Hydrothermal synthesis of PtRu nanoparticles supported on graphene sheets for methanol oxidation in direct methanol fuel cell

Platinum–ruthenium (PtRu) nanoparticles are dispersed on graphene nanosheets and multi-walled carbon nanotubes (MWCNTs) via a hydrothermal method. Transmission electron microsocopy (TEM) observation shows the uniformly dispersed nanoparticles and the average nanoparticle size has been calculated. The electrochemical measurements demonstrate that the Pt–Ru/graphene catalyst exhibits about two times higher mass activity and better tolerance to poisoning species in methanol electro-oxidation than the Pt–Ru/MWCNTs catalyst. This study indicates that the PtRu anodic catalyst synthesized by hydrothermal method can be applied for direct methanol fuel cells (DMFC).     

Design of high efficiency mixed refrigerant Joule–Thomson refrigerator for cooling HTS cable

The substitution of high temperature superconducting (HTS) cables for existing subterranean electric transmission lines is arising as a solution to continuously increasing electricity demand in urban areas. A cryogenic refrigeration system having the characteristics of high reliability, high efficiency, large cooling capacity, and low capital cost is essential to enable such a substitution. These requirements can be satisfied with a mixed refrigerant Joule–Thomson (MR JT) refrigerator. Unfortunately, usual MR JT refrigerators exhibit good performance at refrigeration temperatures above 80 K. A precooled neon–nitrogen MR JT refrigerator is proposed in this paper that can cool HTS cables at 70 K. The coefficient of performance (COP) of the proposed MR JT refrigerator is predicted to be 0.058 at 70 K (19.2% for exergy efficiency) with the optimized design variables. The COP can be improved further to 0.064 by enhancing the efficiency of the precooling cycle. The maximum achievable COP demonstrates the feasibility of MR JT refrigerator for cooling HTS cable.     

Preparation and photoluminescence properties of γ-KCaPO4: Eu phosphors for near UV-based white LEDs

Novel whitish-blue phosphors based on a phosphate host matrix, γ-KCaPO₄: Eu²⁺, were prepared by a conventional solid-state reaction method using slightly phosphorus deficient conditions and their photoluminescence properties were investigated. The concentration quenching process, temperature dependence of the luminescence and decay curve were also investigated. The γ-KCaPO₄: Eu²⁺ phosphor was efficiently excited by UV-Visible light at wavelengths of 200-450 nm and exhibited a bright whitish-blue emission with a maximum peak wavelength of 473 nm. All of these characteristics suggest that the γ-KCaPO₄: Eu²⁺ phosphors combined with red phosphors could be applicable to near UV-based white LEDs, i.e., only two kinds of phosphor powders are needed for the formation of white light.     

Correlation of Microstructure and Hydrogen Delayed Fracture for 1GPa Steels

Automobile industry tries to reduce the weight of automobile using high-strength steels.However,the high-strength steels are highly susceptible to delayed-fracture caused by hydrogen embrittlement.With increasing the strength,hydrogen embrittlement is more sensitive to diffusible hydrogen.The mechanism of delayed-fracture and the relationship with the microstructure and alloying elements are still ambiguous.This study analyzed the effect of the size and the spheroidization rate for the carbides on hydrogen-induced delayed fracture for 1GPa TS steel.     

Efficiency improvement of polymer light-emitting diodes using a quantum dot interlayer between a hole transport layer and an emitting layer

The current efficiency of polymer light-emitting diodes (PLEDs) were improved using a quantum dot interlayer between a hole transport layer and an emitting layer. The quantum dot interlayer played a role of controlling the hole transport in the PLEDs and enhanced the charge balance in the emitting layer. The current efficiency of the PLEDs was increased by more than 20% by the quantum dot interlayer. In particular, the efficiency improvement was significant at high luminance due to reduced efficiency roll-off in the quantum dot-embedded PLEDs.     

Study of impact energy propagation phenomenon and modal characteristics of an armored vehicle undergoing high velocity impact

A new manufacturing technology is being employed to build a new type of armored vehicle. While thick panels are welded together in the old manufacturing technology, relatively thin panels are welded to a frame structure in the new manufacturing technology. The structural integrity of the new type of armor vehicles can be maintained mainly by the frame structures while the panel thickness is reduced significantly to reduce the total vehicle weight. Since the dynamic characteristics of a frame-panel hybrid structure are different from those of the old type of structure which consists of only thick panels, they should be identified to achieve a good performance of the vehicle. For this purpose, a proper FE model of the hybrid type of structure needs to be developed. In the present study, FE models are proposed to represent the frame-panel hybrid type structure efficiently. The impact energy propagation, the transient response and the modal characteristics are investigated with the FE models. This paper was presented at the 4th Asian Conference on Multibody Dynamics(ACMD2008), Jeju, Korea, August 20–23, 2008. Hong-Hee Yoo received a B.S. and M.S. degree in Mechanical Engineering from Seoul National University in 1980 and 1982. He then went on to receive his Ph.D. degree from Michigan State University in 1989. Dr. Yoo is currently a Professor at the School of Mechanical Engineering at Hanyang University in Seoul, Korea. His research interests are in the area of Flexible body dynamics, vibration.     

Semi-transparent thin film solar cells by a solution process

Easily processed, low cost, and highly efficient solar cells are desirable for photovoltaic conversion of solar energy to electricity. We present the fabrication of precursor solution processed CuInGaS2 (CIGS) thin film solar cells on transparent indium tin oxide (ITO) substrates. The CIGS absorber film was prepared by a spin-coating method, followed by two successive heat treatment processes. The first annealing process was on a hot plate at 300 °C for 30 min in air to remove carbon impurities in the film; this was followed by a sulfurization process at 500 °C in an H₂S(1%)/Ar environment to form a polycrystalline CIGS film. The absorber film with an optical band-gap of 1.52 eV and a thickness of about 1.1 µm was successfully synthesized. Because of the usage of a transparent glass substrate, a bifacial CIGS thin film device could be achieved; its power conversion efficiency was measured to be 6.64% and 0.96% for front and rear illumination, respectively, under standard irradiation conditions.     

Failure analysis of Cu(In,Ga)Se2 photovoltaic modules: degradation mechanism of Cu(In,Ga)Se2 solar cells under harsh environmental conditions

High‐temperature‐induced and humidity‐induced degradation behaviors were investigated through the failure analysis of encapsulated Cu(In,Ga)Se₂ (CIGS) modules and non‐encapsulated CIGS cells. After being exposed to high temperature (85 °C) for 1000 h, the efficiency loss of CIGS modules and the resistivities of the aluminum‐doped zinc oxide (AZO) layer, CIGS layer, and Mo layer were slightly increased. After damp heat (DH) testing (85 °C/85% RH), the efficiency of some modules decreased significantly accompanied by discoloration, and in these areas, the resistivity of the AZO layers increased markedly. The causes of degradation of CIGS cells after high temperature and DH tests were suggested through X‐ray photoelectron spectroscopy analysis. The high‐temperature‐induced degradation behaviors were revealed to be increases in series resistance of the CIGS cells, due to the adsorption of oxygen on the AZO, CIGS, and Mo layers. The degradation behavior after DH (85 °C/85% RH) exposure was caused by the adsorption of oxygen, as well as the generation of Zn(OH)₂ due to water molecules. In particular, the humidity‐induced degradation behavior in discolored CIGS modules was ascribed to the generation of Zn(OH)₂ and carboxylic acids in the AZO layer, due to a chemical reaction between the AZO, ethylene‐vinyl acetate copolymer, and water. Copyright © 2014 John Wiley & Sons, Ltd.