgia Institute of Technology, in Atlanta, Georgia, in 1983 and 1989, respectively. From 1983 to 1986, she was a Research Engineer with the Georgia Tech Research Institute in Atlanta, performing studies on radar electronic countermeasure (ECM) systems. In 1986, she became a graduate research assistant with the School of Electrical and Computer Engineering at the Georgia Institute of Technology, where in 1989, she became a Faculty Member and is currently Professor. Her early research areas were optical communications and radar systems. In 1997, she established the Smart Antenna Research Laboratory (SARL), which emphasizes the application of multiple antennas to wireless communication systems. The SARL performs system analysis and design, channel measurement, and prototyping, relating to a wide range of wireless applications, including wireless local area network (WLAN) and satellite communications, with focus on the lower layers of communication networks. Dr. Ingram is a Senior Member of the IEEE.     

Comparison between simulated moving bed and reverse flow chromatographic reactors for equilibrium limited reactions

A staged linear model, containing five parameters, is developed to compare equivalent simulated moving bed chromatographic reactors (SMBCR) and reverse flow chromatographic reactors (RFCR). A first order reversible reaction and linear adsorption equilibrium, with preferential adsorption of the reactant is assumed. The analysis uses simple, easily computable analytical solutions that rigorously represents the transients in the cyclic steady state for both the RFCR and the SMBR. A comparison between the two types of reactors is carried out to determine the maximum conversion attainable and the range of operation where these systems have advantages over conventional steady state reactors. It is found that the maximum conversion of both reactors is similar. The range of operation in terms of amount of catalyst and range of switching times favors the RFCR, while the conversion at low separation factors favors the SMBCR.     

Protective Silica Coatings on Zinc-Sulfide-Based Phosphor Particles

A spray drying approach was used to apply 15-nm-thick SiO₂ continuous coatings onto ZnS:Ag phosphor particles. A prehydrolyzed TEOS dip coating formula was used as the SiO₂ precursor. The phosphor was mixed together with the precursor then atomized without allowing gelation to occur until the droplets containing the particles were in flight. The coating gelled and dried while falling through a graded heat zone. The dried coated particles were captured in a cyclone separator and heat-treated to further densify the SiO₂ coating. The coatings protected the phosphors while in service in field emission display (FED) devices.     

The activation of fibroblast growth factors (FGFs) by glycosaminoglycans: influence of the sulfation pattern on the biological activity of FGF-1

Six synthetic heparin-like oligosaccharides have been used to investigate the effect of the oligosaccharide sulfation pattern on the stimulation of acidic fibroblast growth factor (FGF-1) induced mitogenesis signaling and the biological significance of FGF-1 trans dimerization in the FGF-1 activation process. It has been found that some molecules with a sulfation pattern that does not contain the internal trisaccharide motif, which has been proposed for high affinity for FGF-1, stimulate FGF-1 more efficiently than those with the structure of the regular region of heparin. In contrast to regular region oligosaccharides, in which the sulfate groups are distributed on both sides of their helical three-dimensional structures, the molecules containing this particular sulfation pattern display the sulfate groups only on one side of the helix. These results and the fact that these oligosaccharides do not promote FGF-1 dimerization according to sedimentation-equilibrium analysis, confirm the importance of negative-charge distribution in the activation process and strongly suggest that FGF dimerization is not a general and absolute requirement for biological activity.