影响乙腈回收单元长周期运行的问题分析及对策

介绍了乙腈回收再生单元改进工艺前的运行状况，分析了影响乙腈回收再生单元长周期运行的问题，采取了如下的工艺改进：净化进料；改进排污方式；更新改造回收塔；更新改进洗涤水冷凝器。延长了乙腈回收单元的运行周期。     

End-capped polystyrene with 8-hydroxyquinoline group by ATRP method

8-Hydroxyqunioline end-capped polystyrene was prepared through atom transfer free radical polymerization (ATRP) with 8-(5-chloromethyl) quinolyl acetate as initiator. The results indicated that this polymerization is a first order reaction with respect to monomer conversion. The molecular weight increased linearly with monomer consumption and very narrow distribution of molecular weight was obtained (polydispersity index less than 1.2). The FT-IR and NMR results show that the 8-hydroxyquinloine group was chemically bonded to the polymer end and there is nearly one 8-hydroxyquinoline group in per polymer chain. All those data show that polymerization of styrene at such conditions displayed living characters. The polymer with 8-hydroxyqquinoline end group reacted with triethylaluminum to form polymeric light-emitting complex and single layer LED was prepared by common spin-coating method. The peak wavelength of LED based on synthesized polymeric complex was around 570 nm.     

Leave-one-out cross-validation-based model selection for multi-input multi-output support vector machine

As an effective approach for multi-input multi-output regression estimation problems, a multi-dimensional support vector regression (SVR), named M-SVR, is generally capable of obtaining better predictions than applying a conventional support vector machine (SVM) independently for each output dimension. However, although there are many generalization error bounds for conventional SVMs, all of them cannot be directly applied to M-SVR. In this paper, a new leave-one-out (LOO) error estimate for M-SVR is derived firstly through a virtual LOO cross-validation procedure. This LOO error estimate can be straightway calculated once a training process ended with less computational complexity than traditional LOO method. Based on this LOO estimate, a new model selection methods for M-SVR based on multi-objective optimization strategy is further proposed in this paper. Experiments on toy noisy function regression and practical engineering data set, that is, dynamic load identification on cylinder vibration system, are both conducted, demonstrating comparable results of the proposed method in terms of generalization performance and computational cost.     

耐盐性树脂PAA的合成及应用研究

以丙烯酸-丙烯酰胺为单体，过硫酸钾为引发剂，N，N-亚甲基双丙烯酰胺为交联剂。水浴阶梯升温共聚合成耐盐性树脂，采用正交试验通过分析，研究了主要因素对产物性能的影响，确定较佳反应条件：T=50℃(2h)～65℃(3h)，单体配比nAM：nAA=1：11，单体中和度[N]=90％～95％。引发剂浓度[I]=0．3％，单体浓度[M]=30％～35％，交联剂浓度[C]=0．025％～0．03％，并将此树脂作为缓释剂应用于固载二氧化氯中，取得了良好的效果。     

新版Auto CAD计算机辅助设计在我公司氯碱设计中的应用

随着计算机技术及外围设备的提高和完善 ,计算机辅助设计和计算机辅助工程技术得到了日益广泛应用 ,绘图技术也得到了很大的发展 ,并已成为工程制图发展的必然趋势。我公司应用美国ＡＵＴＯＤＥＳＫ公司推出的新版ＡｕｔｏＣＡＤ2 0 0 2中文版本 ,是当前国际上最为先进和流行的绘图软件之一 ,具有以下增强功能。1　新增设计中心图库 ,在绘图过程中 ,可边绘图 ,边自动将所绘单元图储存在设计中心库中 ,这样可重复和快速使用相同或相近单元图 ,或在绘制新图时 ,可从中心库中随时提取相同或相近单元图形来绘制新图。其次 ,在绘图过程中 ,也可把…     

钛系聚酯催化剂的研究进展

介绍了聚酯催化剂中锑、锗、钛三个系列的各自特点，综述了复合型钛系和超细TiO2型聚酯催化剂的最新进展，认为新型钛系催化剂催化活性更高，更环保，而且用它合成的聚酯产品色相好，热稳定性得到了改善。     

N,N′-乙撑双[N(乙磺酸钠)-十二酰胺]的合成与性能评价

以乙二胺、2-氯乙基磺酸钠、月桂酸等为原料合成了N,N′-乙撑双[N(乙磺酸钠)-十二酰胺](简记为DTM-12)。以IR和1HNMR对其结构进行了初步表征。该目标产物水溶液的CMC(0.5 mmol/L)分别是十二烷基硫酸钠和十二烷基磺酸钠的1/16和1/20,γCMC(29.7 mN/m)低8~9 mN/m。DTM-12分别与十二烷基三甲基溴化铵(DTAB)和辛基酚聚乙氧基醚9-10EO(Triton X-100)组成的复配体系在摩尔比为3∶7时,CMC达到0.106和0.049 mmol/L,γCMC达到25.4和31.7 mN/m,优于十二烷基磺酸钠组成的复配体系。DTM-12还具有良好的起泡性和稳泡性。     

聚乙二醇重氮树脂在聚乙烯膜材料表面的自组装及亲水改性

用铬酸氧化法在聚乙烯薄膜的表面引入了羧基阴离子,合成了端基阳离子性的聚乙二醇重氮树脂,用静电自组装并辅以紫外光照射的方法,在聚乙烯薄膜的表面引入了共价键连接的聚乙二醇分子链.用紫外-可见分光光度法研究了重氮树脂及其静电自组装体系的光分解性质,得到重氮基团的分解速率常数kd=0.021 4 s-1.红外分析表明,紫外光照射后聚乙烯薄膜表面连接的聚乙二醇分子链可耐DMF-ZnC l2-H2O三元极性溶剂的刻蚀.由于在聚乙烯薄膜的表面引入了亲水性的聚乙二醇分子链,其表面接触角从改性前的104°降至48°.     

Water-soluble and amphiphilic polymers

Summary Three PEO-PSt-PEO triblock polymers and their parent ho-nopolystyrene have been studied by means of light scattering technique in chloroform, toluene and ethyl acetate. It has been found that the weight average molecular weights calculated by using the equation Mapp- were unbelievable negative values; and the largest deviation appeared for the sample with PEO mole content of about 50%. Data of PSt-PEO-PSt triblock polymers in literature have been quoted and discussed.     

光活性二氧化钛涂层的研究与制备

本文介绍了制备光活性TiO2涂层的两种主要方法，并就一些影响因素进行了简单的讨论。