聚四氟乙烯烧结成型的制备工艺

对聚四氟乙烯（PTFE）进行了压制试验和烧结试验，讨论了成型压力与试件的致密度、压缩强度以及压缩模量之间的关系，且对不同烧结工艺下试件的压缩强度进行了分析，得到较合适的成型压力和烧结工艺。结果表明：咖材料的压缩强度随压制压力的升高而减小，压缩模量随压制压力的升高而增加；闻的成型压力为27．5MPa，烧结温度380℃，保温时间4h。     

氟磷灰石-氟金云母微晶玻璃的生物活性研究

通过模拟细胞外液浸泡及动物骨内种植的方法研究了氟磷灰石-氟金云母微晶玻璃的生物活性机理。借助于SEM/EDAX,薄膜XRD,IRRS及原子吸收光谱分析等技术,研究了该微晶玻璃在生理环境中表面羟墓碘灰石层的形成过程。根据微晶玻璃中主晶相种类、显微结构特点及溶液中各离子的浓度等讨沦了羟基碑灰石层的形成机理。认为微晶玻璃中残余玻璃相的Ca~(2+)溶出及溶液相对于羟基磷灰石的过饱和状态,对材料表面羟基碑灰石层的形成具有重要意义。形成的羟基磷灰石层具有较低的结晶度,它是由最初的无定形态含水富CaO,P_2O_5薄层晶化转变而成。     

基于SR-UKF的OFDM频偏迭代估计算法研究

对高速运动环境下多普勒效应引起的大载波频偏引起的载波间干扰进行数学分析,建立带频偏的非时变和时变频偏OFDM动态状态空间模型,提出了基于平方根无迹卡尔曼滤波（square-root unscented Kalman filter , SR-UKF）的频偏估计算法。将非线性状态估计思想引入OFDM频偏估计中,实现了对频偏的有效跟踪和估计。仿真结果表明,在大频偏、高阶调制下,SR-UKF频偏估计算法较自消除算法、最大似然估计算法具有更好的误码率性能;在收敛精度、稳定度和对信噪比敏感度方面,性能较扩展卡尔曼滤波算法均有所提升。     

Effects of ion group content and polyol molecular weight on physical properties of HTPB‐based waterborne poly(urethane‐urea)s

A series of waterborne poly(urethane‐urea)s, WPUUs, based on using nonpolar hydroxyl‐terminated polybutadiene (HTPB) as the soft segment, were successfully synthesized in this article. The effects of the COOH group content and soft‐segment molecular weight (Mn_s) on the dispersion, morphology, and physical properties were investigated. Variations of the particle size, viscosity, and zeta potential were first governed by the hydrophilicity of the polymer chain, and then by the swelling derived from water. Fourier transfer infrared spectroscopy (FTIR) and differential scanning calorimetry (DSC) indicated that the degree of phase separation decreased as the COOH group content increased or as Mn_s decreased. However, the hydrogen bonding between the soft and hard segments and the two‐phase mixing could not occur in this nonpolar HTPB‐based WPUU system, indicating that the hard segments tended to form smaller domains and to pack more loosely. It was attributed to the fact that the presence of bulky ionic salt groups destroyed the ordered arrangement of the hard segments. In this case, the increases of the interface area between the soft and hard phases resulted in that the present behaviors were similar to the phase mixing. In tensile properties, HTPB‐based WPUUs exhibited higher tensile stress, elongation at break, and modulus as the COOH group content decreased or as Mn_s decreased. In thermal degradation, the introduction of HTPB polyol improved the thermal stability of WPUU. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Identification of new sesquiterpenoids in cephalic secretion of cuckoo bee,Nomada lathburiana (Apoidea,Anthophoridae)

A series of new sesquiterpene ketones and norsesquiterpene ketones could be identified from the cephalic secretion of females of the cuckoo bee,Nomada lathburiana (K.). The major component proved to be 2,6,10-trimethylundeca-(5E)-2,5,9-trien-4-one. Large amounts of high-boiling-point straight-chain hydrocarbons serve as solvents for the volatile, unstable ketones.     

取代2-四氢萘酮的一步合成新方法研究

本文介绍了一步法制备取代2-四氢萘酮的新方法,与常规合成方法相比,该法具有明显的优点:不需要先将羧酸转化成酰氯,避免了三氯化铝以及含氯溶剂的应用,并使催化剂得以循环利用。因此,该方法安全、环保,有望取代常规的付-克反应在工业上的应用。     

Modification of a carbon/carbon composite with a thermosetting resin precursor as a matrix by the addition of carbon black

Carbon/carbon composites were made through the pyrolysis of stabilized PAN felt and phenolic resin with the addition of 5 or 10 wt % carbon black to the matrix and then heat treatment at 600–2500°C. The effects of adding carbon black to the matrix precursor on the physical properties, microstructure, and mechanical properties of the resultant composites were investigated. Adding carbon black not only reduced the weight loss but also limited the shrinkage of the resultant composites. Adding carbon black also accelerated the formation of carbon basal planes in the matrix. At 2500°C, the crystalline stacking height in the composite with 10 wt % added carbon black was 200% greater than that with no additive. The flexural strength of the composite also increased from 15 to 42 MPa (almost 300%). © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 333–337, 2006     

十二烷基－二甲基（2－羟基）乙基氯化铵系列季铵盐的缓蚀性能

通过失重法和极化曲线、线性极化两种电化学方法，研究了十二烷基二甲基（２－羟基）乙基氯化铵（１２２）、十四烷基二甲基（２－羟基）乙基氯化铵（１４２）和十六烷基二甲基（２－羟基）乙基氯化铵（１６２）对２０＃碳钢在５％盐酸中的缓蚀作用。并与新洁尔灭（十二烷基二甲基苄基溴化铵）进行了比较。结果表明，它们在酸性介质中具有很好的缓蚀作用。     

纳米SiO_2粒子在环氧树脂中的分散工艺研究

研究了纳米SiO2在环氧树脂中的均匀分散工艺,探讨了超声波振荡和超声波分散时间对纳米SiO2/EP复合材料力学性能的影响,确定了最佳分散工艺。SEM表明,采用高剪切与超声波复合分散工艺比高剪切工艺的分散效果好;测试了复合材料的力学性能,进一步证明纳米SiO2具有增韧增强作用。     

TAF-10环氧沥青混合料动态弹性模量及路用性能试验研究

近些年来,环氧沥青混合料以其耐久性好、强度高、冲击韧性优越等特点,广泛地应用于大型桥梁桥面铺装之中.以TAF-10型环氧沥青混合料为研究对象,对其进行不同温度与频率下的动态模量试验,结合时温等效原理,通过Origin数学计算软件,采用西格摩德(Sigmoidal)模型对试验结果进行非线性拟合;并通过高温车辙试验、小梁弯曲试验及冻融劈裂试验,对其高温稳定性、低温抗裂性、水稳定性等路用性能进行检测.结果表明:随着加载频率的增大,TAF-10环氧沥青混合料的动态模量不断增大,而随试验温度的升高其值不断减小;拟合所得到的主曲线方程,可以对任何给定温度与加载频率下该种混合料的动态模量进行有效预估;TAF-10环氧沥青混合料的高温稳定性、低温抗裂性及水稳定性等性能均超出规范要求,满足桥面铺装要求.研究成果可以为TAF-10环氧沥青混合料桥面铺装的动态设计提供参考.