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91.
Ana Isabel Nájera Yolanda Barcina Mercedes de Renobales L. J. R. Barron 《European Food Research and Technology》1998,207(3):197-201
The influence of traditional smoking on the triglyceride (TG) composition of Idiazabal cheese during ripening was studied
using HPLC. The partition numbers (PNs) of the TGs ranged between 22 and 53, the groupings of TG peaks with PN values of 36,
34, and 38 being the main contributors. Statistically significant differences between the smoked and the unsmoked cheeses
were recorded during the ripening period. Smoking had a significant effect on certain groups of TGs at different ripening
times and no effect on others. The differences in the TG profiles of the cheeses were the result of differing levels of lipolytic
activity, which was heightened by smoking.
Received: 29 December 1997 / Revised version: 9 March 1998 相似文献
92.
Jérôme Lopez Gustavo Caceres Elena Palomo Del Barrio Wahbi Jomaa 《International Journal of Heat and Mass Transfer》2010,53(5-6):1195-1207
This paper deals with phase change in composite materials made of graphite and a phase-change material (PCM). The composites are manufactured by compressing a solid mixture of salt and graphite particles. In previous works, the interest of such materials for thermal energy storage at high temperature has been highlighted. They are characterized by quite high energy storage capacity as well as high thermal conductivity. However, first melting/crystallization of these composites could lead to significant salt leakage and shows some a priori unexpected features like melting over a range of temperature instead of at constant temperature and significant loss of heat storage capacity. A poro-thermo-elastic analysis is carried out in this paper for understanding salt melting within the graphite matrices and for proposing reliable ways for composite materials improvement. An intentionally simple think-model, based on mass and energy conservation equations, pressure-dependent liquid–crystal equilibriums, linear elasticity laws and Poiseuille-like flow, is proposed. In spite of the simplicity, the model turns out to be apt to explain main macroscopic features of materials melting as observed in calorimetric tests. The influence on melting dynamics of parameters like the heating rate, the pore-wall rigidity and thickness, the salt volume expansion and the pore connectivity is investigated and several ways for composite materials improvements are discussed. 相似文献
93.
José A. Amador David Sotomayor-Ramírez Gustavo Martínez Lixian Chen Dave Bachoon 《Lakes & Reservoirs: Research and Management》2008,13(4):301-317
Using a combination of chemical and microbiological (culture-dependent and -independent) approaches, sources of human faecal contamination were identified in two water reservoirs in Puerto Rico – Guajataca and La Plata. Fluorescence from optical brighteners (OB) – commonly found in laundry detergents – was used as an indicator of contamination from septic systems and other household discharges. Traditional indicators of faecal contamination (e.g. Escherichia coli; faecal enterococci) were enumerated, and human faecal contamination was confirmed through detection of Bifidobacterium adolescentis utilizing polymerase chain reaction (PCR)-based analyses. For Guajataca Reservoir, four of 19 sampling sites (21%) were positive for the presence of B. adolescentis under baseflow conditions. The OB fluorescence data suggested that the most likely source for three of these sites was residential, whereas the source of contamination at the remaining site, although of human origin, was probably non-residential. B. adolescentis was present in 83% (19 of 23) of the sampling sites in La Plata. The La Plata sources were more difficult to identify because samples were taken under stormflow conditions, although the presence of OB fluorescence suggested a residential origin in a number of instances. OB fluorescence and traditional bacterial indicators of faecal contamination produced a number of false positive and negative findings for both reservoirs, pointing to the importance of understanding the limitations of these tools for tropical freshwater systems. The results of this study should be useful in developing a weight-of-evidence approach for the identification of potential sources and extent of human faecal contamination in similar tropical reservoirs, a necessary step in the development of management plans to reduce or eliminate these sources. 相似文献
94.
José Luis García-Gutiérrez Gustavo A. Fuentes Maria Eugenia Hernández-Terán Ponciano García Florentino Murrieta-Guevara Federico Jiménez-Cruz 《Applied Catalysis A: General》2008,334(1-2):366-373
This work presents the results obtained in the development of Mo/γ-Al2O3 catalysts and their evaluation in the oxidative desulfurization (OD) process of diesel fuel using hydrogen peroxide as the oxidizing reagent. The catalysts were prepared by equilibrium adsorption using several molybdenum precursors and aluminas with different acidity values. They were characterized by Raman spectroscopy. The effect of the reaction time, reaction temperature, nature of solvent, concentration of solvent and hydrogen peroxide, content of molybdenum and phosphate in the catalysts were investigated. The results showed that the activity for sulfur elimination depends mainly on the presence of hepta- and octamolybdates species on the catalyst support and the use of a polar aprotic solvent. Likewise, the presence of phosphate markedly increases the sulfur elimination. In this way, it is possible to reduce sulfur level in diesel fuel from about 320 to less than 10 ppmw at 333 K and atmospheric pressure. Additionally, on the basis of the results obtained a mechanistic proposal for this reaction is described, as an oxidation mechanism by nucleophilic attack of the sulfur atom on peroxo species of hepta- and octamolybdates, but a mechanism involving the singlet oxygen presence can be discarded. 相似文献
95.
Gustavo Da Silva Rita Serrano Elsa Teixeira Gomes Olga Silva 《Microscopy research and technique》2015,78(11):1001-1009
Gymnosporia arenicola Jordaan (Celastraceae) is a shrub or small tree, which naturally occurs in coastal sand dunes of Southern Mozambique and South Africa. Its dried leaf is often used in traditional medicine for the treatment of infectious and inflammatory diseases. Hereby, we present results of studies carried out according to the pharmacopoeia standards for the identification of herbal drugs, in the whole, fragmented, and powdered plant material. These results were complemented with scanning electron microscopy and histochemical techniques. The leaf microscopic analysis revealed a typical dorsiventral mesophyll with a corresponding spongy parenchyma–palisade parenchyma ratio of 0.60, anomocytic and paracytic stomata, papillate cells with a diameter of 4.00 ± 0.40 µm, multicellular uniseriate nonglandular trichomes with a length of 27.00 ± 4.10 µm and cristalliferous idioblasts containing calcium oxalate cluster crystals with a diameter of 23.04 ± 5.84 µm. The present findings demonstrate that the G. arenicola leaf has both nonglandular trichomes and hypoderm, features not previously described in the corresponding botanical section (Gymnosporia sect. Buxifoliae Jordaan). The establishment of these new botanical markers for the identification of G. arenicola leaf is essential for quality, safety and efficacy reasons. Microsc. Res. Tech. 78:1001–1009, 2015. © 2015 Wiley Periodicals, Inc. 相似文献
96.
Physiological and biochemical characteristics of the ethyl tiglate production pathway in the yeast Saprochaete suaveolens
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Eric Grondin Alain Shum Cheong Sing Yanis Caro Gustavo M. de Billerbeck Jean Marie François Thomas Petit 《Yeast (Chichester, England)》2015,32(1):57-66
A yeast identified as Saprochaete suaveolens was investigated for its capacity to produce a large panel of flavouring molecules. With a production of 32 compounds including 28 esters, S. suaveolens seems to be a good producer of fruity flavours and fragrances and especially of unsaturated esters, such as ethyl tiglate. Physiological and biochemical analyses were performed in this study in an attempt to comprehend the metabolic route to the formation of this compound. We show that the accumulation of ethyl tiglate by S. suaveolens is specifically induced by isoleucine. However, and contrary to S. cerevisiae, which harbours a classical Ehrlich pathway leading to the production of 2‐methylbutanol from isoleucine, our results provide phenotypic and enzymological evidence of ethyl tiglate biosynthesis in S. suaveolens through the catabolism of this amino acid by the β‐oxidation pathway, which generates tiglyl‐CoA as a probable intermediate. A kinetic analysis of this flavour molecule during growth of S. suaveolens on glucose and isoleucine showed a phase of production of ethyl tiglate that culminated concurrently with isoleucine exhaustion, followed by a disappearance of this compound, likely due to reassimilation by the yeast. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
97.
Lessening polygalacturonase activity in a commercial enzyme preparation by exposure to pulsed electric fields 总被引:1,自引:0,他引:1
Joaquín?Giner Vicente?Gimeno Montserrat?Palomes Gustavo?V.?Barbosa-Cánovas Olga?MartínEmail author 《European Food Research and Technology》2003,217(1):43-48
The effect of high-intensity pulsed electric field (HIPEF) treatments on polygalacturonase (PG) activity in an aqueous solution of a commercial enzyme preparation was evaluated. HIPEF treatments reduced PG activity notably. Exponentially decaying pulses of 40 and 160 µs generated by a laboratory scale device were applied in a batch processing and bipolar mode. Electric fields ranged from 5.18 to 19.39 kV/cm. The number of pulses ranged up to 400. Temperature was always below 25 °C. Maximum inactivation of PG activity (98%) required 32.4 ms HIPEF treatment at 10.28 kV/cm. PG activity depleted exponentially because of HIPEF treatments. The first order rate constants ranged from 32 to 590 µs -1 and increased exponentially with electric field intensity. PG activity decreased exponentially with input electric energy density. 相似文献
98.
Discrimination of Euterpe oleracea Mart. (Açaí) and Euterpe edulis Mart. (Juçara) Intact Fruit Using Near‐Infrared (NIR) Spectroscopy and Linear Discriminant Analysis
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99.
Pedro Henrique Hatumura Guilherme Santana de Oliveira Gustavo Galo Marcheafave Miroslava Rakocevic Roy Edward Bruns Ieda Spacino Scarminio Amelia Elena Terrile 《Food Analytical Methods》2018,11(7):1906-1914
High planting density has been used to increase coffee production but there are few studies related to the variations it provokes in metabolite compositions. The use of 1H NMR data associated with chemometric techniques allows the determination of metabolic fingerprints and verification of metabolic changes when coffee is subjected to high planting densities. The aim of this work is to investigate 1H NMR spectral data of green bean extracts of Coffea arabica cv. IAPAR 59 grown in a square pattern at two planting densities, 6000 and 10,000 plants ha?1. Thirty extracts were obtained using a simplex centroid design with four solvents (ethanol, acetone, dichloromethane, and hexane). The lyophilized extracts were dissolved in DMSO-d6 to obtain the 1H NMR spectra. The spectral data were analyzed with principal component (PCA) and cluster analyses (CA). Significant differences between ethanolic and non-ethanolic extracts were found by PCA. Only the ethanolic mean spectrum showed characteristic chemical shifts of sugars and trigonelline. Acetone extracts were separated by cluster analysis. 相似文献