Tailored microstructure of zirconia and hafnia-based thermal barrier coatings with low thermal conductivity and high hemispherical reflectance by EB-PVD

Zirconia and hafnia based thermal barrier coating materials were produced by industrial prototype electron beam-physical vapor deposition (EB-PVD). Columnar microstructure of the thermal barrier coatings were modified with controlled microporosity and diffuse sub-interfaces resulting in lower thermal conductivity (20–30% depending up on microporosity volume fraction), higher thermal reflectance (15–20%) and more strain tolerance as compared with standard thermal barrier coatings (TBC). The novel processed coating systems were examined by various techniques including scanning electron microscopy (SEM), X-ray diffraction, thermal conductivity by laser technique, and hemispherical reflectance.     

Elastohydrodynamic analysis of a cylindrical journal bearing with a flexible bearing shell

The effect of the elastic deformation of a bearing shell was considered in the determination of the performance characteristics of a hydrodynamic journal bearing. The finite element method with an iteration scheme was employed to solve the Reynolds equation governing flow in the clearance space and the three-dimensional linear elasticity equations representing the displacement vector field in the bearing shell. For design convenience a nondimensional deformation coefficient ψ relating μ, E_m, U₀ , C, R_j and tis defined. The performance characteristics were obtained in terms of load-carrying capacity, fluid flow, power loss and attitude angle for an aspect ratio $\text{L}\text{D = 1}$, eccentricity ? = 0.6 and for a wide range of deformation coefficients. The results are compared for bearing materials having Poisson's ratio v equal to 0.3 and 0.4.     

pH-Metric Studies on the interaction of oxovanadium (IV) with iminodiacetic (IMDA) and nitrilotriacetic (NTA) acids

Solution equilibrium studies on the interaction of oxovanadium (IV) with iminodiacetic (IMDA) and nitrilotriacetic (NTA) acids have been carried out. pH-Titrations of the reaction mixtures containing vanadyl sulphate and aminopolycarboxylic acid in equimolar ratio have shown the formation of 1:1 chelates. With IMDA, the possibility of 1:2 chelate (metal ion: IMDA) is also indicated. The equilibrium, chelate formation, hydrolysis and polymerization constants have been calculated at 25 and 30°C and also the thermodynamic functions viz. ΔH, ΔF, and ΔS.     

FMS machine loading: A simulated annealing approach

In this paper the problem of FMS machine loading is considered with the objective of minimizing the system imbalance using a simulated annealing (SA) approach. New job sequences are generated with a proposed perturbation scheme named the 'modified insertion scheme' (MIS). These sequences are used in the proposed simulated annealing algorithm to arrive at a near global optimum solution. A new approach for temperature variation in the SA algorithm is also suggested in which temperature is assumed to be parabolic. The SA algorithm using the proposed MIS and the assumed temperature variation proved to be giving substantial improvement in system imbalance as against conventional sequences.     

Selection of the optimum decomposition level using the discrete wavelet transform for automobile suspension system

Journal of Mechanical Science and Technology - This paper discusses the determination of the optimum decomposition level by using the discrete wavelet transform (DWT) method for an automobile...     

Design and Development of a Bimodal Optical Instrument for Simultaneous Vibrational Spectroscopy Measurements

Vibrational spectroscopy techniques are widely used in analytical chemistry, physics and biology. The most prominent techniques are Raman and Fourier-transform infrared spectroscopy (FTIR). Combining both techniques delivers complementary information of the test sample. We present the design, construction, and calibration of a novel bimodal spectroscopy system featuring both Raman and infrared measurements simultaneously on the same sample without mutual interference. The optomechanical design provides a modular flexible system for solid and liquid samples and different configurations for Raman. As a novel feature, the Raman module can be operated off-axis for optical sectioning. The calibrated system demonstrates high sensitivity, precision, and resolution for simultaneous operation of both techniques and shows excellent calibration curves with coefficients of determination greater than 0.96. We demonstrate the ability to simultaneously measure Raman and infrared spectra of complex biological material using bovine serum albumin. The performance competes with commercial systems; moreover, it presents the additional advantage of simultaneously operating Raman and infrared techniques. To the best of our knowledge, it is the first demonstration of a combined Raman-infrared system that can analyze the same sample volume and obtain optically sectioned Raman signals. Additionally, quantitative comparison of confocality of backscattering micro-Raman and off-axis Raman was performed for the first time.     

Localization-limited exciton oscillator strength in colloidal CdSe nanoplatelets revealed by the optically induced stark effect

2D materials are considered for applications that require strong light-matter interaction because of the apparently giant oscillator strength of the exciton tra...