Chemical structure designing to enhance the yield stress of electrorheological fluids based on modified chitosan compounds

For studying the influences of alkyl chain length, end groups of the side chains, and mixture on enhancing the shear stress of electrorheological (ER) fluids, chitosan carboxylates were synthesized for ER particles and prepared ER fluids by dispersing the particles in silicone oil. After comparing the shear stress of all prepared ER fluids, the conclusion obtained was that ER particles having two functional groups showed higher shear stress than those having one functional group. However, after mixing two ER particles having one functional group respectively, the ER fluid having those particles showed a lower shear stress. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 1559–1566, 2004     

Preparation of transparent ts-1 zeolite film and its photocatalytic isomerization under uv irradiation

TS-1 zeolite film has been prepared by using nano sized TS-1 zeolite particles for the photocatalytic isomerization of cis-2-butene. TS-1 zeolite film showed optical transparent property and the thickness of film was 0.7 μm. UV irradiation of TS-1 zeolite film in the presence ofcis-2-butene leads to the photocatalytic isomerization ofcis-2-butene intotrans-2-butene at the temperature of 275 K. The yield oftrans- 2-butene was linearly increased with UV-irradiation time.     

Cyclic behaviour of post-Northridge WUF-B connections

The purpose of this study is to evaluate the cyclic behavior of post-Northridge Welded Unreinforced Flange-Bolted web (WUF-B) connections made using new notch tough welding materials and welding procedures, and a modified access hole. Since no WUF-B connection test results were found which satisfy the minimum design and detail requirements of the 2002 AISC Seismic Provisions for Structural Steel Buildings, this study made three full-scale test specimens of WUF-B connections according to the provisions. The main variable of the specimens was the ratio of the panel zone strength to the connected beam strength (panel zone strength ratio). Quasi-static cyclic testing was conducted. This study found that post-Northridge WUF-B connection specimens having a stronger panel zone experienced more significant slip between the bolted shear tab and the beam web. It was observed that the slip caused stress concentrations in and around the access hole, resulting in connection failure. The WUF-B connection specimen having the weakest panel zone did not, however, experience excessive slip between the bolted shear tab and beam web. Moreover, this WUF-B specimen could not achieve the required beam strength. This study observed that post-Northridge WUF-B connections with a panel zone strength ratio ranging from 0.9 to 1.6 provides a drift ratio exceeding 0.2. This drift ratio is required for satisfactory performance of the connections of Intermediate Moment Frames. Furthermore, this study proposed an analytical model for post Northridge WUF-B connections having different panel zone strength ratios.     

InGaAs/InP heterostructures with strained quantum wells and quantum dots (λ=1.5–1.9 µm)

Strongly strained In_xGa_1−x As/In_0.53Ga_0.47As/InP heterostructures with indium content x=0.69−1.0 in the active region were investigated experimentally and theoretically. Two types of structures were obtained by vapor-phase epitaxy from metalorganic compounds: 1) with isolated compression-strained quantum wells and 2) with self-organized nanosize InAs clusters (quantum dots). The temperature dependence of the quantum radiation efficiency of samples with quantum wells in the temperature range 77–265 K is characterized by T ₀=43 K. One reason for the low value of T ₀ is electron delocalization in the active region. The maximum radiation wavelength obtained in structures with quantum dots is 1.9 μm at 77 K. Fiz. Tekh. Poluprovodn. 33, 1105–1107 (September 1999)     

A study on UV-curable coatings for HD-DVD: Primer and top coats

This study relates to the development of coatings for optical discs in high-density digital versatile disc systems (HD-DVD or blue lay disk) that use a high numerical aperture of 0.85 at 405 nm wavelength and have a protective top layer over a primer layer for protection against damage and dust. Ultraviolet-curable raw materials of two acrylic monofunctional monomers ( isobornylacrylate, IBA and tetrahydrofurfurylacrylate, THFA) and two kinds of urethaneacrylate oligomers (OUMD and OUME) have been easily mixed with photoinitiators. Curing rate of these materials was characterized by FT-IR. In case of top coats, VTES (vinyltriethoxysilane) and acrylic acid were added to enhance the abrasion resistance. These two kinds of UV-curable resinous materials having no solvent were synthesized and investigated as means for making a blue ray disk having good optical and mechanical properties. In addition, dynamic characteristics including reflectivity, fluctuation of RF signal and noise level were also investigated.     

Ozonolysis of cyclododecene

Ozonolysis of cyclododecene was carried out to produce an w-formyl carboxylic acid (12-oxododecanoic acid) which is derived from zwitterion and aldehyde moiety that are formed during the reaction. The ozonolysis was performed to examine the product distribution under such reaction variables as temperature, kinds of solvent, and presence of catalyst. The yield of polymeric ozonide, which is undesirable product, was measured to be dominantly 86% without pyridine catalyst, whereas, only 10.25% with the catalyst. The optimum reaction condition was to be in MC (methylene chloride) solvent, and in the presence of equimolar olefin and pyridine catalyst at O°C, at which the yields of polymeric ozonide, 1,12-dodecanedialdehyde, 1,12-dodecanedicarboxylic acid, and 12-oxo-dodecanoic acid were 10.25%, 26.72%, 26.31%, and 36.72%, respectively.     

压力容器定期检验方案的制定

以一台1万m3液化石油气球罐的定期检验方案为例,介绍一般压力容器定期检验方案的制定方法、内容和重点,供有关人员参考。     

龙滩矿井采煤工作面诱发开采沉陷的动态变化特征

为掌握地下开采引起的地表沉降动态变化规律与特征,在龙滩矿井3115工作面对应地表建立地表移动观测站,运用理论分析法对监测数据进行分析整理,据此绘制地表移动变形曲线并详细叙述其特征。研究结果表明：地表最大下沉值约为73 mm;各测点的下沉值、倾斜值及曲率值随工作面推进呈逐渐增大的变化规律。通过掌握工作面开采时地表移动变形规律,可为开采沉陷综合治理及矿区地质环境保护工作提供数据支持和技术性指导。     

Fluorescent dye labeled bacteriophages--a new tracer for the investigation of viral transport in porous media: 1. Introduction and characterization

A new method for the study of pathogen transport in porous media is presented. The method is based on conjugation of fluorescent dyes to target bacteriophages and application of the modified bacteriophages for tracer studies. We demonstrate that the relevant transport determining properties of Rhodamine and several fluorescein-labeled phages are practically identical to those of the native bacteriophages. The advantages of the proposed method relative to direct enumeration of bacteriophages by plaque forming unit method, turbidity, fluorescent microspheres, and other alternative tracers are discussed. Notable advantages include simple quantitation by optical methods, unbiased signals even when virus aggregates are formed, and the ability to decouple inactivation kinetics from transport phenomena. Additionally, the signal reflects the removal and transport of the studied microorganism and not a surrogate.