双核稀土配合物Gd_xSm_(1-x)(TTA)_3phen的制备及发光性能

合成了系列钆钐双核稀土有机配合物GdxSm1-x(TTA)3phen(x=0~0.9).红外光谱(IR)、X射线衍射(XRD)、热重(TG)结果推测了配合物可能的分子结构;紫外可见光谱(UV/vis)结果表明,该系列稀土有机配合物能有效的吸收紫外光,吸收峰主要来自于有机配体TTA和phen(270nm和351nm处);荧光光谱(FS)结果表明,Gd3+对于Sm3+具有荧光增效,当Gd3+的摩尔分数为0.6时,Gd0.6Sm0.4(TTA)3phen类配合物的特征荧光(562nm,596nm和643nm处)强度均达到最大.     

变热流工况土壤导热系数对热恢复特性的影响研究

土壤热恢复特性是土壤源热泵长期稳定高效运行的决定性因素之一.土壤导热系数是土壤热物性最重要的参数之一,对土壤的热恢复特性具有决定性意义.利用ANSYS有限元分析模型,模拟研究在变热流工况下,土壤的导热系数对土壤热恢复特性的影响.     

河南省农业水资源污染与防治研究

农业水资源污染已成为河南省生态环境恶化的主要原因之一,严重制约了其农业和农村经济环境的可持续发展.针对河南省农业水资源污染问题,通过分析河南省水资源污染及农业水资源污染现状,指出在水资源贫乏的当代,农药、化肥的过量使用,水土流失,秸秆焚烧以及畜禽养殖是造成农业面源污染的主要因素.对此,根据已有的经验和河南省的实际情况,在科学技术和政府的宏观调控等方面,提出对河南省农业水资源污染防治的措施.     

基于AVR微处理器的钢坯保温车电气系统

为钢坯运输车设计的专用保温罩,其可靠、高效工作有赖于优异的电气控制系统。采用ATMEL公司AVR微处理器为核心,并设计相关接口电路、驱动电路,最后制作出PCB控制板。该控制板能够实现对保温罩的顺序控制、延时控制及故障报警等功能。系统设有用于紧急情况的强制按钮。     

人体腰椎模拟植入椎弓根螺钉的有限元分析

利用三维绘图软件构建人体腰椎L4-L5节段几何模型,并模拟植入椎弓根螺钉.通过UG与Ansys Workbench的无缝接口将所建模型导入后者,对模型赋值并进行有限元分析,得出在人体站立情况下腰椎的应力云图与位移云图.从云图中可看出正常腰椎模型的最大应力出现在L4下关节突附近,值为15.073 MPa;最大位移出现在椎间盘上表面前部,值为0.161 mm.植入椎弓根螺钉的腰椎模型最大应力出现在螺钉的中部,值为38.613 MPa;最大位移出现在第4腰椎上端的前部,值为0.136 mm.结果表明：植入的椎弓根螺钉可缓解椎体的承载负担,并且可使腰椎变形减小.该结论可为同类腰椎固定手术以及脊柱的生物力学分析提供理论参考.     

Preparation of zeolite NaA for CO2 capture from nickel laterite residue

Zeolite NaA was successfully prepared from nickel laterite residue for the first time via a fusion-hydrothermal procedure. The structure and morphology of the as-synthesized zeolite NaA were characterized with a range of experimental techniques, such as X-ray diffraction, scanning electronic microscopy, and infrared spectroscopy. It was revealed that the structures of the produced zeolites were dependent on the molar ratios of the reactants and hydrothermal reaction conditions, so the synthesis conditions were optimized to obtain pure zeolite NaA. Adsorption of nitrogen and carbon dioxide on the prepared zeolite NaA was also measured and analyzed. The results showed that zeolite NaA could be prepared with reasonable purity, it had physicochemical properties comparable with zeolite NaA made from other methods, and it had excellent gas adsorption properties, thus demonstrating that zeolite NaA could be prepared from nickel laterite residue.     

Dissolution mechanism and solubility of hemimorphite in NH3-(NH4)2SO4-H2O system at 298.15 K简

The dissolution mechanism of hemimorphite in NH3-（NH4）2SO4-H2O system at 298.15 K was investigated by X-ray powder diffraction （XRD）, scanning electron microscopy （SEM）, Fourier transform infrared spectroscopy （FTIR） and X-ray photoelectron spectroscopy （XPS） analysis. The results show that hemimorphite is soluble in NH3-（NH4）2SO4-H2O system and its residue exists in the form of an amorphous SiO2 layer on the hemimorphite surface. The XPS data also indicate that the Si 2p3/2 and O ls spectra of the hemimorphite are broadened and shift to higher binding energies and their binding energies are closer to silica with an increase of total ammonia and time. Solubility of hemimorphite in NH3-（NH4）2SO4-H2O system was measured by means of isothermal solution method at 298.15 K based on the study of the dissolution mechanism of hemimorphite. The results show that the solubility of zinc in solution increases firstly and then decreases with the increase of cr（NH3） （total ammonia concentration） at different NH3/NH4^＋ ratios. The solubility of silicon in solution decreases from 0.0334 mol/kg in ct（NH3）-4.1245 mol/kg NH3-（NH4）2SO4-H2O solution to 0.0046 mol/kg in cT（NH3）=7.6035 mol/kg NH3-（NH4）2SO4-H2O solution.     

Cadmium in agricultural soils,vegetables and rice and potential health risk in vicinity of Dabaoshan Mine in Shaoguan,China

Soil cadmium （Cd） contamination resulted from mining and smelting is a major environmental concern,and health risk associated with Cd exposure to multi-media through muti-pathway is increasing.Cd concentrations in soils,vegetables and paddy rice were investigated,and potential non-carcinogenic and carcinogenic health risks exposure to Cd were estimated at six villages around the Dabaoshan Mine,South China.A total of 87 soil samples were found to exceed the China＇s maximum permission level （MPL） for Cd,while the highest value of 4.42 mg/kg was found near irrigation ditch associated with Hengshi River in Xinyi （XY） Village.Cd contents in vegetables and rice exceeded the maximum permissible concentration by more than five times in every village.Cadmium accumulation in plants is in the order of celery 〉 lactuca sativa L 〉 Chinese cabbage 〉 Romaine lettuce 〉 asparagus lettuce 〉 mustard 〉 cabbage mustard 〉 cabbage.The mean hazard quotient （HQ） of all villages is in the range of [5.29,25.75],and the mean values of cancer risk for investigated areas are more than 10 times greater than the USEPA （2009） threshold limit value of 10-4.Moreover,human non-carcinogenic and carcinogenic risks are mainly attributable to paddy rice intake,followed by vegetables intake,soil ingestion,inhalation,and dermal contact.The results indicate that Cd has a huge potential risk on human health for the local residents.     

一种改进的H.264帧层码率控制算法

针对H.264码率控制算法在缓冲区控制上的不足,提出一种改进的帧层码率控制算法.对缓冲区进行监视,根据已编码帧实际缓冲与目标缓冲占用率的情况进行量化参数的调整.当实际缓冲偏离目标缓冲较大时,适当增大或者减小量化参数,使编码后实际缓冲更接近目标缓冲,防止缓冲发生上溢或下溢.仿真结果表明,对于纹理简单的序列,改进的算法在PSNR几乎不变的情况下,得到了更精确的码率控制,实际缓冲更接近目标缓冲,缓冲区占有率更稳定.     

虚拟牛顿环光参量测试仪

虚拟仪器在测试测量领域、自动控制和工业控制领域有着广泛的应用.本文以虚拟牛顿环光参量的测量为例,介绍了虚拟仪器在物理实验中的具体应用.