Microstructure developed in the surface layer of Ti-6Al-4V alloy after sliding wear in vacuum

Microstructural changes in the surface layer of Ti-6Al-4V alloy after sliding wear in vacuum have been studied by means of scanning and transmission electron microscopy (SEM and TEM). The wear rates of Ti-6Al-4V alloy in vacuum were measured under different sliding velocities and loads. The experimental results showed that a severely deformed layer with a grain size of 50–100 nm and thickness about 70 μm was formed underneath the worn surface. Under the slower sliding velocities, the substructure of the layer had a high dislocation density, while under higher sliding velocities, twins were found to exist in the substructure. A process by which the deformed layer formed has been proposed and the deformation of materials at the contacting spots of the Ti-6Al-4V sample is discussed.     

泡沫铝负载氧化铈的制备及其除氟性能研究

以六水合硝酸铈为铈源、六次甲基四胺为沉淀剂,通过水热法制备了氧化铈(CeO2)粉末和泡沫铝负载氧化铈复合体。环境扫描电镜(ESEM)观察表明成功实现了泡沫铝负载氧化铈,且氧化铈在泡沫金属上不易脱落。透射电子显微镜(TEM)观察表明氧化铈(CeO2)粉末颗粒的粒径为5～10nm,呈立方块状,选区电子衍射为多晶环。研究了pH值和时间对氧化铈及泡沫铝负载氧化铈复合体除氟性能的影响,经理论计算及实验数据拟合,结果表明CeO2及复合体除氟是在其表面的羟基同氟离子发生可逆交换吸附去除氟离子,属于交换吸附模型。     

有限单元法在地下工程围护结构传热中的应用

分析总结现有地下工程围护结构传热研究不足的基础上,对实际贴壁式和离壁式衬砌地下工程围护结构进行合理的物理数学简化,建立了热传递过程的数学模型.该数学模型中详细考察了不同的边界条件.有限单元法对复杂区域具有良好的适应性,论述了有限单元法在地下工程维护结构传热中的应用.     

Architecture engineering of hierarchically porous chitosan/vacuum-stripped graphene scaffold as bioanode for high performance microbial fuel cell

The bioanode is the defining feature of microbial fuel cell (MFC) technology and often limits its performance. In the current work, we report the engineering of a novel hierarchically porous architecture as an efficient bioanode, consisting of biocompatible chitosan and vacuum-stripped graphene (CHI/VSG). With the hierarchical pores and unique VSG, an optimized bioanode delivered a remarkable maximum power density of 1530 mW m(-2) in a mediator-less MFC, 78 times higher than a carbon cloth anode.     

氯化聚乙烯对氯丁橡胶与甲基丙烯酸甲酯接枝共聚反应的影响

研究了高氯氯化聚乙烯(HCPE)对氯丁橡胶与甲基丙烯酸甲酯接枝共聚及其反应产物的影响。结果表明,HCPE能加快聚合速率,提高转化率、接枝效率和接枝度。含HCPE的产物,含有较高分子量的级份,分子量分布较宽,树脂相的分布比较均匀,并具有较好的机械性能和较高的粘接强度。     

两种不同焊丝对7A05铝合金焊接性的影响

选择两种焊丝,对Al Zn Mg系合金7A05 T6进行焊接性研究。焊接裂纹试验结果表明,采用两种焊丝焊接7A05合金时,接头均具有较好的抗热裂纹敏感性。两种焊丝焊接接头的拉伸强度均为母材强度的75%以上,经过时效处理的焊接接头力学性能有了明显的提高。分析认为微观组织中沉淀物质点越小,均匀分散到晶界上越多,接头的拉伸强度越高。     

再生塑料内污染物迁移的有限元分析

建立计算仿真模型,该模型可用来预测再生塑料内污染物向液体产品(如食品)的迁移.该仿真模型的建立是基于有限元方法,可分析多层结构中的迁移.该项工作对于再生塑料尤其是有低阻隔性的聚烯烃在食品包装上的应用具有潜在意义.     

Direct vapor phase growth process and robust photoluminescence properties of large area MoS2 layers

There has been growing research interest in the use of molybdenum disulfide in the fields of optoelectronics and energy harvesting devices, by virtue of its indirect-to-direct band gap tunability. However, obtaining large area thin films of MoS2 for future device applications still remains a challenge. In the present study, the amounts of the precursors （S and MOO3） were varied systematically in order to optimize the growth of highly crystalline and large area MoS2 layers by the chemical vapor deposition method. Careful control of the amounts of precursors was found to the key factor in the synthesis of large area highly crystalline flakes. The thickness of the layers was confirmed by Raman spectroscopy and atomic force microscopy. The optical properties and chemical composition were studied by photoluminescence （PL） and X-ray photoelectron spectroscopy. The emergence of strong direct excitonic emissions at 1.82 eV （A-exciton, with a normalized PL intensity of -55 × 10^3） and 1.98 eV （B-exciton, with a normalized PL intensity of -5 × 10^3） of the sample at room temperature clearly indicates the high luminescence quantum efficiency. The mobility of the films was found to be 0.09 cm^2/（V.s） at room temperature. This study provides a method for the controlled synthesis of high-quality two-dimensional （2D） transition metal dichalcogenide materials, useful for applications in nanodevices, optoelectronics and solar energv conversion.     

高能球磨制备TiB_2/TiC纳米复合粉体

研究了通过高能球磨制备ＴｉＢ２／ＴｉＣ纳米复合粉体的反应过程和机理,对粉体的显微结构进行了表征．实验结果表明,采用金属 Ｔｉ和 Ｂ４Ｃ为原料,在球磨过程中, ＴｉＣ先于 ＴｉＢ２形成．球磨５ｈ后Ｔｉ与Ｂ４Ｃ反应生成ＴｉＢ２和ＴｉＣ,在随后的长时间高能球磨过程中ＴｉＢ２和ＴｉＣ两相保持稳定．球磨 ３０ｈ后,直径约 ８ｎｍ的 ＴｉＣ纳米粒子分布在 １００～２００ ｎｍ的 ＴｉＢ２粒子中,形成均匀分布的纳米ＴｉＢ２／ＴｉＣ复合粉体．