Steady-state multiplicity phenomena during the electrochemical promotion of NO reduction by C2H4 in presence of O2 on thin Rh and Pt catalyst-electrodes in a monolithic electropromoted reactor

The electrochemical promotion of catalysis (EPOC) was used to promote the selective reduction of NO by hydrocarbons in presence of oxygen using thin (40 nm) porous Rh and Pt catalyst layers sputtered on the opposite surfaces of thin (0.25 mm) solid electrolyte (YSZ) plates serving as electrocatalytic elements of a monolithic electrochemically promoted reactor (MEPR). Using 22 Rh/YSZ/Pt type cells it was found that the reduction of NO in presence of 1.1 kPa O₂ and 0.36 kPa C₂H₄ can be efficiently electropromoted with 340% rate enhancement, reaching 95% NO conversion with 100% selectivity to N₂ in the temperature range from 280 to 340 °C. The apparent Faradaic efficiency is larger than unity for both the NO reduction and the C₂H₄ oxidation reaction.At elevated temperatures (≥300 °C) and high reactant conversions it was found that after current interruption, the catalytic rates do not return to their initial values but remain in a new highly active steady state. It appears that this highly active state is not a genuine intrinsic permanent NEMCA state but is manifestation of steady-state multiplicity in the monolithic reactor resulting from near complete gaseous O₂ consumption. Thus the low and high activity steady states corresponding to zero applied potential appear to correspond to high and low average P_O2 in the reactor. The latter is the result of the near complete reactant conversion under the preceding electropromoted operation. These highly active permanent NEMCA states may be quite useful for practical applications.     

Analytical modeling of the partially-depleted SOI MOSFET

An analytical model for the partially-depleted (PD) silicon-on-insulator (SOI) MOSFET above threshold was developed. In contrast to previous models, this model includes front-back interface coupling with all the possibilities associated with it (accumulated, neutral, and depleted back interface). The model applies to tied-body as well as floating-body devices; however, thermal and edge effects are neglected. Interface coupling and floating-body effects are integrated together in a new “unified” algorithm. The “pseudo-two-dimensional” approach (which was used successfully to model lateral fields in bulk-Si devices) is extended to SOI devices. The model is extremely physical and thus highly predictive. Good agreement with experiment was obtained over a wide range of channel lengths and back gate voltages. Because of the model's neglect of thermal effects, however, disagreement was observed at high current levels. A brief physical interpretation of the results is also presented     

Electrical properties of TeAsGe films

The effect of temperature T, electrode separation d and substrate temperature T_s on the I–V characteristics of amorphous films 3500 Å thick, vapour deposited from the alloy TeAsGe (53:36:11 at. %) onto a glass substrate at room temperature, were investigated. The material displayed the behaviour of a negative resistance device with a memory. The behaviour for T=constant is described by the relation V = CIexp (?αI), where C and α are constants for a specimen at constant temperature. The threshold voltage at which the off state transforms to the negative resistance state decreased with T according to the relation V_th = V₀exp (E_v/2 kT), where E_v = 0.21 eV. V_th increased with d and decreased with T_s and was related to changes in resistance and structure. Microscope examination showed the formation of filaments containing recrystalized structure arising from Joule heating.     

Incremental Evaluation of Sliding-Window Queries over Data Streams

Two research efforts have been conducted to realize sliding-window queries in data stream management systems, namely, query revaluation and incremental evaluation. In the query reevaluation method, two consecutive windows are processed independently of each other. On the other hand, in the incremental evaluation method, the query answer for a window is obtained incrementally from the answer of the preceding window. In this paper, we focus on the incremental evaluation method. Two approaches have been adopted for the incremental evaluation of sliding-window queries, namely, the input-triggered approach and the negative tuples approach. In the input-triggered approach, only the newly inserted tuples flow in the query pipeline and tuple expiration is based on the timestamps of the newly inserted tuples. On the other hand, in the negative tuples approach, tuple expiration is separated from tuple insertion where a tuple flows in the pipeline for every inserted or expired tuple. The negative tuples approach avoids the unpredictable output delays that result from the input-triggered approach. However, negative tuples double the number of tuples through the query pipeline, thus reducing the pipeline bandwidth. Based on a detailed study of the incremental evaluation pipeline, we classify the incremental query operators into two classes according to whether an operator can avoid the processing of negative tuples or not. Based on this classification, we present several optimization techniques over the negative tuples approach that aim to reduce the overhead of processing negative tuples while avoiding the output delay of the query answer. A detailed experimental study, based on a prototype system implementation, shows the performance gains over the input-triggered approach of the negative tuples approach when accompanied with the proposed optimizations     

Performance of Primary Users in Spectrum Sharing Cognitive Radio Environment

This paper investigates the performance of the primary user in a multiuser cognitive radio environment. Using spectrum sharing method, multiple cognitive users compete to share a channel dedicated to the primary user in order to transmit their data to a common receiver unit. Only one cognitive user is scheduled to share the channel, and to do so, its transmit power should not increase the primary user’s outage probability above a certain limit. The average bit error rate and the average channel capacity of the primary user are derived in this setup for different cognitive scheduling schemes. The performance measures of the primary user are found to depend on the cognitive user’s scheduling criterion and on the parameters of the communication environment.     

New applications of pHluorin—measuring intracellular pH of prototrophic yeasts and determining changes in the buffering capacity of strains with affected potassium homeostasis

pHluorin is a pH‐sensitive variant of green fluorescent protein for measuring intracellular pH (pH_in) in living cells. We constructed a new pHluorin plasmid with the dominant selection marker KanMX. This plasmid allows pH measurements in cells without auxotrophic mutations and/or grown in chemically indefinite media. We observed differing values of pH_in for three prototrophic wild‐types. The new construct was also used to determine the pH_in in strains differing in the activity of the plasma membrane Pma1 H⁺‐ATPase and the influence of glucose on pH_in. We describe in detail pHluorin measurements performed in a microplate reader, which require much less hands‐on time and much lower cell culture volumes compared to standard cuvettes measurements. We also utilized pHluorin in a new method of measuring the buffering capacity of yeast cell cytosol in vivo, shown to be ca. 52 mM /pH for wild‐type yeast and moderately decreased in mutants with affected potassium transport. Copyright © 2010 John Wiley & Sons, Ltd.     

Analysis of Causes of Falsework Failures in Concrete Structures

A study of 85 major falsework collapses of bridges and buildings in the past 23 yrs has documented the types of collapsed falseworks and failed permanent structures, the construction stages at the time of collapse, and the causes of failures. Three causes of failure were identified: triggering; enabling; and procedural causes. Most failures occurred because of the interaction of the triggering and enabling events that were, in many cases, produced by inadequacies in the procedural methods. Impact forces resulting from concreting operations have repeatedly triggered falsework failures that were enabled by deficiencies in the falsework bracings, components, connections, foundations, and design. Inadequate review of falsework design and monitoring procedures were frequent problems that facilitated the occurrernce of these events. The findings emphasize the importance of proper delineation of responsibility of each party in the building process in order to reduce falsework failures in the future.