CO<Subscript>2</Subscript>-laser treatment of indium tin oxide nanoparticle coatings on flexible polyethyleneterephthalate substrates

A CO₂-laser treatment was used to improve the electrical conductivity of coatings of indium tin oxide (ITO) nanoparticles on flexible polyethyleneterephthalate (PET) substrates. The electrical conductivity and the transparency of CO₂-laser-treated ITO nanoparticle coatings were characterized with regard to the application as transparent electrodes. Furthermore, the stability of the electrical conductivity under oscillatory bending was investigated. A specific resistance of 0.12 Ω cm is obtained by CO₂-laser treatment without thermally damaging the PET film. The improvement of the electrical conductivity can be explained by a slight sinter neck formation. For a film thickness of 3 μm, a sheet resistance of 400 Ω/□ and a transmission in the visible range of 80% were achieved. The stability of the electrical conductivity of CO₂-laser-treated ITO nanoparticle coatings under bending was investigated using a specially constructed device for the application of various oscillatory bending loads. For a bending radius of 10 mm, the sheet resistance does not exceed 1000 Ω/□ after 300 bending cycles. Compared to commercial sputtered ITO coatings, CO₂-laser-treated ITO nanoparticle coatings show a significant higher stability under oscillatory bending.     

Synthesis of Metal-containing Polymers via Ring Opening Metathesis Polymerization (ROMP). Part I. Polymers Containing Main Group Metals

Synthesis of a broad range of diverse polymers containing main group metals by the new ROMP approach starting from metal-functionalized cyclic monomers and taking advantage of both classical and well-defined W-, Mo- and Ru-based metathesis catalytic systems is critically surveyed. Emphasis is laid upon Si-containing ring-opening metathesis polymers, popular due to the easy accessibility of the corresponding monomers and the valuable properties of the obtained polymers. Also highlighted is the production of modern advanced materials based on metal-containing polymers as well as some of their multifarious applications. Future opportunities for this field are finally outlined.     

DIMENSIONLESS REPRESENTATION OF PARTICLE SEPARATION CHARACTERISTIC OF CYCLONES

In particular the collection efficiencies were measured as a function of flow rate, cyclone dimensions and particle size. For this purpose a fast, accurate and problem adapted measuring technique has been used, which enables the determination of grade efficiency curves by measuring the size distributions in the cyclone up- and downstream with optical particle counters. The extended experimental data from this parameter study were analysed by the methods of dimensional analysis and theory of models. An evaluation of all measuring results for two cyclone designs has been resulted in an empirical, nondimensional correlation of the collection characteristic, a dimensionless grade efficiency curve. Deviating from geometric similarity this correlation includes a variation of cyclone outlet diameter. Grade efficiencies of the cyclones are a definite function of the dimensionless numbers Stokes and Reynolds number and of the dimensionless cyclone outlet diameter. Analysis of own and published data has shown that this experimental correlation includes the influence of the temperature and that cyclone body diameter do not influence efficiency. The influence of cyclone height on flow behaviour and collection characteristic could be quantified as well. The range, in which prediction of collection efficiencies is possible, is marked in a state diagram Reynolds number versus dimensionless cyclone height.     

Asymmetric bihomologous crosslinkers for bicomponent gels—The way to strongly increased elastic moduli

2‐Hydroxyethylmethacrylate (HEMA) and acrylamide (AA) have been copolymerized via free radical mechanism, in the presence of 5 mol % of four different crosslinker systems, the symmetric ethylenglycoldimethacrylate (EGDMA), bisacrylamide (BIS), a mixture of EGDMA and BIS, and the asymmetric acrylamideethylenmethacrylate (METAA). The polymerizations have been monitored with a rheometer, exhibiting the gel obtained with the asymmetric METAA, an elastic modulus that is dramatically increased compared with those of the gels prepared with the other three crosslinker systems. A kinetic analysis using the terminal model has been used to build probabilistic surfaces that give information about how the crosslinker is incorporated into the network. This analysis shows a high dissimilarity between the reactions using the asymmetric and the mixture of symmetric crosslinkers, what has been correlated to the difference in modulus. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Molecular structure and rheological properties of a poly(ethylene terephthalate) modified by two different chain extenders

This paper compares the molecular structure and rheological properties of a commercial poly(ethylene terephthalate) (PET) after reactive processing with different concentrations of either pyromellitic dianhydride (PMDA) or a multifunctional epoxide (Joncryl®ADR-4368) as a chain extender. By size exclusion chromatography with triple detection, an increase of molar mass, a broadening of molar mass distribution, and the generation of long-chain branched molecules were found for both chain extenders. While gel-free materials were obtained with PMDA, the processing with Joncryl leads to the formation of gels. The effect of branching, indicated by the Mark–Houwink exponent, is more pronounced for materials with Joncryl compared to PMDA and points to a more compact branching structure of the PET/Joncryl molecules. Rheological measurements in shear and elongation support the analysis from SEC and reveal a complex tree-like branching structure for both chain extenders. In addition, the role of the two modifiers with respect to processing was assessed.     

Newly Isolated Animal Pathogen Corynebacterium silvaticum Is Cytotoxic to Human Epithelial Cells

Corynebacterium silvaticum is a newly identified animal pathogen of forest animals such as roe deer and wild boars. The species is closely related to the emerging human pathogen Corynebacterium ulcerans and the widely distributed animal pathogen Corynebacterium pseudotuberculosis. In this study, Corynebacterium silvaticum strain W25 was characterized with respect to its interaction with human cell lines. Microscopy, measurement of transepithelial electric resistance and cytotoxicity assays revealed detrimental effects of C. silvaticum to different human epithelial cell lines and to an invertebrate animal model, Galleria mellonella larvae, comparable to diphtheria toxin-secreting C. ulcerans. Furthermore, the results obtained may indicate a considerable zoonotic potential of this newly identified species.     

Determination of thermal radiative properties of packed-bed media containing a mixture of polydispersed particles

Thermal radiative characteristics of packed beds containing a mixture of polydispersed SiO₂, ZnO, and C particles are determined numerically by employing the Monte Carlo technique, which is validated with the experimentally measured overall transmittance. A radiative heat transfer model is formulated for a pseudo-continuum multi-component medium of Mie-scattering particles. Good agreement is achieved by incorporating approximate phase functions that reproduce the experimentally observed preference for forward scattering.     

Performance of a solid oxide fuel cell couple operated via in situ catalytic partial oxidation of n-butane

The operation of a pair of anode-to-anode-facing solid oxide fuel cells (SOFCs) via in situ catalytic partial oxidation (CPO) of n-butane was investigated. In this simple “no-chamber” setup, butane is partially oxidized by heterogeneous reactions inside the porous anodes, providing processed fuel and the heat required for SOFC operation. The cell couple yielded a power density of up to 270 mW cm⁻², and the maximum total power obtained was 1.2 W with cell sizes of 13 mm × 23 mm. The maximum electrical efficiency was 1.3%. High CO concentrations of up to 1000 ppm were detected in the exhaust gas, indicating that the cell couple could not efficiently consume the complete provided fuel. A flame, lit at the exhaust, minimized the carbon monoxide level while having insignificant influence on the cell performance. Thermal insulation of the cell couple improved the output remarkably, showing the strong influence of temperature on cell performance. The two cells had a distance of only 2 mm, suggesting a potential for high volumetric power densities in multi-cell configurations for a self-sustained combined heat and power system.     

Exact Minkowski Products of N Complex Disks

An exact parameterization for the boundary of the Minkowski product of N circular disks in the complex plane is derived. When N > 2, this boundary curve may be regarded as a generalization of the Cartesian oval that bounds the Minkowski product of two disks. The derivation is based on choosing a system of coordinated polar representations for the N operands, identifying sets of corresponding points with matched logarithmic Gauss map that may contribute to the Minkowski product boundary. By means of inversion in the operand circles, a geometrical characterization for their corresponding points is derived, in terms of intersections with the circles of a special coaxal system. The resulting parameterization is expressed as a product of N terms, each involving the radius of one disk, a single square root, and the sine and cosine of a common angular variable over a prescribed domain. As a special case, the N-th Minkowski power of a single disk is bounded by a higher trochoid. In certain applications, the availability of exact Minkowski products is a useful alternative to the naive bounding approximations that are customarily employed in "complex circular arithmetic."