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81.
In this paper, the thermodynamic properties of lithium nitrate-ammonia mixtures are presented. The vapour pressure-temperature correlations are developed by fitting the experimental P-T-x data. The enthalpy of solution, the latent heat of vaporization, the integral heat of solution and the differential heat of solution are presented in appropriate tabular and graphical forms. 相似文献
82.
A differential feeder protection that utilizes voltage and current signals is described. This approach obviates the need for relay bias to compensate for capacitance spill current, thus improving the relay sensitivity. From a practical point of view, the scheme has been designed to simplify the digital hardware requirements and reduce the bandwidth requirements for signal transmission over a fiber-optic link 相似文献
83.
Heavy metal fluoride (HMF) glass optical fibres were spliced by fusing the two ends of fibres using a DC arc. An average optical loss of 0.08 dB per splice and strengths of up to 600 MPa were achieved for fusion splices using an inert gas purge during splicing. Estimates are made to determine the feasibility of achieving a splice loss of 0.005 dB for single-mode (HMF) fibres.<> 相似文献
84.
Chappell MA Laird DA Thompson ML Li H Teppen BJ Aggarwal V Johnston CT Boyd SA 《Environmental science & technology》2005,39(9):3150-3156
Smectites, clay minerals commonly found in soils and sediments, vary widely in their ability to adsorb organic chemicals. Recent research has demonstrated the importance of surface charge density and properties of exchangeable cations in controlling the affinity of smectites for organic molecules. In this study, we induced hysteresis in the crystalline swelling of smectites to test the hypothesis that the extent of crystalline swelling (or interlayer hydration status) has a large influence on the ability of smectites to adsorb atrazine from aqueous systems. Air-dried K-saturated Panther Creek (PC) smectite swelled less (d(001) = 1.38 nm) than never-dried K-PC (d(001) = 1.7 nm) when rehydrated in 20 mM KCl. Correspondingly, the air-dried-rehydrated K-PC had an order of magnitude greater affinity for atrazine relative to the never-dried K-PC. Both air-dried-rehydrated and never-dried Ca-PC expanded to approximately 2.0 nm in 10 mM CaCl2 and both samples had similar affinities for atrazine that were slightly lower than that of never-dried K-PC. The importance of interlayer hydration status in controlling sorption affinity was confirmed by molecular modeling, which revealed much greater interaction between interlayer water molecules and atrazine in a three-layer hydrate relative to a one-layer hydrate. The entropy change on moving atrazine from a fully hydrated state in the bulk solution to a partially hydrated state in the smectite interlayers is believed to be a major factor influencing sorption affinity. In an application test, choice of background solution (20 mM KCl versus 10 mM CaCl2) and air-drying treatments significantly affected atrazine sorption affinities for three-smectitic soils; however, the trends were not consistent with those observed for the reference smectite. Further, extending the initial rehydration time from 24 to 240 h (prior to adding atrazine) significantly decreased the soil's sorption affinity for atrazine. We conclude that interlayer hydration status has a large influence on the affinity of smectites for atrazine and that air-drying treatments have the potential to modify the sorption affinity of smectitic soils for organic molecules such as atrazine. 相似文献
85.
Wood samples and veneers of Hevea brasiliensis (Rubber wood) and Acacia auriculaeformis treated with aqueous solutions of chromium trioxide, ferric chloride and ferric nitrate were studied for water repellency and their reaction with wood constituents. FTIR spectra obtained from wood surface treated with chromium trioxide indicate the formation of a water insoluble complex between chromium trioxide and aromatic ring of lignin, whereas no reaction takes place with ferric salts. Treatment of wood by chromium trioxide was found to be effective in imparting water repellency in wood. 相似文献
86.
Anu Bajaj Atul Khanna Narendra K. Kulkarni Suresh K. Aggarwal 《Journal of the American Ceramic Society》2009,92(5):1036-1041
Bismuth borate glasses from the system: 40Bi2 O3 –59B2 O3 –1Tv2 O3 (where Tv=Al, Y, Nd, Sm, and Eu) and three glasses of composition: 40Bi2 O3 –60B2 O3 , 37.5Bi2 O3 –62.5B2 O3 and 38Bi2 O3 –60B2 O3 –2Al2 O3 were prepared by melt quenching and characterized by density, UV-visible absorption spectroscopy and differential thermal analysis (DTA) studies. Bismuth borate glasses exhibit a very strong optical absorption band just below their absorption edge. Glasses were devitrified by heat treatment at temperatures above their glass transition temperatures and the crystalline phases produced in them were characterized by Fourier transform infrared (FTIR) absorption spectroscopy and X-ray diffraction (XRD). Bi3 B5 O12 was found to be the most abundant phase in all devitrified samples. DTA studies on glasses and FTIR and XRD analysis on crystallized samples revealed that very small amounts of trivalent ion doping causes significant changes in the devitrification properties of bismuth borate glasses; rare-earth ions promote the formation of metastable BiBO3 –I and BiBO3 –II phases during glass crystallization. 相似文献
87.
Manoj K. Sharma Arvind S. Ambolikar Suresh K. Aggarwal 《Journal of Materials Science》2011,46(17):5715-5722
In situ one-step chemical synthesis route for the preparation of a gold–polyaniline composite in nanopores of polycarbonate
(PC) membrane is reported. PC membrane, which was placed in a specially designed two-compartment cell, separated the aqueous
solution of aniline from HAuCl4 solution. Concentration gradient across the membrane caused movement of AuCl4
− and anilinium ions in the pores of polycarbonate membrane. Nanopores in PC membrane acted as reaction vessels where aniline
and HAuCl4 were allowed to mix together, and the redox reaction between aniline and HAuCl4 led to the formation of gold–polyaniline composite. The gold–polyaniline composite in PC membrane was characterised by EDXRF,
XRD, UV–Vis spectroscopy, FTIR and TEM. Peak broadening in XRD suggests that Au particles formed in the membrane are nanocrystallites
and average crystallite size is (24 ± 4) nm. TEM studies show that gold nanoparticles are randomly dispersed in polyaniline
clusters formed in the nanopores of PC membrane. Characterisation results show that the surfaces of the PC membrane exposed
to HAuCl4 and aniline have significantly higher concentrations of Au nanoparticles and polyaniline, respectively. 相似文献
88.
Mining associations with the collective strength approach 总被引:1,自引:0,他引:1
The large itemset model has been proposed in the literature for finding associations in a large database of sales transactions. A different method for evaluating and finding itemsets referred to as strongly collective itemsets is proposed. We propose a criterion stressing the importance of the actual correlation of the items with one another rather than their absolute level of presence. Previous techniques for finding correlated itemsets are not necessarily applicable to very large databases. We provide an algorithm which provides very good computational efficiency, while maintaining statistical robustness. The fact that this algorithm relies on relative measures rather than absolute measures such as support also implies that the method can be applied to find association rules in data sets in which items may appear in a sizeable percentage of the transactions (dense data sets), data sets in which the items have varying density, or even negative association rules 相似文献
89.
Theoretical and experimental study of the second-order polarizabilities of Schiff''s bases for nonlinear optical applications 总被引:1,自引:0,他引:1
K. Bhat J. Choi S.D. McCall M.D. Aggarwal B.H. Cardelino C.E. Moore Benjamin G. Penn D.O. Frazier M. Sanghadasa T.A. Barr N.B. Laxmeshwar 《Computational Materials Science》1997,8(4):309-316
A series of twenty-four Schiff's bases was synthesized and nonresonant static molecular second order polarizabilities (β) of these compounds were theoretically calculated and compared with experimental values. The computational method employed obtained: (a) values of polarization versus static electric fields using a semiempirical Hamiltonian; (b) all tensor elements of β by performing polynomial fits of the former data, within the finite-field approach. The experimental values were obtained using a modified electric field induced second harmonic generation (EFISH) experiment with 1,4-dioxane as the solvent. The measured quantities were the projection of β on μ (the permanent dipole moment), relative to MNA (2-methyl-4-nitroaniline). The correlation between the predicted static molecular quantities and their corresponding experimental values was 0.95 (based on a simple least-squares regression forced through the origin). A factor of 8.7 ± 0.3 was determined to be the adjustment parameter for Schiff's bases to account for the solvent and dispersion effects at the fundamental wavelength of 1064 nm. 相似文献
90.