Simultaneous Voltammetric Determination of Synthetic Colorants in Foods Using a Magnetic Core–Shell Fe<Subscript>3</Subscript>O<Subscript>4</Subscript>@SiO<Subscript>2</Subscript>/MWCNTs Nanocomposite Modified Carbon Paste Electrode

This paper reports the production of a novel magnetic nanocomposite based on multi-walled carbon nanotubes (MWCNTs) decorated with magnetic core–shell Fe₃O₄@SiO₂ nanoparticles which were used to fabricate a modified carbon paste electrode (Fe₃O₄@SiO₂/MWCNT-CPE). The Fe₃O₄@SiO₂/MWCNT-CPE was investigated for the simultaneous determination of sunset yellow (SY) and tartrazine (TT) in 0.1 mol/L phosphate buffer solution (pH 6.0) using square wave voltammetry (SWV). The synthesized nanocomposite was characterized by transmission electron microscopy, scanning electron microscopy, energy dispersive spectroscopy and Fourier transform infrared spectroscopy. The proposed electrode exhibits linear ranges of 0.5–100 μmol/L SY and TT with detection limits of 0.05 and 0.04 μmol/L for SY and TT, respectively. The novel proposed voltammetric method was successfully applied in the simultaneous determination of SY and TT in food products, with results similar to those obtained using a HPLC method at 95 % confidence level.

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Graphical Abstract A magnetic nanocomposite based on MWCNTs decorated with core–shell Fe₃O₄@SiO₂ was prepared and showed good ability to distinguish the response of SY and TT

     

Constrained grinding optimization for time,cost, and surface roughness using NSGA-II

Selection of parameters in machining process significantly affects quality, productivity, and cost of a component. This paper presents an optimization procedure to determine the optimal values of wheel speed, workpiece speed, and depth of cut in a grinding process considering certain grinding conditions. Experimental studies have been carried out to obtain optimum conditions. Mathematical models have also been developed for estimating the surface roughness based on experimental investigations. A non-dominated sorting genetic algorithm (NSGA II) is then used to solve this multi-objective optimization problem. The objectives under investigation in this study are surface finish, total grinding time, and production cost subjected to the constraints of production rate and wheel wear parameters. The Pareto-optimal fronts provide a wide range of trade-off operating conditions which an appropriate operating point can be selected by a decision maker. The results show the proposed algorithm demonstrates applicability of machining optimization considering conflicting objectives.     

Power Sharing Improvement in Standalone Microgrids with Decentralized Control Strategy

Abstract—This article proposes a method that enables ideal sharing of reactive power among converter-based micro-sources in a microgrid with a decentralized control strategy. Power sharing must be properly performed among micro-sources to avoid circulating currents or overloading. Using conventional droop characteristics to achieve power sharing is not satisfactory, as system asymmetry will greatly impact the quality of sharing. In the proposed method, droop characteristic parameters are modified upon a change in system operating point such that ideal sharing takes place after the modification process. Simulation results are presented to show the validity of analysis.     

Control Optimization of a Slotted Switched Reluctance Generator for High-torque Applications

This article describes the control optimization of a slotted switched reluctance generator for low-speed applications. The machine is simulated with the finite-element method. The turn-off and turn-on angles are optimized by means of a genetic algorithm to maximize the output power and minimize the torque ripple. First, these two criteria are optimized separately with a mono-objective genetic algorithm, and then a multi-objective Pareto genetic algorithm is used. An analysis of optimized parameters and resulting current waveforms is also performed. Experimental results based on a 6/4 switched reluctance generator are also presented.     

Optimization of Output Power and Thermal Efficiency of Solar‐Dish Stirling Engine Using Finite Time Thermodynamic Analysis

This paper presents an investigation on finite time thermodynamic (FTT) evaluation of a solar‐dish Stirling heat engine. FTTs has been applied to determine the output power and the corresponding thermal efficiency, exergetic efficiency, and the rate of entropy generation of a solar Stirling system with a finite rate of heat transfer, regenerative heat loss, conductive thermal bridging loss, and finite regeneration process time. Further imperfect performance of the dish collector and convective/radiative heat transfer mechanisms in the hot end as well as the convective heat transfer in the heat sink of the engine are considered in the developed model. The output power of the engine is maximized while the highest temperature of the engine is considered as a design parameter. In addition, thermal efficiency, exergetic efficiency, and the rate of entropy generation corresponding to the optimum value of the output power is evaluated. Results imply that the optimized absorber temperature is some where between 850 K and 1000 K. Sensitivity of results against variations of the system parameters are studied in detail. The present analysis provides a good theoretical guidance for the designing of dish collectors and operating the Stirling heat engine system.     

转速对6061-T6铝合金搅拌摩擦搭接焊接头力学性能的影响(英文)

采用场发射扫描电子显微镜(FE-SEM),研究转速对厚度为5 mm的6061-T6铝合金搅拌摩擦搭接焊接头的宏观和微观组织、硬度、搭接头剪切性能和失效模式的影响。结果表明:在最低的转速度下,上模板和下模板具有十分相似的硬度分布。采用EDX分析发现,焊核区的断裂面中含有Fe的化合物。     

Ag2O-石墨混合物非等温分解的动力学分析

根据模型拟合Malek法、积分主曲线法和无模型的先进等转化率法,采用差示扫描量热仪系统研究了Ag2O-石墨混合物热分解的动力学。结果表明,热分解包含两个阶段,在第一阶段,Ag2O分解形成多孔银颗粒,该过程复杂,至少存在两种机制;在第二阶段,多孔粒子发生结构变化而形成大块银晶体,此过程为单步过程。     

Electrocatalytic and simultaneous determination of isoproterenol, uric acid and folic acid at molybdenum (VI) complex-carbon nanotube paste electrode

This paper describes the development, electrochemical characterization and utilization of a novel modified molybdenum (VI) complex-carbon nanotube paste electrode for the electrocatalytic determination of isoproterenol (IP). The electrochemical profile of the proposed modified electrode was analyzed by cyclic voltammetry (CV) that showed a shift of the oxidation peak potential of IP at 175 mV to less positive value, compared with an unmodified carbon paste electrode. Differential pulse voltammetry (DPV) in 0.1 M phosphate buffer solution (PBS) at pH 7.0 was performed to determine IP in the range from 0.7 to 600.0 μM, with a detection limit of 35.0 nM. Then the modified electrode was used to determine IP in an excess of uric acid (UA) and folic acid (FA) by DPV. Finally, this method was used for the determination of IP in some real samples.     

Wrinkling of sandwich column: comparison between finite element analysis and analytical solutions

Wrinkling analysis of sandwich columns was carried out. Two methods were used, namely finite element methods and analytical solutions. In the finite element methods, shell elements based on Reissner–Mindlin were employed across the beam thickness. A very fine element was used to model both the skin and the core across the beam thickness. The buckling mode was increased up to 100 in order to be able to model the wrinkling mode. The analytical solutions used energy methods and Raleigh–Ritz solutions developed earlier by the author. Finally, comparisons were made with experimental data taken from published results. Good agreements were achieved between the experimental results and both the finite element and analytical solution. The difference was less than 10%. Both finite element and analytical solutions were able to predict both symmetrical and asymmetrical wrinkling.     

EIS study of corrosion behavior of metallic materials in ethanol blended gasoline containing water as a contaminant

In the present paper, the effects of ethanol as a gasoline additive and water as a contaminant on the corrosion behavior of metallic components of a fuel delivery system were investigated. Electrochemical impedance spectroscopy (EIS) testing was performed in both water-free and water contaminated gasoline containing 0%, 5%, 10% and 15% ethanol without the addition of any supporting electrolyte. The surface of the specimens examined in 10% ethanol blended gasoline was observed by scanning electron microscope to understand what types of corrosion attack occurred. The results revealed that the addition of ethanol to gasoline fuel decreased the solution resistance and polarization resistance values of the specimens, resulting in an increase in the corrosion rates of these specimens in ethanol blended gasoline. Water contaminant caused a decrease in the polarization resistance of the ferrous specimens, whereas the observed behavior in others was reversed. Among the investigated metallic materials, the brazing alloy fared the best while Al 6061 alloy showed satisfactory corrosion resistance compared to the rest of the materials in both water-free and water-contaminated ethanol blended gasoline. Moreover, no localized attack was observed in corrosion products.