热熔凝聚法加工农药悬浮剂研究

介绍了采用热熔凝聚法对加工二氯喹磷酸、氟虫睛、乙霉威悬浮剂的试验结果，并测定了制剂的粒度分布、冷贮、热贮稳定性等理化性质。该法工艺简单、加工方便、节省能源、工业上切实可行。     

耐盐性树脂PAA的合成及应用研究

以丙烯酸-丙烯酰胺为单体，过硫酸钾为引发剂，N，N-亚甲基双丙烯酰胺为交联剂。水浴阶梯升温共聚合成耐盐性树脂，采用正交试验通过分析，研究了主要因素对产物性能的影响，确定较佳反应条件：T=50℃(2h)～65℃(3h)，单体配比nAM：nAA=1：11，单体中和度[N]=90％～95％。引发剂浓度[I]=0．3％，单体浓度[M]=30％～35％，交联剂浓度[C]=0．025％～0．03％，并将此树脂作为缓释剂应用于固载二氧化氯中，取得了良好的效果。     

Water-soluble and amphiphilic polymers

Summary Three PEO-PSt-PEO triblock polymers and their parent ho-nopolystyrene have been studied by means of light scattering technique in chloroform, toluene and ethyl acetate. It has been found that the weight average molecular weights calculated by using the equation Mapp- were unbelievable negative values; and the largest deviation appeared for the sample with PEO mole content of about 50%. Data of PSt-PEO-PSt triblock polymers in literature have been quoted and discussed.     

钛酸钾品须填充UHMWPE复合材料的摩擦磨损性能研究

用钛酸钾晶须(PTW)对超高摩尔质量聚乙烯(UHMWPE)进行填充改性,考察了复合材料的摩擦磨损性能,研究了其结晶情况,观察了磨损表面形貌并分析了其机理.结果表明随着PTW用量的增加,复合材料的硬度、结晶度以及维卡软化点都有所增大.PTW提高了复合材料的耐磨性,但摩擦系数有所上升.PTW的加入使得UHMWPE的磨损机理从黏着磨损和塑性变形改变成疲劳磨损和轻微的塑性变形,提高了其抗磨粒磨损的性能.     

中央空调的水处理

本文扼要介绍了中央空调循环冷却水和冷冻水系统中常见的问题及其原因,并对冷却水和冷冻水的处理程序作了初步的阐述.     

ATO包裹硅酸锆的制备与应用

采用化学共沉淀技术制备了锑掺杂二氧化锡(ATO)包裹硅酸锆的导电粉体,对比了该导电粉体与ATO在防静电陶瓷中的应用效果。结果表明与掺纯ATO相比较,掺入ATO包裹硅酸锆的防静电陶瓷颜色比较浅,并且能明显减少氧化锡的用量,当陶瓷的表面电阻为107Ω/□量级时,用ATO包裹硅酸锆作为导电填料可以节省25%左右的ATO。     

The determination of the pore structural parameters of isoporous resins by inverse GPC

The swollen pore structure of a series of microporous isoporous resins (7.4–140 Å) are investigated with inverse GPC, n-alkylbenzenes and linear polystyrenes being used as probe molecules. The results indicated that, with the lowering of crosslinking degree of isoporous resins, the average pore diameter increased and the pore distribution curve broadened. All pore volume distribution obeyed a log-normal distribution. Based on the linear regression method, the experimental data were fitted to a monotonously declining exponential function and a normal distribution function by a computer, and some important structural parameters such as average pore diameter, pore volume distribution, specific surface area, etc. were obtained. The specific surface area of swollen gels were found much greater than those in the dry state measured by N₂ adsorption.     

冷却器盘管失效分析及防范措施

本文介绍了冷却器盘管破裂泄漏的情况，分析了失效破坏的原因，并提出防止冷却器盘管破裂泄漏的措施。     

四种杀菌剂对枸杞黑果病的防治效果

枸杞黑果病是枸杞产区的主要病害．发病后造成黑花、黑蕾和黑果，使枸杞产量降低，品质变劣。为探明四种杀菌剂对枸杞黑果病的防治效果及最佳剂量，2003年对下述四种杀菌剂进行了田间药效对比试验，调查防效结果如下：20％三苯基醋酸锡WP450～281g／hm^2(以有效成分计，下同)，20％氟硅唑EC21．08g／hm^21．5％噻霉酮EW16、88～21．08g／hm^2、40％氟硅唑EC450g／hm^2和70％甲基托布津WP787．5g/hm^2对枸杞黑果病防效均在88．25％以上。经LSD检验各处理间防效无显著差异。     

Electrochemical performance of nanocrystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol–gel method

A novel sol–gel method based on V₂O₅·nH₂O hydro-gel was developed to synthesize nanocrystalline Li₃V₂(PO₄)₃/carbon composite material. In this route, V₂O₅·nH₂O hydro-gel, NH₄H₂PO₄, Li₂CO₃ and high-surface-area carbon were used as starting materials to prepare precursor, and the Li₃V₂(PO₄)₃/carbon was obtained by sintering precursor at 750 °C for 4 h in flowing argon. The sol–gel synthesis ensures homogeneity of the precursors and improved reactivity. The sample was characterized by XRD, SEM and TEM. X-ray diffraction results show Li₃V₂(PO₄)₃ sample is monoclinic structure with the space group of P2₁/n. The TEM image indicates that the Li₃V₂(PO₄)₃ particles modified by conductive carbon are about 70 nm in diameter. The Li₃V₂(PO₄)₃/carbon system showed that the discharge capacities in the first and 50th cycle are about 155.3 and 143.6 mAh/g, respectively, in the range of 3.0–4.8 V. The sol–gel method is fit for the preparation of Li₃V₂(PO₄)₃/carbon composite material which may offer some favorable properties for commercial application.