The effect of ionic interaction on the miscibility and crystallization behaviors of poly(ethylene glycol)/poly(L‐lactic acid) blends

The effect of end groups (2NH₂) of poly(ethylene glycol) (PEG) on the miscibility and crystallization behaviors of binary crystalline blends of PEG/poly(L ‐lactic acid) (PLLA) were investigated. The results of conductivity meter and dielectric analyzer (DEA) implied the existence of ions, which could be explained by the amine groups of PEG gaining the protons from the carboxylic acid groups of PLLA. The miscibility of PEG(2NH₂)/PLLA blends was the best because of the ionic interaction as compared with PEG(2OH, 1OH‐1CH₃, and 2CH₃)/PLLA blends. Since the ionic interaction formed only at the chain ends of PEG(2NH₂) and PLLA, unlike hydrogen bonds forming at various sites along the chains in the other PEG/PLLA blend systems, the folding of PLLA blended with PEG(2NH₂) was affected in a different manner. Thus the fold surface free energy played an important role on the crystallization rate of PLLA for the PEG(2NH₂)/PLLA blend system. PLLA had the least fold surface free energy and the fast crystallization rate in the PEG(2NH₂)/PLLA blend system, among all the PEG/PLLA systems studied. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Effects and properties of poly(arylene ether benzonitrile)s of various molecular weights blended with sulfonated poly(ether ether ketone)

Poly(arylene ether benzonitrile) (PAEBN) was synthesized with 2,6‐dichlorobenzonitrile and biphenol. PAEBNs with various molecular weights (MWs), 1,640,000 and 185,000 g/mol, were synthesized by control of the stoichiometry of the monomers and were blended with sulfonated poly(ether ether ketone) (SPEEK). The effects of MW on the water uptake, swelling, methanol permeability, and proton conductivity of the SPEEK/PAEBN blend membranes were investigated. The molecular mobility of the SPEEK/PAEBN blends was also examined in this study. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

土钉加锚杆联合支护基坑的失稳分析及处理

根据具体工程实例,介绍了在基坑开挖时采用土钉加锚杆的联合支护方式后在施工过程中出现坍塌裂缝的现象,针对这一现象,分析了施工条件与环境,得出了事故发生的原因,并结合实际情况提出了处理措施.     

带传动摆架式自动张紧装置的张紧力计算

基于带传动在稳定工作时的受力平衡，从理论上导出了摆架式自动张紧装置所产生的张紧力的计算公式。结果表明：只要合理选择计算安装参数，其张紧力总能满足张紧条件的要求，以对张紧装置进行设计计算；并指出该装置产生的张紧力，具有随外载荷变化而自动调节的性能，使传力零件部分卸载。     

Solution-chemistry analysis of ammonium bicarbonate consumption in rare-earth-element precipitation

A solution-chemistry analysis is applied to estimating the consumption of ammonium bicarbonate in the recovery of rare-earth (RE) elements from leachates of weathered clays. The theoretical analysis shows that a two-step process is needed for recovering RE from the leachates of the weathered clays by precipitation using ammonium bicarbonate. The first step is a precipitation at solution pH 5 to remove impurities such as Fe and Al. The second step is to precipitate RE by adjusting the solution pH above 8. The consumption of ammonium bicarbonate was found to depend on the concentration of RE elements and impurities in the leachates. The total amount of ammonium bicarbonate consumption for the entire process was determined experimentally, and the results showed an excellent agreement with that calculated based on solution-chemistry analysis. The decomposition of H₂CO₃ was identified as one of the main causes of ammonium bicarbonate overdose, accounting for up to 41 pct in comparison to 20 pct consumption for the removal of impurities. The amount of ammonium bicarbonate required in terms of the NH₄HCO₃: RE₂O₃ (RE oxides) molar ratio was found to be 4:1 for maximal RE recovery. An overall RE recovery around 90 pct was achieved with a product purity being about 90 pct.     

劈刀和肋环夹持工况对超声键合换能系统电学特性的影响

通过实验分析了肋环夹持松紧度和劈刀存在两个因素对超声键合换能系统电学导纳特性的影响规律。对换能系统在悬挂有无劈刀和夹持8个松紧度等各个情况下进行谐振频率附近的导纳圆测量,确定换能系统等效电路各特征参数的变化情况。由实验结果的分析可知,劈刀的附加质量以及肋环松紧程度对换能系统谐振频率的影响不大,但劈刀的存在改变了换能系统的能量分布和耗散,是影响换能系统各特征参量的主要因素之一。这些结论有助于超声键合换能系统的优化。     

加工矿用液压支柱工艺设备的改进

通过对加工矿用液压支柱工艺设备润滑系统的综合分析,提出了用潜水电泵替代原机床配套的螺杆油泵构想。改造后,年节约资金5.9万元。     

曲柄摇杆机构的三圆图解设计法

这里探讨了对给定行程速比系数K，摇杆摆角ψ，另外再给定摇杆长度l3(机架长度l4)、曲柄长度l1(连杆长度l2)等，找出如何运用辅助圆图解设计曲柄摇杆机构的方法。